This Page keeps a track of the latest advances in Au/Ag/Pt catalysis and is supported by the National Science Foundation (NSF) under grant # 0969157. Thank you for visiting!!!

Dec 6-12th


Youliang Wang

Simple and Mild Synthesis of Indoles via Hydroamination Reaction Catalysed by NHC–Gold Complexes: Looking for Optimized Conditions

Electronic Interactions in Gold(I) Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

Water-Soluble Gold–N-Heterocyclic Carbene Complexes for the Catalytic Homogeneous Acid- and Silver-Free Hydration of Hydrophilic Alkynes

Concise Total Synthesis of Enigmazole A

Silver-catalyzed one-step synthesis of multiply substituted quinolines

On the Mechanism of the Digold(I)–Hydroxide-Catalysed Hydrophenoxylation of Alkynes

Synthesis of Fused Carbazoles by Gold-Catalyzed Tricyclization of Conjugated Diynes via Rearrangement of an N-Propargyl Group

Nov 29-Dec 5th




Gold Catalyzed Synthesis of Substituted Furan by Intermolecular Cascade Reaction of Propargyl Alcohol and Alkyne

Intramolecular Gold-Catalyzed and NaH-Supported Cyclization Reactions of N-Propargyl Indole Derivatives with Pyrazole and Pyrrole Rings: Synthesis of Pyrazolodiazepinoindole, Pyrazolopyrazinoindole, and Pyrrolopyrazinoindole

Gold-Catalyzed Allenamide [2+2+2]-Cyclotrimerization

Synthesis of Fused Carbazoles by Gold-Catalyzed Tricyclization of Conjugated Diynes via Rearrangement of an N-Propargyl Group

Use of Planar Chiral Ferrocenyl­phosphine-Gold(I) Complexes in the Asymmetric Cycloisomerization of 3-Hydroxylated 1,5-Enynes

Nov 16-22th



Gold-Catalyzed C[BOND]H Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acyl Indoles

Gold Catalyzed Synthesis of Substituted Furan by Intermolecular Cascade Reaction of Propargyl Alcohol and Alkyne

Nov 9-15th



E-Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis

Diastereoselective Synthesis of Protected 1,3-Diols by Catalytic Diol Relocation

Synthesis of Functionalized Chromeno[2,3-b]pyrrol-4(1H)-ones by Silver-Catalyzed Cascade Reactions of Chromones/Thiochromones and Isocyanoacetates

Theoretical insight into the mechanisms of the synthesis of chiral gold(I)–aminocarbene complexes

C–H insertions in oxidative gold catalysis: synthesis of polycyclic 2H-pyran-3(6H)-ones via a relay strategy

Nov 1-7



Mild and Efficient Silver(I) Triflate Catalyzed Synthesis of 2-Aryl-2,3-dihydroquinolin-4(1H)-ones, and Their Antioxidant Activities

Gold-Catalyzed Intermolecular anti-Markovnikov Hydroamination of Methylenecyclopropanes with 2-Pyridones

Amidinatogermylene Complexes of Copper, Silver, and Gold

The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation

Synthesis of new benzo[f]imidazo[1,2-d][1,4]oxazepines: AgNO3-mediated intramolecular hydroamination

Gold-Catalyzed Ring Expansion of Alkynyl Heterocycles through 1,2-Migration of an Endocyclic Carbon–Heteroatom Bond

SilverCatalyzed Cascade Carboxylation and Cyclization of Trimethyl(2-methylenebut-3-yn-1-yl)silane Derivatives

Oct 26-31st


Xingguang Li

Divergent C H Insertion–Cyclization Cascades of N-Allyl Ynamides

Gold(I)-Catalyzed Dearomative [2+2]-Cycloaddition of Indoles with Activated Allenes: A Combined Experimental–Computational Study

Gold(I)-catalyzed highly stereoselective synthesis of polycyclic indolines: the construction of four contiguous stereocenters

Dual gold/photoredox-catalyzed C(sp)–H arylation of terminal alkynes with diazonium salts

Polysubstituted 2-Aminopyrrole Synthesis via Gold-Catalyzed Intermolecular Nitrene Transfer from Vinyl Azide to Ynamide: Reaction Scope and Mechanistic Insights

Silver(I)-Catalyzed Enantioselective Desymmetrization of Cyclopentenediones: Access to Highly Functionalized Bicyclic Pyrrolidines

Silver-Catalyzed Enantioselective Propargylation Reactions of N-Sulfonylketimines

Oct 12-19th



Self-Relay Gold(I)-Catalyzed Pictet–Spengler/Cyclization Cascade Reaction for the Rapid Elaboration of Pentacyclic Indole Derivatives

Gold(I)-Assisted α-Allylation of Enals and Enones with Alcohols

Alkene-Directed N-Attack Chemoselectivity in the Gold-Catalyzed [2+2+1]-Annulations of 1,6-Enynes with N-Hydroxyanilines

Activation of a Hydroamination Gold Catalyst by Oxidation of a Redox-Noninnocent Chlorostibine Z-Ligand

Oct 5-11th



Kinetic or Dynamic Control on a Bifurcating Potential Energy Surface? An Experimental and DFT Study of Gold-Catalyzed Ring Expansion and Spirocyclization of 2-Propargyl-β-tetrahydrocarbolines

Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines

Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2–O Bond Forming Reactions

Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent

Luminescent (N^C^C)-Gold(III) Complexes: Stabilized Gold(III) Fluorides

Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

Dinuclear planar chiral ferrocenyl gold(I) & gold(II) complexes

Synthesis of highly strained bicyclic[3.n.1]alkenes by a metal-catalyzed Conia-ene reaction

From proton transferred to cyclometalated platinum(IV) complex: Crystal structure and biological activity

A highly efficient Mukaiyama–Mannich reaction of N-Boc isatin ketimines and other active cyclic ketimines using difluoroenol silyl ethers catalyzed by Ph3PAuOTf

Concurrent B-to-Pt Methyl Migration and B-Center Retention in Aerobic Oxidation of Methylborato Platinum(II) Complexes

Synthesis of Oxazolidin-2-ones by Tandem Cyclization of Propargylic Alcohols and Phenyl Isocyanate Promoted by Silver Catalysts as π-Lewis Acids

Gold-catalyzed tandem reactions of amide–aldehyde–alkyne coupling and cyclization-synthesis of 2,4,5-trisubstituted oxazoles

Sept 28-Oct 3



Indium Versus Gold Catalysis in Dehydrative Reactions with Allylic Alcohols

Polyoxometalate-Gold(I)/H+ Complexes: Air-Stable, Efficient, Polyvalent, and Bifunctional Catalysts

Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes

Gold-catalyzed stereoselective 1,4-conjugate addition of pyrazoles to propiolates and their hydrogenation to β-pyrazolyl acid esters

Diastereoselective synthesis of quinolizidin-4-one and indolizidin-3-one derivatives with a spirocyclic motif via cascade cyclization using a gold(I)/Brønsted acid relay catalysis

Gold(I)/(III)-Catalyzed Synthesis of 2-Substituted Piperidines; Valency-Controlled Cyclization Modes

Synthesis of 2,5-Dihydrofurans via a Gold(I)-Catalyzed Formal [4 + 1] Cycloaddition of α-Diazoesters and Propargyl Alcohols

Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Sept 14-20th



A Stimuli-Responsive Rotaxane–Gold Catalyst: Regulation of Activity and Diastereoselectivity

Silver-Catalyzed Decarboxylative Azidation of Aliphatic Carboxylic Acids

Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis

Sept 7-13rd



Silver(I)-Catalyzed N-Trifluoroethylation of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane

Steric control of the in/out sense of bridgehead substituents in macrobicyclic compounds: isolation of new “crossed chain” variants of in/out isomers

Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z– or E-configured buta-1,3-dien-2-yl esters

Sep 1-7 



Silver-catalyzed [3 + 2] cycloaddition of isocyanides with diazo compounds: new regioselective access to 1,4-disubstituted-1,2,3-triazoles

Selectfluor promoted NHC–oxazoline gold(I) complex catalyzed cycloaddition/oxidation reaction of enynones with alkenes

Aug 25-31



Silver(I)-Catalyzed Dearomatization of Alkyne-Tethered Indoles: Divergent Synthesis of Spirocyclic Indolenines and Carbazoles

Insights into the Gold-Catalyzed Propargyl Ester Rearrangement/Tandem Cyclization Sequence: Radical versus Gold Catalysis¡-Myers-Saito- versus Schmittel-Type Cyclization

Aug 17-24th



Dual Gold Catalysis: Stepwise Catalyst Transfer via Dinuclear Clusters

Gold-Catalyzed Cycloisomerization and Diels–Alder Reaction of 1,6-Diyne Esters with Alkenes and Diazenes to Hydronaphthalenes and -cinnolines

Divergent Gold(I)-Catalyzed Skeletal Rearrangements of 1,7-Enynes

Insights into the Gold-Catalyzed Propargyl Ester Rearrangement/Tandem Cyclization Sequence: Radical versus Gold Catalysis—Myers–Saito- versus Schmittel-Type Cyclization

Aug 10-16th


Zhou Xu

Ligand Control over the Electronic Properties within the Metallic Core of Gold Nanoparticles

A Desulfonylative Approach in Oxidative Gold Catalysis: Regiospecific Access to Donor-Substituted Acyl Gold Carbenes

Construction of Multifunctionalized Azopyrazoles by Silver- Catalyzed Cascade Reaction of Diazo Compounds

Aug 3-9th



Au-Catalyzed Pentannulation Reaction of Propargylic Esters Occurring at C(sp3)–H Site

Copper Catalyzed Enantioselective Alkylation of Pyrrole with β,γ-Unsaturated α-Ketoesters: Application to One-Pot Construction of the Seven-Membered Ring by Merging a Gold Catalysis

Formal Gold-to-Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladium

Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study

Synthesis of 1,2-Diamines via Hydroamination Reactions


July 26-Aug 2



Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution

Generation of α-Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

July 13th-July 19



Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules

AgSCF3-Mediated Trifluoromethylthiolation/Radical Cascade Cyclization of 1,6-Enynes

Gold-catalyzed formal [4π+2π]-cycloadditions of tert-butyl propiolates with aldehydes and ketones to form 4H-1,3-dioxine derivatives

Construction of Multifunctionalized Azopyrazoles by Silver- Catalyzed Cascade Reaction of Diazo Compounds

July 6th-July 12


Zhou Xu

Synergistic Gold and Iron Dual Catalysis: Preferred Radical Addition toward Vinyl–Gold Intermediate over Alkene

Catalytic Dual 1,1-H-Abstraction/Insertion for Domino Spirocyclizations

Gold-Catalyzed Proto- and Deuterodeboronation

Catalyst-controlled divergence in cycloisomerisation reactions of N-propargyl-N-vinyl sulfonamides: gold-catalysed synthesis of 2-sulfonylmethyl pyrroles and dihydropyridines

Mechanistic Insights into the Post-Cyclization Isomerization in Gold-Catalyzed 7-exodig-Hydroarylations

Asymmetric Dearomatization of 1-Amino­naphthalene Derivatives through C–C Bond Formation with Electron-Rich Heterocycles as Nucleophiles

Gold(III)-Catalyzed Intramolecular Cyclization of α-Pyrroles to Pyrrolopyridinones and Pyrroloazepinones: A DFT Study

June 29th-July 5th



Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles

Identifying Solid Luminogens through Gold-Catalysed Intramolecular Hydroarylation of Alkynes

Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

Jun 22-28th



Prying open a Reactive Site for Allylic Arylation by Phosphine-Ligated Geminally Diaurated Aryl Complexes

Computational and Experimental Study on Selective sp2/sp3 or Vinylic/Aryl Carbon–Hydrogen Bond Activation by Platinum(II): Geometries and Relative Stability of Isomeric Cycloplatinated Compounds

Chiral Phosphine–Silver(I) Complex Catalyzed Enantioselective Interrupted Feist–Bénary Reaction with Ynones: The Aldol–Cycloisomerization Cascade

Jun 15-21th



Catalyst-Dependent Stereodivergent and Regioselective Synthesis of Indole-Fused Heterocycles through Formal Cycloadditions of Indolyl-Allenes

Silver-Catalyzed Aerobic Oxidative Decarboxylative Coupling of Arylpropiolic Acids with H-Phosphine Oxides: Mild and Facile Synthesis of β-Oxophosphine Oxides

Engineering Ligands on Au Center: Discovering Broadly Applicable Gold Catalysis with High Turn Over Numbers

Jun 1-14th



Silver-Mediated N-Trifluoromethylation of Sulfoximines

Gold-Catalyzed Cyclization Leads to A Bridged Tetracyclic Indolenine that Represses β-Lactam Resistance

Ligand-Assisted Gold-Catalyzed Cross-Coupling with Aryldiazonium Salts: Redox Gold Catalysis without an External Oxidant

Diversity in Gold-Catalyzed Formal Cycloadditions of Ynamides with Azidoalkenes or 2H-Azirines: [3+2] versus [4+3] Cycloadditions

Asymmetric Dearomatization of 1-Amino­naphthalene Derivatives through C–C Bond Formation with Electron-Rich Heterocycles as Nucleophiles

Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides

Silver Triflate Catalyzed Cyclopropyl ­Carbinol Rearrangement for Benzo[b]oxepine and 2H-Chromene Synthesis

Gold(I)-Catalyzed Tandem Reaction of γ-Amino-Substituted Propargylic Esters to Pyrrolines and its Application in the Formal Synthesis of (±)-Aphanorphine

Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes

May 25-31th



Synthesis of Multiple-Substituted Pyrroles via Gold(I)-Catalyzed Hydroamination/Cyclization Cascade

Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement

Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions

Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of 5-Iodotriazoles

Gold-Catalyzed Cycloisomerization and Diels–Alder Reaction of 1,4,9-Dienyne Esters to 3 a,6-Methanoisoindole Esters with Pro-Inflammatory Cytokine Antagonist Activity

Mechanistic Investigations of the AuCl3-Catalyzed Nitrene Insertion into an Aromatic C—H Bond of Mesitylene

May 18-24th



Indole Functionalization via Photoredox Gold Catalysis

Gold(I)/(III)-Catalyzed Synthesis of Cyclic Ethers; Valency-Controlled Cyclization Modes

Synthesis of γ-Acetoxy β-Keto Esters Through Regioselective Hydration of γ-Acetoxy-α,β-alkynoates

Gold- and Silver-Catalyzed 7-endodig Cyclizations for the Synthesis of Oxazepines

Gold and silver catalysis: from organic transformation to bioconjugation

May 4th-May 11th



Ligand-Controlled Product Selectivity in Gold-Catalyzed Double Cycloisomerization of 1,11-Dien-3,9-Diyne Benzoates

Synthesis of diverse di- to penta-substituted 1,2-dihydropyridine derivatives from gold(I)-catalyzed intramolecular addition of tertiary enamides to alkynes

The Stabilizing Effects in Gold Carbene Complexes†

AuCl3– and AuCl3–Phenylacetylene-Catalyzed Glycosylations by Using Glycosyl Trichloroacetimidates

Gold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketals

Apr 19 – May 3




Skeletal Rearrangement of O-Propargylic Formaldoximes by a Gold-Catalyzed Cyclization/Intermolecular Methylene Transfer Sequence

Synthesis and Characterization of a Gold Vinylidene Complex Lacking p-Conjugated Heteroatoms

N-Methylation of Amines with Methanol at Room Temperature

Synthetic Progress toward Azadirachtins. 1. Enantio- and Diastereoselective Synthesis of the Left-Wing Fragment of 11-epi-Azadirachtin I

Highly Selective Carboxylative Cyclization of Allenylmethylamines with Carbon Dioxide Using N-Heterocyclic Carbene-Silver(I) Catalysts

Silver-Catalyzed Direct Thiolation of Quinones by Activation of Aryl Disulfides to Synthesize Quinonyl Aryl Thioethers

Cobalt(II)/silver relay catalytic isocyanide insertion-cycloaddition cascades: A new access toward pyrrolo[2,3-b]indoles

Gold(I)-catalyzed cyclization of o-(alkynyl)styrene ether mediated by MeOH for the construction of 2-aryl-1H-indene acetal

Apr 13-19



Synthesis of 3-Sulfonylamino Quinolines from 1-(2-Aminophenyl) Propargyl Alcohols through a Ag(I)-Catalyzed Hydroamination, (2 + 3) Cycloaddition, and an Unusual Strain-Driven Ring Expansion

Silver-Catalyzed Tandem Hydroazidation/Alkyne–Azide Cycloaddition of Diynes with TMS-N3: An Easy Access to 1,5-Fused 1,2,3-Triazole Frameworks

Unique distal size selectivity with a digold catalyst during alkyne homocoupling

Silver(I)-Catalyzed Tandem Approach to β-Oxo Amides

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5-exo/6-endodig Selectivity, Methodology and Scope

Scope and Limitations of the Intermolecular Furan-Yne Cyclization

Lewis Acid-Catalyzed or Base-Promoted Regioselective Cycloisomerization of N-Imidoyl-o-alkynylanilines for Synthesis of N-Imidoyl-(1 H)-indoles and 4-Alkylidene-3,4-dihydroquinazolines

From Isonitriles to Unsaturated NHC Complexes of Gold, Palladium and Platinum

Silver Hexafluoroantimonate-Catalyzed Direct α-Alkylation of Unactivated Ketones

Apr 6-12



Expanding the Forefront of Strong Organic Brønsted Acids: Proton-Catalyzed Hydroamination of Unactivated Alkenes and Activation of Au(I) for Alkyne Hydroamination

Construction of β-Mannosidic Bonds via Gold(I)-Catalyzed Glycosylations with Mannopyranosyl ortho-Hexynylbenzoates and Its Application in Synthesis of Acremomannolipin A

Remarkably stable chelating bis-N-heterocyclic carbene adducts of phosphorus(I) cations

Regioselectivity in the Au-catalyzed hydration and hydroalkoxylation of alkynes

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5-exo/6-endodig Selectivity, Methodology and Scope

Silver salts and DBU cooperatively catalyzed nucleophilic addition/cyclization of propargylic alcohols with trifluoromethyl ketones

Gold-catalysed glycosylation reaction using an easily accessible leaving group

Direct access to pyrido/pyrrolo[2,1-b]quinazolin-9(1H)-ones through silver-mediated intramolecular alkyne hydroamination reactions

Mar 29-Apr 4



Synthesis of the Spirastrellolide A, B/C Spiroketal: Enabling Solutions for Problematic Au(I)-Catalyzed Spiroketalizations

Sequential O–H/C–H Bond Insertion of Phenols Initiated by the Gold(I)-Catalyzed Cyclization of 1-Bromo-1,5-enynes

Construction of β-Mannosidic Bonds via Gold(I)-Catalyzed Glycosylations with Mannopyranosyl ortho-Hexynylbenzoates and Its Application in Synthesis of Acremomannolipin A

Divergence in the Reactivity between Amine- and Phosphine-Catalyzed Cycloaddition Reactions of Allenoates with Enynals: One-Pot Gold-Catalyzed Synthesis of Trisubstituted Benzofurans from the [3 + 2] Cycloadduct via 1,2-Alkyl Migration and Dehydrogenation

Gold(I)-Catalyzed Selective Heterocyclization of Propargylic Thioureas: Mechanistic Study of Competitive Gold-Activation Mode

A Highly Efficient Gold-Catalyzed Photoredox α-C(sp3)-H Alkynylation of Tertiary Aliphatic Amines with Sunlight

Silver Hexafluoroantimonate-Catalyzed Direct α-Alkylation of Unactivated Ketones

Mar 15-Mar 22


Hongyi Chen

Design of Pyrazolo-pyrrolo-pyrazines and Pyrazolo-pyrrolo-diazepines via AuCl3-Catalyzed and NaH-Supported Cyclization of N-Propargyl Pyrazoles

Theoretical Insight into the Mechanism of Gold(I)-Catalyzed Rearrangement of 2-Propargyl 2H-Azirines to Pyridines

Regioselective Hydration of Terminal Alkynes Catalyzed by a Neutral Gold(I) Complex [(IPr)AuCl] and One-Pot Synthesis of Optically Active Secondary Alcohols from Terminal Alkynes by the Combination of [(IPr)AuCl] and Cp*RhCl[(R,R)-TsDPEN]

Silver-catalyzed asymmetric Michael addition of azomethine ylide to arylidene diphosphonates using ThioClickFerrophos ligand

Silver-Mediated Decarboxylative Fluorination of Paraconic Acids: A Direct Entry to β-Fluorinated γ-Butyrolactones

Gold(I)-Catalyzed Decarboxylation of Propargyl Carbonates: Reactivity Reversal of the Gold Catalyst from π-Lewis Acidity to σ-Lewis Acidity

Mar 8-Mar 14



Zhou Xu

Direct Construction of Fused Indoles by Gold-Catalyzed Cascade Cyclization of Conjugated Diynes

Platinum-Catalyzed Domino Reaction with Benziodoxole Reagents for Accessing Benzene-Alkynylated Indoles

Asymmetric Synthesis of Optically Active Spiroacetals from Alkynyl Glycols Catalyzed by Gold Complex/Brønsted acid Binary System

Gold(I)-catalyzed [2 + 2 + 2] cycloaddition of allenamides, alkenes and aldehydes: a straightforward approach to tetrahydropyrans

Mar 1-Mar 7



Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

The Reactivity of 4-Hydroxy- and 4-Silyloxy-1,5-allenynes with Homogeneous Gold(I) Catalysts

Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates

Anomalous ligand effect in gold(I)-catalyzed intramolecular hydroamination of alkynes

Tandem Gold/Silver-Catalyzed Cycloaddition/Hydroarylation of 7-Aryl-1,6-Enynes to Form 6,6-Diarylbicyclo[3.2.0]heptanes

Feb 22- Feb 28



Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles

Total Synthesis of an Exceptional Brominated 4-Pyrone Derivative of Algal Origin: An Exercise in Gold Catalysis and Alkyne Metathesis

Oxidative Addition of Carbon–Carbon Bonds to Gold

Remote Amide-Controlled Gold-Catalyzed Stereoselective Hydro-heteroarylation of Acrylamides: Access to Pyrido[3,4-b]indoles

Ligand- and Brønsted acid/base-switchable reaction pathways in gold(I)-catalyzed cycloisomerizations of allenoic acids

Gold-catalyzed allene cycloisomerization for pyrrole synthesis: towards highly fluorinated BODIPY dyes

Diversely Substituted Indoloazepinones and Indoloazocinones: A Post-Ugi Gold-Catalyzed Regioselective Carbocyclization Approach

Gold(I)-Catalyzed Oriented Assembly of Dihydropyridines

Gold-Catalyzed, SN1-Type Reaction of Alcohols to Afford Ethers and Cbz-Protected Amines

Feb 16 – Feb 22


Three-Component Domino Process for the Pyrrolizine Skeleton via [3 + 2]-Cycloaddition-Enamine Cyclization Triggered by a Gold Catalyst

Platinum-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Phenols

Gold-Catalyzed Cycloaddition Reactions of Ethyl Diazoacetate, Nitrosoarenes, and Vinyldiazo Carbonyl Compounds: Synthesis of Isoxazolidine and Benzo[b]azepine Derivatives

Gold-Catalyzed Tandem Hydroamination/Formal Aza-Diels-Alder Reaction of Homopropargyl Amino Esters: A Combined Computational and Experimental Mechanistic Study

Gold Acetonyl Complexes: From Side-Products to Valuable Synthons

Synthesis of (-)-Cryptopleurine by Combining Gold(I) Catalysis with a Free Radical Cyclization

Feb 9- Feb 15



Gold(I)/Copper(II)-Cocatalyzed Tandem Cyclization/Semipinacol Reaction: Construction of 6-Aza/Oxa-Spiro[4.5]decane Skeletons and Formal Synthesis of (±)-Halichlorine

Gold-Catalyzed Carbenoid Transfer Reactions of Diynes – Pinacol Rearrangement versus Retro-Buchner Reaction

Feb 2-Feb 8


Zhou Xu

Gold(I)-Catalyzed Asymmetric Desymmetrization of meso-Alkynyl Diols and Kinetic Resolution of the Corresponding dl-Diols: Effects of Celite Filtration and Silver Salts

Jan 26-Feb 1



Platinum-Catalyzed Tandem Cyclization Reaction to Multiply Substituted Indolines under Microwave-Assisted Conditions

Gold(I)-catalyzed asymmetric [3 + 2]-cycloadditions of γ-1-ethoxyethoxy-propiolates and aldehydes

Jan 18-24th



Dual Gold Catalysis: A Novel Synthesis of Bicyclic and Tricyclic Pyrroles from N-Propargyl Ynamides

Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes

Intramolecular C[BOND]H Activation through Gold(I)-Catalyzed Reaction of Iodoalkynes

Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond

Jan 4-10th



Silver-Mediated Radical Cyclization of Alkynoates and α-Keto Acids Leading to Coumarins via Cascade Double C–C Bond Formation

Platinum-catalyzed allylation of carbon electrophiles with alkenylsilanes

Exploratory studies toward a synthesis of flavaglines. A novel access to a highly substituted cyclopentenone intermediate

Synthesis of Oxazocenones via Gold(I)-Catalyzed 8-Endo-Dig Hydroalkoxylation of Alkynamides

Ambient Synthesis of Dienals via Triazole–Gold and Amine Catalysis Relay

Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization

Dec 29th-Jan 3th



Zhou Xu

Synthesis of 2-Spiropseudoindoxyls via an Intramolecular Nitroalkyne Redox–Dipolar Cycloaddition Cascade

Combining silver- and organocatalysis: an enantioselective sequential catalytic approach towards pyrano-annulated pyrazoles

Gold(I)-Catalyzed Cycloisomerizations and Alkoxycyclizations of ortho-(Alkynyl)styrenes

Gold-Catalyzed Hydroarylating Cyclization of 1,2-Bis(2-iodoethynyl)benzenes

Dec 14-28th



Synthesis of 5,6-Dihydropyrazolo[1,5-c]quinazolines through Gold-Catalyzed Chemoselective Bicyclization of N-Propargylic Sulfonylhydrazones

Regioselective Gold-Catalyzed Oxidative C–N Bond Formation

Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

Silver-Catalyzed C(sp2)–H Functionalization/C–O Cyclization Reaction at Room Temperature

Efficient and practical synthesis of enantioenriched 2,3-dihydropyrroles through gold-catalyzed anti-Markovnikov hydroamination of chiral homopropargyl sulfonamides

Exploratory studies toward a synthesis of flavaglines. A novel access to a highly substituted cyclopentenone intermediate

Platinum-catalyzed allylation of carbon electrophiles with alkenylsilanes

Synthesis of 2-acyl-1-naphthols by gold-catalyzed oxidative cyclization of 2-alkenylphenyl alkynyl ketones

Synthesis and Characterization of Gold(I) Complexes of Dibenzotropylidene-Functionalized NHC Ligands (Trop-NHCs)

Reactivity of Gold Hydrides: O2 Insertion into the Au–H Bond

Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude

Gold-Catalyzed Intermolecular Anti-Markovnikov Hydroamination of Alkylidenecyclopropanes

Dec 14.



Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination

Silver-Mediated Selective Oxidative Cross-Coupling between C–H/P–H: A Strategy to Construct Alkynyl(diaryl)phosphine Oxide

Silver(I)-Catalyzed Ring-Contractive Rearrangement: A New Entry to 5-Alkylidene-2-cyclopentenones

CO-Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated through Water Addition to Gold Vinylidenes

Gold-Catalyzed Intermolecular Nitrene Transfer from 2H-Azirines to Ynamides: A Direct Approach to Polysubstituted Pyrroles

Supported Gold Nanoparticle-Catalyzed Hydration of Alkynes under Basic Conditions

Dec 7.


Zhou Xu

Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles

Synthesis of β-Ketophosphonates via AgNO3-Catalyzed Hydration of Alkynylphosphonates: A Rate-enhancement Effect of Methanol

Gold(I)-catalysed synthesis of cyclic sulfamidates: current scope, stereochemistry and competing ene-allene cycloisomerisation

Gold-Catalyzed Synthesis of 3-Acylimidazo[1,2-a]pyridines via Carbene Oxidation


Nov. 30



Coinage Metals Binding as Main Group Elements: Structure and Bonding of the Carbene Complexes [TM(cAAC)2] and [TM(cAAC)2]+ (TM = Cu, Ag, Au)

Tuning the Reactivity of Isocyano Group: Synthesis of Imidazoles and Imidazoliums from Propargylamines and Isonitriles in the Presence of Multiple Catalysts

Enantioselective Oxidative Gold Catalysis Enabled by a Designed Chiral P,N-Bidentate Ligand

Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds

Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

Metal controlled regioselectivity in the cyclometallation of 2-(1-naphthyl)-pyridine

Concise synthesis of the tricyclic skeleton of crotobarin and crotogoudin via a gold-catalyzed cycloisomerization reaction

Gold superacid-catalyzed preparation of benzo[c]thiophenes

Formal [4+2] Reaction between 1,3-Diynes and Pyrroles: Gold(I)-Catalyzed Indole Synthesis by Double Hydroarylation

Gold(I)/Chiral Brønsted Acid Catalyzed Enantioselective Hydroamination–Hydroarylation of Alkynes: The Effect of a Remote Hydroxyl Group on the Reactivity and Enantioselectivity

Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

Gold-catalyzed highly efficient benzylation of alcohols with N-Cbz-N-benzyl-propargylamine

Atom-economic generation of gold carbenes: gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles

A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis

Nov. 23



Asymmetric Hetero-Diels–Alder Reaction of Diazenes Catalyzed by Chiral Silver Phosphate: Water Participates in the Catalysis and Stereocontrol

Modular Synthesis of Sulfonyl Benzoheteroles by Silver-Catalyzed Heteroaromatization of Propargylic Alcohols with p-Toluenesulfonylmethyl Isocyanide (TosMIC): Dual Roles of TosMIC

Gold(I)-Catalyzed Intermolecular Cycloaddition of Allenamides with α,β-Unsaturated Hydrazones: Efficient Access to Highly Substituted Cyclobutanes

Gold(I)-Catalyzed 1,4- and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations

Gold-Catalyzed Spiro-N,O-Ketal Synthesis

Nov. 9

Efficient Diastereo- and Enantioselective Synthesis of exo-Nitroprolinates by 1,3-Dipolar Cycloadditions Catalyzed by Chiral Phosphoramidite⋅Silver(I) Complexes

Regio- and Diastereoselective Cycloaddition of Azomethine Ylides with Benzylidenemalononitrile: Assembly of a New Set of Multisubstituted 4,4-Dicyanopyrrolidine-2-carboxylate and Nornicotine Scaffolds

Gold(I)-catalysed synthesis of a furan analogue of thiamine pyrophosphate

Gold-Catalyzed Dearomative Spirocyclization of Aryl Alkynoate Esters

A Unique 1,2-Acyl Migration for the Construction of Quaternary Carbon by Visible Light Irradiation of Platinum(II) Polypyridyl Complex and Molecular Oxygen

Platinum(II) Olefin Hydroarylation Catalysts: Tuning Selectivity for the anti-Markovnikov Product

Nov. 3


Zhou Xu

Stereoselective Synthesis of α-Trifluoromethyl Enones by AuI/CuI-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates

Sequential multicomponent synthesis of α-ketoimides, from acyl chlorides, isocyanides, and silver salts of carboxylic acids

Synthesis of Highly Substituted γ-Butyrolactones by a Gold-Catalyzed Cascade Reaction of Benzyl Esters.

Silver-mediated synthesis of indolizines via oxidative C–H functionalization and 5-endodig cyclization

Synthesis of the Tricyclic Core in Stemonamine Alkaloids via One-Pot Gold(I)-Catalyzed Cyclization and Schmidt Rearrangement: Formal Synthesis of (±)-Stemonamine.

Oct. 26



One-Pot Synthesis of 2,5-Dihydropyrroles from Terminal Alkynes, Azides, and Propargylic Alcohols by Relay Actions of Copper, Rhodium, and Gold

The ortho-Substituent Effect on the Ag-Catalysed Decarboxylation of Benzoic Acids

Efficient silver-catalyzed direct sulfenylation and selenylation of rich arenes

Silver(I)-catalyzed annulation for the regioselective synthesis of N-imino-γ-carbolinium ylides from hydrazones of indole-3-carbonyl derivatives and propargylic alcohols

Synthesis of Au(I) Trifluoromethyl Complexes. Oxidation to Au(III) and Reductive Elimination of Halotrifluoromethanes

A Facile and General Approach to 3-((Trifluoromethyl)thio)-4H-chromen-4-one

Expedient Synthesis of Complex γ-Butyrolactones from 5-(1-Arylalkylidene) Meldrum’s Acids via Sequential Conjugate Alkynylation/Ag(I)-Catalyzed Lactonization

Oct. 19



Gold-Catalyzed Regioselective Meyer–Schuster Rearrangement and Ring Expansion Cascade Leading to α-Hydroxy-α-vinylcyclopentanones

Silver(I)-Catalyzed Annulation for the Regioselective Synthesis of N-Imino-γ-Carbolinium Ylides from Hydrazones of Indole-3-Carbonyl Derivatives and Propargylic Alcohols

Gold-Catalyzed C–H Bond Functionalization of Metallocenes: Synthesis of Densely Functionalized Ferrocene Derivatives

An efficient homogeneous gold(I) catalyst for N-alkylation of amines with alcohols by hydrogen autotransfer

Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives

One-Pot Synthesis of Keto Thioethers by Palladium/Gold-Catalyzed Click and Pinacol Reactions

Oct. 12



Computational Characterization of the Mechanism for Coinage-Metal-Catalyzed Carboxylation of Terminal Alkynes

Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus-aluminum ligand to gold

Dual Gold Catalysis: Synthesis of Polycyclic Compounds via C-H Insertion of Gold Vinylidenes

Revised Role of Selectfluor in Homogeneous Au-Catalyzed Oxidative C-O Bond Formations

Synthesis of Quinuclidines by Intramolecular Silver-Catalysed Amine Additions to Alkynes

Gold-catalyzed Carboalkoxylations of 2-Ethynylbenzyl Ethers to Form 1- and 3-Substituted 2-Methoxy-1-Hindenes: Brønsted Acid Versus Gold Catalysis

Oct. 05



Designer HF-Based Fluorination Reagent: Highly Regioselective Synthesis of Fluoroalkenes and gem-Difluoromethylene Compounds from Alkynes

Controlling Regiochemistry in the Gold-Catalyzed Synthesis of Unsaturated Spiroketals

Efficient Silver-Catalyzed Direct Sulfenylation and Selenylation of Rich Arenes

Synthesis of 2-trifluoromethylpyrazolo[5,1-a]isoquinolines via silver triflate-catalyzed or electrophile-mediated one-pot tandem reaction

Sept. 28



Combining Silver Catalysis and Organocatalysis: A Sequential Michael Addition/Hydroalkoxylation One-Pot Approach to Annulated Coumarins

Gold-Catalyzed Tandem Cycloisomerization/Functionalization of in Situ Generated α-Oxo Gold Carbenes in Water

Gold(I)-Catalyzed Highly Diastereo- and Enantioselective Alkyne Oxidation/Cyclopropanation of 1,6-Enynes

Unexpected Anion Effect in the Alkoxylation of Alkynes Catalyzed by N-Heterocyclic Carbene (NHC) Cationic Gold Complexes

A General Diversified Synthesis of Carbazoles and the First Synthesis of Karapinchamine A

Synthesis of Furans through Silver-Catalyzed Propargyl–Claisen Rearrangement Followed by Cyclocondensation

Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates

Sep. 21



Mechanistic Studies on the Rearrangement of 1-Alkenyl-2-alkynylcyclopropanes: From Allylic Gold(I) Cations to Stable Carbocations

Au(I)/Ag(I)-catalyzed annulation of sugar aldehyde tethered with 3-phenylprop-2-yn-1-yl ether with aryl amines for the pyrano[4,3-b]quinoline derivatives

Silver-promoted trans-hydrofluorination of ynamides: a regio- and stereoselective approach to (Z)-α-fluoroenamides

Understanding the Mechanisms of Unusually Fast H[BOND]H, C[BOND]H, and C[BOND]C Bond Reductive Eliminations from Gold(III) Complexes

Quantitative Description of Structural Effects on the Stability of Gold(I) Carbenes

Synthesis of Highly Substituted N-(Furan-3-ylmethylene)benzenesulfonamides by a Gold(I)-Catalyzed Oxidation/1,2-Alkynyl Migration/Cyclization Cascade

Silver-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Ynol Ethers

Gold-Catalyzed Hydroarylation of Alkenes with Dialkylanilines

Sep. 14



Gold-Catalyzed Oxidative Cross-Coupling of Terminal Alkynes: Selective Synthesis of Unsymmetrical 1,3-Diynes

1,2-Boryl Migration Empowers Regiodivergent Synthesis of Borylated Furans

Gold(I) Catalysis at Extreme Concentrations Inside Self-Assembled Nanospheres

Introducing deep eutectic solvents as biorenewable media for Au(I)-catalysed cycloisomerisation of ?-alkynoic acids: an unprecedented catalytic system

Aerobic oxygenative cleavage of electron deficient C–C triple bonds in the gold-catalyzed cyclization of 1,6-enynes

Gold-Catalyzed Asymmetric Allylic Substitution of Free Alcohols: An Enantioselective Approach to Chiral Chromans with Quaternary Stereocenters for the Synthesis of Vitamin E and Analogues

Selectivity, Compatibility, Downstream Functionalization, and Silver Effect in the Gold and Palladium Dual-Catalytic Synthesis of Lactones


Sep. 7



Axially Chiral Allenyl Gold Complexes

Tandem Gold Self-Relay Catalysis for the Synthesis of 2,3-Dihydropyridin-4(1 H)-ones: Combination of σ and π Lewis Acid Properties of Gold Salts

Enantioselective Intramolecular Hydroamination of Unactivated Alkenes Catalyzed by Mono- and Bis(gold) Phosphine Complexes

Aminosulfonylation of Arenes, Sulfur Dioxide, and Hydrazines Cocatalyzed by Gold(III) Chloride and Palladium Acetate

Asymmetric Alkynylative Ring Opening Reaction of Oxabenzonorbornadienes Promoted by Palladium/Silver Cocatalytic System

Silver-Catalyzed Transformation of Propargylic Amine N-Oxides to Enones and Acyloxy Ketones via Isoxazolinium Intermediates

Aug. 31



Synthesis of Substituted Azulenes via Pt(II)-Catalyzed Ring-Expanding Cycloisomerization

Silver-Mediated Decarboxylative C–S Cross-Coupling of Aliphatic Carboxylic Acids under Mild Conditions

Synthesis of spiroaminals by bimetallic Au/Sc relay catalysis: TMS as a traceless controlling group

Cyclometalated gold(III) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: divergent synthesis of indolizines and pyrroles

[Au]/[Pd] Multicatalytic Processes: Direct One-Pot Access to Benzo[c]chromenes and Benzo[b]furans

Telluroether to Telluroxide Conversion in the Coordination Sphere of a Metal: Oxidation-Induced Umpolung of a Te–Au Bond

Reactivity of Organogold Compounds with B(C6F5)3: Gold–Boron Transmetalation via σ-B/π-Au Species

Template Synthesis of Tetracarbene Platinum(II) Complexes with Five- and Six-Membered-Ring N-Heterocyclic Carbenes

Electrostatic control of regioselectivity via ion pairing in a Au(I)-catalyzed rearrangement

Aug. 24



Silver-Catalyzed Domino Hydroarylation/Cycloisomerization Reactions of ortho-Alkynylbenzaldehydes: An Entry to Functionalized Isochromene Derivatives

Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: divergent synthesis of indolizines and pyrroles

Regioselective Dihalohydration Reactions of Propargylic Alcohols: Gold-Catalyzed and Non-Catalyzed Reactions†

Gold-catalyzed oxidation of propargylic ethers with internal C-C triple bonds: Impressive regioselectivity enabled by inductive effect

Generation of 1-amino-isoquinoline-N-oxides via a silver(I) and copper(I) co-catalyzed reaction of 2-alkynylbenzaldoxime with secondary amines

Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules

Silver-Catalyzed Transformation of Propargylic Amine N-Oxides to Enones and Acyloxy Ketones via Isoxazolinium Intermediates

Enantioselective Intramolecular Hydroamination of Unactivated Alkenes Catalyzed by Mono- and Bis(gold) Phosphine Complexes

Aug. 17



Direct Synthesis of α-Trifluoromethyl Ketone from (Hetero)arylacetylene: Design, Intermediate Trapping, and Mechanistic Investigations

The Au(I) Catalyzed Activation of Allenamides and Their Subsequent Transformation into Chromanes: A Method for the Regiocontrolled Addition to the α- and γ-Positions of the Allene Unit

NHC–AuCl/Selectfluor: A Highly Efficient Catalytic System for Carbene-Transfer Reactions

Synthesis of Pyrrolo-/Indolo[1,2-a]quinolines and Naphtho[2,1-b]thiophenes from gem-Dibromovinyls and Sulphonamides

Catalytic Generation of Vinylthionium Ions. (4 + 3)-Cycloadditions and Friedel–Crafts Alkylations

Silver(I) and Copper(I) Cocatalyzed Tandem Reaction of 2-Alkynylbenzaldoximes with Aldehydes or Alcohols: Approach to 4-Carboxylated Isoquinolines

Asymmetric Gold-Catalyzed Lactonizations in Water at Room Temperature

Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines

When Gold Meets Chiral Brønsted Acid Catalysts: Extending the Boundaries of Enantioselective Gold Catalysis

Gold-Catalyzed Cycloisomerization of 1,6,8-Dienyne Carbonates and Esters to cis-Cyclohepta-4,8-diene-Fused Pyrrolidines

Phosphathiahelicenes: Synthesis and Uses in Enantioselective Gold Catalysis

Silver-mediated C–H bond functionalization: one-pot to construct substituted indolizines from 2-alkylazaarenes with alkynes

A tandem reaction of 2-alkynylbenzaldoximes with cyclic ethers co-catalyzed by silver(I) triflate and copper(II) acetate

Silver mediated direct C–H arylation of 3-bromoisothiazole-5-carbonitrile

Aug. 10



Role of Gold(I) α-Oxo Carbenes in the Oxidation Reactions of Alkynes Catalyzed by Gold(I) Complexes

Silver-Catalyzed Reaction of Enynals with Alkenes: A Tandem 1,3-Dipolar Cycloaddition/Cyclopropanation

Silver-Catalyzed Radical Tandem Cyclization: An Approach to Direct Synthesis of 3-Acyl-4-arylquinolin-2(1H)-ones

[Silver(I)(Pyridine-Containing Ligand)] Complexes As Unusual Catalysts for A3-Coupling Reactions

Kinetics and Mechanism of the Racemization of Aryl Allenes Catalyzed by Cationic Gold(I) Phosphine Complexes

Cyclobutene Formation in PtCl2-Catalyzed Cycloisomerizations of Heteroatom-Tethered 1,6-Enynes

Gold-Catalyzed Carbocyclization of Phenols with a Terminal Alkyne via an Intramolecular ipso-Friedel–Crafts Alkenylation

Aug. 3



Asymmetric Synthesis of First Generation Molecular Motors

Silver-Catalyzed Tandem Hydroamination/Hydroarylation of 1-(2-Allylamino)phenyl-4-hydroxy-but-2-yn-1-ones to 1′-Allylspiro[indene-1,2′-indolin]-3′-ones

Gold(I)-Catalyzed Synthesis of Optically Active 1,4-Oxazepan-7-ones

A direct approach to β-keto sulfones via AgNO3/K2S2O8 catalyzed aerobic oxysulfonylation of alkenes in aqueous medium

Gold-catalyzed intermolecular oxidation of o-alkynylbiaryls: an easy and practical access to functionalized fluorenes

Gold(I)-Catalysed Direct Thioetherifications Using Allylic Alcohols: an Experimental and Computational Study

Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G

Synthesis of Pyrrolidines and Pyrroles by Tandem Amination/Cyanation/Alkylation and Amination/Oxidation Sequences

Aminosulfonylation of Arenes, Sulfur Dioxide, and Hydrazines Cocatalyzed by Gold(III) Chloride and Palladium Acetate

July 27



Chemoselective Carbophilic Addition of α-Diazoesters through Ligand-Controlled Gold Catalysis

Gold-Catalyzed Carbocyclization of Phenols with a Terminal Alkyne via an Intramolecular ipso-Friedel–Crafts Alkenylation

Silver-Catalyzed Radical Tandem Cyclization: An Approach to Direct Synthesis of 3-Acyl-4-arylquinolin-2(1H)-ones

Gold(I)-Catalyzed Synthesis of Optically Active 1,4-Oxazepan-7-ones

July 20



Synthesis and characterization of fullerophosphine–Au(I) complexes

Synthesis and characterisation of Au(I)-(ITent) complexes

3-Halotetrahydropyran-4-one Derivatives from Homopropargyl Acetal

Gold- and Silver-Catalyzed [4+2]Cycloadditions of Ynamides with Oxetanes and Azetidines

July 13



Asymmetric Annulation of 3-Alkynylacrylaldehydes with Styrene-Type Olefins by Synergetic Relay Catalysis from AgOAc and Chiral Phosphoric Acid

A Cyclization–Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes

Silver(I) and gold(I)-promoted synthesis of alkylidene lactones and 2H-chromenes from salicylic and anthranilic acid derivatives

Taming Gold(I)–Counterion Interplay in the De-aromatization of Indoles with Allenamides

June 22-July 06



Gold-Catalyzed 1,3-Transposition of Ynones

A Gold Exchange: A Mechanistic Study of a Reversible, Formal Ethylene Insertion into a Gold(III)–Oxygen Bond

A Mechanistic Change Results in 100 Times Faster CH Functionalization for Ethane versus Methane by a Homogeneous Pt Catalyst

Gold-Catalyzed [1,5]-Hydride Shift onto Unactivated Alkynes To Trigger an Intermolecular Diels–Alder Reaction

General Silver-Catalyzed Hydroazidation of Terminal Alkynes by Combining TMS-N3 and H2O: Synthesis of Vinyl Azides

Regiocontrolled Gold-Catalyzed [2+2+2] Cycloadditions of Ynamides with Two Discrete Nitriles to Construct 4-Aminopyrimidine Cores

Synthesis, Structure, and Reactivity of a Gold Carbenoid Complex That Lacks Heteroatom Stabilization

Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts

Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides

June 15



Coinage-Metal Mediated Ring Opening of cis-1,2-Dimethoxycyclopropane: Trends from the Gold, Copper, and Silver Fischer Carbene Bond Strength

Cationic Gold Catalyst Poisoning and Reactivation

Selective Aerobic Oxidation of Alcohols to Aldehydes, Carboxylic Acids, and Imines Catalyzed by a Ag-NHC Complex

Isolation of a Non-Heteroatom-Stabilized Gold–Carbene Complex

Total Synthesis and Configurational Validation of (+)-Violapyrone C

Synthesis of Fully Substituted 3-Formyl-4-iodofurans via a Gold(I)-Catalyzed Oxidation/1,2-Alkynyl Migration/Cyclization/Iodination Cascade

One-Pot Synthesis of Multi-Substituted 4-Pyrones by a Gold- Catalyzed Cascade of Wolff Rearrangement/[4+2] Cycloaddition/ Elimination Reactions

June 8



Mild Gold-Catalyzed Aerobic Dehydrogenative Coupling of Amines and Phenylglyoxal Derivatives

Mono- vs. Dinuclear Gold-Catalyzed Intermolecular Hydroamidation

Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis

Gold-Catalyzed C(sp3)-H/C(sp)-H Coupling/Cyclization/Oxidative Alkynylation Sequence: A Powerful Strategy for the Synthesis of 3-Alkynyl Polysubstituted Furans

May 25



Electrophilic Pt(II) Complexes: Precision Instruments for the Initiation of Transformations Mediated by the Cation–Olefin Reaction

Gold-catalyzed C(sp3)–H bond functionalization

Access to 1,2-Dihydroisoquinolines through Gold-Catalyzed Formal [4+2] Cycloaddition

Cationic gold(I)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity

May 18


Photoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination

Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media

Silver-mediated radical cyclization: construction of Δ2-isoxazolines from α-halo ketoximes and 1,3-dicarbonyl compounds

May 4



Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

Gold-Catalyzed Allylation of Aryl Boronic Acids: Accessing Cross-Coupling Reactivity with Gold

April 27


ABC → ABCE/D Based Approaches to the Pentacyclic Ring System of the Vinca Alkaloids Using Intramolecular Hetero-[2+2]cycloaddition and Gold(I)-catalyzed 6-Endo-Dig Cyclisation Protocols

Structure of Silver–N-Heterocyclic Carbenes in Solution: Evidence of Equilibration in DMSO at Very Different Time Scales by 1H NMR Experiments

Synthesis, Characterization, and Catalytic Activity of Alcohol-Functionalized NHC Gold(I/III) Complexes

Gold(I) N-heterocyclic carbene complexes with an “activable” ester moiety: Possible biological applications

Gold(I)-, Palladium(II)-, Platinum(II)-, and Mercury(II)-Catalysed Spirocyclization of 1,3-Enynediols: Reaction Scope

Gold-Catalyzed 5-endodig Cyclization of 2-[(2-Aminophenyl)ethynyl]phenylamine with Ketones for the Synthesis of Spiroindolone and Indolo[3,2-c]quinolone Scaffolds

Gold-Catalyzed 1,2-Oxoarylations of Nitriles with Pyridine-Derived Oxides†

Highly Diastereo- and Enantioselective Silver-Catalyzed Double [3+2] Cyclization of α-Imino Esters with Isocyanoacetate†

Silver-Catalyzed Oxidative Activation of Benzylic C-H Bonds for the Synthesis of Difluoromethylated Arenes

Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion†

A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

Room-Temperature Hydrohydrazination of Terminal Alkynes Catalyzed by Saturated Abnormal N-Heterocyclic Carbene–Gold(I) Complexes

Highly Efficient Gold-Catalyzed Synthesis of Dibenzocycloheptatrienes

Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes

Novel Method of Tetramic Acid Synthesis: Silver-Catalyzed Carbon Dioxide Incorporation into Propargylic Amine and Intramolecular Rearrangement

April 20


Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion

Ambient Intermolecular [2 + 2] Cycloaddition: An Example of Carbophilicity and Oxophilicity Competition in Au/Ag Catalysis

Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes

Gold-Catalyzed 5-endodig Cyclization of 2-[(2-Aminophenyl)ethynyl]phenylamine with Ketones for the Synthesis of Spiroindolone and Indolo[3,2-c]quinolone Scaffolds

A Gold-Catalysed Fully Intermolecular Oxidation and Sulfur-Ylide Formation Sequence on Ynamides Synergistic Gold(I)/Trimethylsilyl Catalysis: Efficient Alkynylation of N,O-Acetals and Related Pro-Electrophiles

April 13

Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-fluoropyridines with Arylamines

Synthesis of Cyclic Amine Boranes through Triazole-Gold(I)-Catalyzed Alkyne Hydroboration

Gold-Catalyzed Synthesis of Functionalized Pyridines by Using 2H-Azirines as Synthetic Equivalents of Alkenyl Nitrenes

Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction

Gold(I)-, Palladium(II)-, Platinum(II)-, and Mercury(II)-Catalysed Spirocyclization of 1,3-Enynediols: Reaction Scope

April 6

Enantioselective Synthesis and Enhanced Circularly Polarized Luminescence of S-Shaped Double Azahelicenes

C-H Bond Functionalization through Intramolecular Hydride Transfer

High Yielding Synthesis of Carboranes Under Mild Reaction Conditions Using a Homogeneous Silver(I) Catalyst: Direct Evidence of a Bimetallic Intermediate

Gold(I) as an Artificial Cyclase: Short Stereodivergent Syntheses of (−)-Epiglobulol and (−)-4β,7α- and (−)-4α,7α-Aromadendranediols

Gold-Catalyzed Intermolecular C-S Bond Formation: Efficient Synthesis of α-Substituted Vinyl Sulfones

Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-fluoropyridines with Arylamines

Gold(I)-Catalyzed Intra- and Intermolecular Alkenylations of β-Yne-pyrroles: Facile Formation of Fused Cycloheptapyrroles and Functionalized Pyrroles

Gold-Catalyzed Enantioselective Ring-Expanding Cycloisomerization of Cyclopropylidene Bearing 1,5-Enynes

Stereoselective tandem synthesis of oxazolo-fused pyrroloquinolines from o-alkynylaldehydes via Ag(I)-catalyzed regioselective 5-exo-dig ring closure

Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction

Synthesis of Oxindoles through Silver-Catalyzed Trifluoromethylation–, Difluoromethylation– and Arylsulfonylation–Cyclization Reaction of N-Arylacrylamides

March 30th


Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions

Pigment–Acceptor–Catalyst Triads for Photochemical Hydrogen Evolution

Silver(I)-Catalyzed Hydroazidation of Ethynyl Carbinols: Synthesis of 2-Azidoallyl Alcohols

Expanded-Ring N-Heterocyclic Carbenes Efficiently Stabilize Gold(I) Cations, Leading to High Activity in π-Acid-Catalyzed Cyclizations

Rollover-Assisted C(sp2)-C(sp3) Bond FormationA gold-catalysed imine–propargylamine cascade sequence: synthesis of 3-substituted-2,5-dimethylpyrazines and the reaction mechanism

Oxidative Addition of Propargyl Halides, Chloroacetonitrile, and Ethyl Chloroacetate to a Dimethylplatinum(II) Complex: Kinetic and DFT Studies

Experimental and Theoretical Studies on the Platinum-Mediated Selective C(sp)–Si Bond Cleavage of Alkynylsilanes

Mechanistic Understanding of a Silver Pyridylpyrrolide as a Catalyst for 3 + 2 Cyclization of a Nitrile with Diazo Ester

One-Step Synthesis of Methanesulfonyloxymethyl Ketones via Gold-Catalyzed Oxidation of Terminal Alkynes: A Combination of Ligand and Counter Anion Enables High Efficiency and a One-Pot Synthesis of 2,4-Disubstituted Thiazoles

Mar 23

1,2-Selective Hydrosilylation of Conjugated Dienes

Arylnitration of alkenes by nitration/C–H functionalization cascade using AgNO3 and HOAc

Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

A Highly Efficient and Broadly Applicable Cationic Gold Catalyst

A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions

Structure of a Reactive Gold Carbenoid

Gold(I)-Catalyzed Hydration of Alkynylphosphonates: Efficient Access to β-Ketophosphonates

Silver Triflate-Catalyzed Cyclization of 2-Amino-6-propargyl- amineazines Leading to Iminoimidazoazines

Mar 16

Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: efficient oxidative union of allylic sulfides and terminal alkynes via C–C bond formation

Gold-catalyzed imine-propargylamine cascade sequence: Synthesis of 3-substituted-2,5-dimethylpyrazines and reaction mechanism

Gold-Catalyzed Tandem Diels-Alder Reactions of Enynals/Enynones with Alkenes: Generation and Trapping of Cyclic o-QDMs

Mar 9

Cyclization of Gold Acetylides: Synthesis of Vinyl Sulfonates via Gold Vinylidene Complexes

Dual Platinum and Pyrrolidine Catalysis in the Direct Alkylation of Allylic Alcohols: Selective Synthesis of Monoallylation Products

Direct Catalytic Enantio- and Diastereoselective Mannich Reaction of Isocyanoacetates and Ketimines

Silver perchlorate induced rearrangement of a tetraarylethene involving an apparent oxygen migration

Formal Total Synthesis of Kendomycin by Way of Alkyne Metathesis/Gold Catalysis

Feb 23 – Mar 2

AgF/TFA-promoted highly efficient synthesis of α-haloketones from haloalkynes

Nanogold-Catalyzed cis-Silaboration of Alkynes with Abnormal Regioselectivity

One-Pot Synthesis of Fused Pyrroles through a Key Gold-Catalysis-Triggered Cascade

A Robust, Well-Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2-Ethynylanilines Leading to Indoles

AgNO3 catalyzed synthesis of 5-substituted-1H-tetrazole via [3+2] cycloaddition of nitriles and sodium azide

Feb 16

A non-diazo strategy to cyclopropanation via oxidatively generated gold carbene: The benefit of a conformationally rigid P,N-bidentate ligand

Zn(II)- or Ag(I)-Catalyzed 1,4-Metathesis Reactions between 3-En-1-ynamides and Nitrosoarenes

Diastereoselective Pt Catalyzed Cycloisomerization of Polyenes to Polycycles

Ground-State Elevation Approach To Suppress Side Reactions in Gold-Sensing Systems Based on Alkyne Activation

Gold-Catalyzed Benzannulation of 5-Hydroxy-3-oxoalk-6-ynoate Esters to o-Phenolic Esters

Silver-catalyzed one-pot cyclization/fluorination of 2-alkynylanilines: highly efficient synthesis of structurally diverse fluorinated indole derivatives

Gold/Acid-Co-catalyzed Direct Microwave-Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides

Alkyne/Alkene/Allene-Induced Disproportionation of Cationic Gold(I) Catalyst

Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions

Azocinoindole Synthesis by a Gold(I)-Catalyzed Ring Expansion of 2-Propargyl-β-Tetrahydrocarboline

Chemosensing of Chloride Based on a Luminescent Platinum(II) NCN Pincer Complex in Aqueous Media

Gold(III) complexes inhibit growth of cisplatin-resistant ovarian cancer in association with upregulation of proapoptotic PMS2 gene

Feb 9 2014

Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtIIMe(OHn)(2–n)– Complex from Theory with Validation from Experiment

Silver-Mediated Radical Aryltrifluoromethylthiolaton of Activated Alkenes

N-Halosuccinimide/AgNO3-Efficient Reagent Systems for One-Step Synthesis of 2-Haloglycals from Glycals: Application in the Synthesis of 2C-Branched Sugars via Heck Coupling Reactions

Bifunctional AgOAc/ThioClickFerrophos complex-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with aryl- and alkylidene malonates

Silver-catalyzed one-pot cyclization/fluorination of 2-alkynylanilines: highly efficient synthesis of structurally diverse fluorinated indole derivatives

Unexpected regio- and chemoselectivity of cationic gold-catalyzed cycloisomerizations of propargylureas: access to tetrasubstituted 3,4-dihydropyrimidin-2(1H)-ones

Jan 26 2014

Gold(I)/(III)-Catalyzed Rearrangement of Divinyl Ketones and Acyloxyalkynyloxiranes into Cyclopentenones

Gold(I)-Catalysed Tandem Cyclisation of Propargyl Acetals and Vinyl Esters

Mild Gold-Catalyzed Three-Component Dehydrogenative Coupling of Terminal Alkynes to Amines and Indole-2-carboxaldehyde

Jan 19 2014

1,3-Cationic Alkylidene Migration of Nonclassical Carbocation: A Density Functional Theory Study on Gold(I)-Catalyzed Cycloisomerization of 1,5-Enynes Containing Cyclopropene Moiety

A New Strategy To Construct Acyclic Nucleosides via Ag(I)-Catalyzed Addition of Pronucleophiles to 9-Allenyl-9H-purines

Leveraging the Micellar Effect: Gold-Catalyzed Dehydrative Cyclizations in Water at Room Temperature

A Non-Diazo Approach to ¦Á-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation

Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex

Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

Quantitative kinetic investigation of triazole¨Cgold(I) complex catalyzed [3,3]-rearrangement of propargyl ester

Gold(I)-catalysed [1,3] O¡úC rearrangement of allenyl ethers

Synthesis of 6-acyl phenanthridines by oxidative radical decarboxylation¨Ccyclization of ¦Á-oxocarboxylates and isocyanides

Reaction Mechanism for the Dual Gold-Catalyzed Synthesis of Dibenzopentalene: A DFT Study

Gold-Catalyzed Cyclization of Diynes: Controlling the Mode of 5-endo versus 6-endo Cyclization¡ªAn Experimental and Theoretical Study by Utilizing Diethynylthiophenes

Jan 12 2014

Development of Catalysts and Ligands for Enantioselective Gold Catalysis

Au(III)-catalyzed regio- and stereoselective tandem synthesis of oxazolo fused naphthyridines and isoquinolines from o-alkynylaldehydes

Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex

ZnII- and AuI-Catalyzed Regioselective Hydrative Oxidations of 3-En-1-ynes with Selectfluor. Realization of 1,4-Dioxo and 1,4-Oxohydroxy Functionalizations

Enhanced Reactivity in Homogeneous Gold Catalysis through Hydrogen Bonding

Gold(I)-catalyzed rearrangement of alkynylaziridine indoles for the synthesis of spiro-tetrahydro-β-carbolines

Au(III)-catalyzed regio- and stereoselective tandem synthesis of oxazolo fused naphthyridines and isoquinolines from o-alkynylaldehydes

Jan 5 2014

Gold(I) Carbenes by Retro-Buchner Reaction: Generation and Fate

Gold(III)-Mediated Contraction of Benzene to Cyclopentadiene: From p-Benziporphyrin to Gold(III) True Tetraarylcarbaporphyrin

Dec 15 2013

Radical Route for the Alkylation of Purine Nucleosides at C6 via Minisci Reaction

Gold-Catalyzed Tandem [3,3]-Propargyl Ester Rearrangement Leading to (E)-1H-Inden-1-ones

Hybrid Gold/Chiral Brønsted Acid Relay Catalysis Allows an Enantioselective Synthesis of (−)-5-epi-Eupomatilone-6

An expedient synthesis of pyrrole-2-phosphonates via direct oxidative phosphorylation and γ-hydroxy-γ-butyrolactams from pyrroles

Gold catalysed synthesis of 3-alkoxyfurans at room temperature

A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

Synthesis of Polycyclic Indole Skeletons by a Gold(I)-Catalyzed Cascade Reaction

Hexanuclear Gold(I) Phosphide Complexes as Platforms for Multiple Redox-Active Ferrocenyl Units

Solvent effects in gold-catalysed A3-coupling reactions

Dehydrogenative Meyer–Schuster-Like Rearrangement: A Gold-Catalyzed Reaction Generating an Alkyne

Gold(I)-Catalyzed Diastereoselective Hydroacylation of Terminal Alkynes with Glyoxals

dec 1 2013Platinum(II)-Catalyzed Asymmetric Ring-Opening Addition of Arylboronic Acids to Oxabenzonorbornadienes

Direct Evidence for Intermolecular Oxidative Addition of σ(Si-Si) Bonds to Gold

Solvent effects in gold-catalysed A3-coupling reactions

C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

New Gold-Catalysed Azidation of Allenes

Competitive Gold-Activation Modes in Terminal Alkynes: An Experimental and Mechanistic Study

Nov 24 2013

Efficient synthesis of propargylamines from terminal alkynes, dichloromethane and tertiary amines over silver catalysts

Gold(I) and Palladium(II) Complexes of 1,3,4-Trisubstituted 1,2,3-Triazol-5-ylidene “Click” Carbenes: Systematic Study of the Electronic and Steric Influence on Catalytic Activity

Interaction of Gold Acetylides with Gold(I) or Silver(I) Cations

Au(III)/TPPMS-Catalyzed Benzylation of Indoles with Benzylic Alcohols in Water

Silver(I)-Mediated Dual Cleavage of C–C and C–O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyl­oxy)butyl 2,2,2-Trifluoroacetate Derivatives

Catalysis by Unsupported Skeletal Gold Catalysts

Atom-Efficient Gold(I)-Chloride-Catalyzed Synthesis of α-Sulfenylated Carbonyl Compounds from Propargylic Alcohols and Aryl Thiols: Substrate Scope and Experimental and Theoretical Mechanistic Investigation


Nov 17 2013

Gold versus Palladium: A Regioselective Cycloisomerization of Aromatic Enynes

Tunable, Chemoselective Amination via Silver Catalysis

Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates

Noninnocent Counterion Effect on the Rearrangements of Cationic Intermediates in a Gold(I)-Catalyzed Alkenylsilylation Reaction

Modular, Gold-Catalyzed Approach to the Synthesis of Lead-like Piperazine Scaffolds

Gold-Catalyzed Synthesis of Tetrazoles from Alkynes by C-C Bond Cleavage

Nov 08 2013

Vicinal Bisheterocyclizations of Alkynes via Nucleophilic Interception of a Catalytic Platinum Carbene

On the Silver Effect and the Formation of Chloride-Bridged Digold Complexes

Electrophilic Difluoro(phenylthio)methylation: Generation, Stability, and Reactivity of α-Fluorocarbocations

Chiral Iminoesters Derived from d-Glyceraldehyde in [3 + 2] Cycloaddition Reactions. Asymmetric Synthesis of a Key Intermediate in the Synthesis of Neuramidinase Inhibitors

Synthesis of 2,8-Dioxabicyclo[3.3.1]nonane Derivatives via a Sequential Knoevenagel Condensation and Hetero-Diels–Alder Reaction in an Aqueous Medium

Palladium and Platinum η2-Disilyne Complexes Bearing an Isolable Dialkyldisilyne as a Ligand

Silver-catalyzed cascade cyclization–stannylation of o-alkynylaniline derivatives with 2-tributylstannylfuran: an efficient synthesis of (3-indolyl)stannanes

Gold(I)-Catalyzed Bis-Alkynylation Reaction of Aromatic Aldehydes with Alkynylsilanes

Nov 01 2013

Intriguing mechanistic labyrinths in gold(I) catalysis

Gold-Catalyzed Tandem Reactions of Methylenecyclopropanes and Vinylidenecyclopropanes

Gold-Catalyzed Rearrangements and Beyond

Flexible and Practical Synthesis of Anthracenes through Gold-Catalyzed Cyclization of o-Alkynyldiarylmethanes

Oct 26 2013

Gold(I)-Catalyzed Bis-Alkynylation Reaction of Aromatic Aldehydes with Alkynylsilanes

Synthesis and Structural Characterization of Water-Soluble Gold(I) N-Heterocyclic Carbene Complexes. An X-ray Absorption Fine Structure Spectroscopy (XAFS) Study

Flexible and Practical Synthesis of Anthracenes through Gold-Catalyzed Cyclization of o-Alkynyldiarylmethanes

Platinum-Catalyzed One-Pot Alkenylation of Aldehydes Using Alkynes and Triethylsilane: Dual Catalysis by Platinum(II) Chloride

Oct 20 2013

Platinum-Catalyzed C–H Arylation of Simple Arenes

Synthesis of Vinylogous Amides by Gold(I)-Catalyzed Cyclization of N-Boc-Protected 6-Alkynyl-3,4-dihydro-2H-pyridines

Silver-Catalyzed Hydrogenation of Aldehydes in Water

Photoredox Transformations with Dimeric Gold Complexes

Intriguing Mechanistic Labyrinths in Gold(I) Catalysis

Gold-Catalyzed Multicomponent Reaction: Facile Strategy for the Synthesis of N-Substituted 1,4-Dihydropyridines by Using Activated Alkynes, Aldehydes, and Methanamine

Oct 13 2013

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving C-C and C-P Bond Formation

Cycloisomerization of 2-Alkynylanilines to Indoles Catalyzed by Carbon-Supported Gold Nanoparticles and Subsequent Homocoupling to 3,3′-Biindoles

Diastereoselective Synthesis of Eight-Membered-Ring Allenes from Propargylic Epoxides and Aldehydes by Silylene Insertion into Carbon–Oxygen Bonds

Gold-Catalyzed Hydroarylation of Aryl Alkynylphosphonates for the Synthesis of Phosphacoumarins

Regioselective synthesis of oxepinones and azepinones by gold-catalyzed cycloisomerizations of functionalyzed cyclopropyl alkynes

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

Oct 06 2013

1,6-Carbene Transfer: Gold-Catalyzed Oxidative Diyne Cyclizations

Gold-Mediated Expulsion of Dinitrogen from Organic Azides

An Efficient Gold-Catalyzed Domino Process for the Construction of Tetracyclic Ketoethers

NHC–Gold(I) Complexes as Effective Catalysts for the Carboxylative Cyclization of Propargylamines with Carbon Dioxide

Sep 29 2013

Synthesis of benzannulated spiroacetals using chiral gold–phosphine complexes and chiral anions

Gold-catalyzed cascade C–C and C–N bond formation: synthesis of polysubstituted indolequinones and pyrroles

Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

A donor–acceptor cyclopropene as a dipole source for a silver(I) catalyzed asymmetric catalytic [3+3]-cycloaddition with nitrones

A durable template for carbosilane dendrimer synthesis

Mechanistic Intricacies of Gold-Catalyzed Intermolecular Cycloadditions between Allenamides and Dienes

A Theoretical DFT-Based and Experimental Study of the Transmetalation Step in Au/Pd-Mediated Cross-Coupling Reactions

Gold(I)-Catalyzed Protodecarboxylation of (Hetero)Aromatic Carboxylic Acids

Sep 17 2013

Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

Gold-Catalyzed Cyclization of 3-(2′-Azidoaryl)-1-arylpropargyl Carbonates or 3-Aryl-1-(2′-azidoaryl)propargyl Carbonates to Produce Quinolines

Gold-Catalyzed Hydration of Haloalkynes to α-Halomethyl Ketones

Gold-Catalyzed Oxidative Rearrangement Involving 1,2-Acyl Migration: Efficient Synthesis of Functionalized Dihydro-γ-Carbolines from α-(2-Indolyl) Propargylic Alcohols and Imines

Gold-Catalyzed Oxidative Cycloadditions to Activate a Quinoline Framework

Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

Constructing Molecular Complexity from Alkynol Derivatives: A Journey from Fischer Carbene Complexes to Tandem Catalysis with Gold and other Carbophilic Lewis Acids

Gold-Catalyzed Intermolecular Oxidation of Terminal Alkynes: Simple and Efficient Synthesis of α-Mesyloxy Ketones

Post Ugi Gold(I)- and Platinum(II)-Catalyzed Alkyne Activation: Synthesis of Diversely Substituted Fused Azepinones and Pyridinones

Straightforward and Highly Efficient Synthesis of α-Acetoxy Ketones through Gold-Catalyzed Intermolecular Oxidation of Terminal Alkynes

Sep 8 2013

Gold(I)-Catalyzed Bis-Alkynylation Reaction of Aromatic Aldehydes with Alkynylsilanes

β- and α-Hydride Abstraction in Gold(I) Alkyl Complexes
Sep 1 2013

Silver/ThioClickFerrophos Complex as an Effective Catalyst for Asymmetric Conjugate Addition of Glycine Imino Ester to Unsaturated Malonates and α-Enones

Gold and BINOL-Phosphoric Acid Catalyzed Enantioselective Hydroamination/N-Sulfonyliminium Cyclization Cascade

Merging Synthesis and Enantioselective Functionalization of Indoles by a Gold-Catalyzed Asymmetric Cascade Reaction

Aug 25 2013Synthesis of Azepine Derivatives by Silver-Catalyzed [5+2] Cycloaddition of γ-Amino Ketones with Alkynes
Aug 11 2013Platinum-Catalyzed Tandem Indole Annulation/Arylation for the Synthesis of Diindolylmethanes and Indolo[3,2-b]carbazoles

Oxidant-Dependent Chemoselectivity in the Gold-Catalyzed Oxidative Cyclizations of 3,4,6,6-Tetrasubstituted 3,5-Dien-1-ynes

Oxidative Trifluoromethylation of Unactivated Olefins: An Efficient and Practical Synthesis of α-Trifluoromethyl-Substituted Ketones

Air-Stable, Dinuclear and Tetranuclear σ,π-Acetylide Gold(I) Complexes and Their Catalytic Implications

A Unique Au–Ag–Au Triangular Motif in a Trimetallic Halonium Dication: Silver Incorporation in a Gold(I) Catalyst

From Ynamides to Highly Substituted Benzo[b]furans: Gold(I)-Catalyzed 5-endo-dig-Cyclization/Rearrangement of Alkylic Oxonium Intermediates

Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media

Gold(I)-Catalyzed Functionalization of Benzhydryl C(sp3)-H Bonds

Aug 4th 2013

Gold-Mediated Synthesis and Functionalization of Chiral Halopyridones

Gold(I)-Catalyzed Benz[c]azepin-4-ol Synthesis by Intermolecular [5 + 2] Cycloaddition

Au-Catalyzed Formation of Functionalized Quinolines from 2-Alkynyl Arylazide Derivatives

Silver-Catalyzed Carboazidation of Arylacrylamides

Efficient Intramolecular Cyclizations of Phenoxyethynyl Diols into Multisubstituted α,β-Unsaturated Lactones

Gold-Catalyzed Oxidative Cyclization of 4-Allenyl-1-ynes with 8-Methylquinoline Oxide

Hingeless Negative Linear Compression in the Mechanochromic Gold Complex [(C6F5Au)2(μ-1,4-diisocyanobenzene)]

Bis-cyclometallated Gold(III) Complexes as Efficient Catalysts for Synthesis of Propargylamines and Alkylated Indoles

Jul 28th 2013

Hydrophenoxylation of Alkynes by Cooperative Gold Catalysis

Regioselective C–H Activation Preceded by Csp2–Csp3 Reductive Elimination from Cyclometalated Platinum(IV) Complexes

Gold-Catalyzed Domino Aminocyclization/1,3-Sulfonyl Migration of N-Substituted N-Sulfonyl-aminobut-3-yn-2-ols to 1-Substituted 3-Sulfonyl-1H-pyrroles

Synthesis of Functionalized Oxazoles via Silver-Catalyzed Cyclization of Propargylamides and Allenylamides

Chemoselectivity Control: Gold(I)-Catalyzed Synthesis of 6,7-Dihydrobenzofuran-4(5H)-ones and Benzofurans from 1-(Alkynyl)-7-oxabicyclo[4.1.0]heptan-2-ones

Jul 14th 2013

Gold-Mediated Synthesis and Functionalization of Chiral Halopyridones

Gold-Catalyzed Cyclization of 1-(Indol-3-yl)-3-alkyn-1-ols: Facile Synthesis of Diversified Carbazoles

Regioselective Synthesis of Functionalized Pyrroles via Gold(I)-Catalyzed [3+2] Cycloaddition of Stabilized Vinyl Diazo Derivatives and Nitriles

Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes

Gold-Catalyzed Highly Diastereoselective Synthesis of Functionalized 3,4-Disubstituted Butyrolactams via Phosphatyloxy or Carbonate Double Migrations

Cyclometallated Gold(III) Complexes as Effective Catalysts for Synthesis of Propargylic Amines, Chiral Allenes and Isoxazoles

Enantioselective Functionalization of Terminal Alkynes by Gold Catalysis

When Alkyne π-Activation Meets Pinacol-Type [1,2]-Rearrangement: On the Invention of Domino Reactions for the Synthesis of Carbocycles and Heterocycles

Jul 7th 2013

Efficient Preparation of 4-Hydroxyquinolin-2(1H)-one Derivatives with Silver-Catalyzed Carbon Dioxide Incorporation and Intramolecular Rearrangement

Si-Si and Si-O Bond Activation at Platinum: Stepwise Formation of a SiH3 Complex

Oxidative N-deprotection of 2-azetidinones using silver(II)–persulfate complexes as a twin oxidant/co-oxidant

Platinum-Based Heterogeneously Catalyzed Hydrosilylation

Gold(I)-catalyzed enantioselective bromocyclization reactions of allenes

Jun 22nd 2013

A Remote Lewis Acid Trigger Dramatically Accelerates Biaryl Reductive Elimination from a Platinum Complex

Gold-Catalyzed Cyclizations of cis-Enediynes: Insights into the Nature of Gold–Aryne Interactions

Highly Active Mononuclear NAC–Gold(I) Catalysts

Formation of Quaternary Centers by Copper-Catalyzed Asymmetric Conjugate Addition of Alkylzirconium Reagents

Combining NHC–Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

Oxidation of a Dimethylplatinum(II) Complex with Oxaziridines: A Hemiaminal Intermediate but No Oxo Complex

When Alkyne π-Activation Meets Pinacol-Type [1,2]-Rearrangement: On the Invention of Domino Reactions for the Synthesis of Carbocycles and Heterocycles

Gold Carbenes from Substituted Propargyl Acetates: Intramolecular Ene-type Reactions to 2-Acetoxynaphthalene Derivatives

Jun 15th 2013

Binding Motif of Terminal Alkynes on Gold Clusters

Gold-Catalyzed Formal Cycloaddition of 2-Ethynylbenzyl Ethers with Organic Oxides and α-Diazoesters

Easy activation of the aryl–sulfur bond by platinum(II)

In Situ Generation of Nucleophilic Allenes by the Gold-Catalyzed Rearrangement of Propargylic Esters for the Highly Diastereoselective Formation of Intermolecular C(sp3) C(sp2) Bonds

Direct syn Insertion of Alkynes and Allenes into Au Si Bonds

The Original Coordination Chemistry of 2-Phosphaphenol with Copper(I) and Gold(I) Halides

A dinuclear silver hydride and an umpolung reaction of CO2

Silver-mediated fluorination, trifluoromethylation, and trifluoromethylthiolation of arynes

Jun 2nd 2013One-Pot Gold-Catalyzed Aminofluorination of Unprotected 2-Alkynylanilines
May 18th 2013

Platinum(IV) Prodrugs with Haloacetato Ligands in the Axial Positions can Undergo Hydrolysis under Biologically Relevant Conditions

Strongly Luminescent Gold(III) Complexes with Long-Lived Excited States: High Emission Quantum Yields, Energy Up-Conversion, and Nonlinear Optical Properties

Gold-Catalyzed Intramolecular Regio- and Enantioselective Cycloisomerization of 1,1-Bis(indolyl)-5-alkynes

Synthesis and Reactivity of N-Heterocyclic Carbene Gold(I) and Gold(III) Imidate Complexes and Their Catalytic Activity in 1,5-Enyne Cycloisomerization

Nitrones as Trapping Reagents of α,β-Unsaturated Carbene Intermediates – [1,2]Oxazino[5,4-b]indoles by a Platinum- Catalyzed Intermolecular [3+3] Cycloaddition

Tandem Gold-Catalyzed Hydrosilyloxylation–Aldol and –Mannich Reaction with Alkynylaryloxysilanols in 6-exo Mode

Silver-Catalyzed Stereoselective [3+2] Cycloadditions of Cyclopropyl-Indanimines with Carbonyl Compounds

May 12nd 2013

Synthesis of 3-Aza-bicyclo[3.1.0]hexan-2-one Derivatives via Gold-Catalyzed Oxidative Cyclopropanation of N-Allylynamides

Direct Catalytic Asymmetric Mannich-Type Reaction of α-Sulfanyl Lactones

Computational Study of Gold-Catalyzed Homo- and Cross-Coupling Reactions

Gold(I)-Catalyzed Formation of Bicyclo[4.2.0]oct-1-enes

Azulenophenanthrenes from 2,2′-Di(arylethynyl)biphenyls through C[BOND]C Bond Cleavage of a Benzene Ring

Biarylphosphonite Gold(I) Complexes as Superior Catalysts for Oxidative Cyclization of Propynyl Arenes into Indan-2-ones

Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles

Gold(I)-Catalyzed Cascade Cycloadditions between Allenamides and Carbonyl-Tethered Alkenes: An Enantioselective Approach to Oxa-Bridged Medium-Sized Carbocycles

Gold-Catalyzed Regioselective Synthesis of 2- and 3-Alkynyl Furans

Gold-Catalyzed Intramolecular Regio- and Enantioselective Cycloisomerization of 1,1-Bis(indolyl)-5-alkynes

Synthesis of new chiral ferrocenyl P,N-ligands with a benzoxazole ring and their application in Ag-catalyzed asymmetric [3+2] cycloaddition

Gold-Catalyzed Synthesis of Iodofulvenes

May 5th 2013

Optimizing P,N-Bidentate Ligands for Oxidative Gold Catalysis: Efficient Intermolecular Trapping of α-Oxo Gold Carbenes by Carboxylic Acids

Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides

Metal-Controlled Cycloaddition of 2-Alkynyl-1,4-benzoquinones and Styrenyl Systems: Lewis Acid versus π Acid

Apr 28th 2013

Catalytic Generation and Selective Heterocoupling of Two Electron-Rich Alkenes

Direct Observation of a Cationic Gold(I)–Bicyclo[3.2.0]hept-1(7)-ene Complex Generated in the Cycloisomerization of a 7-Phenyl-1,6-enyne

Gold Catalysis: Highly Functionalized Cyclopentadienes Prepared by Intermolecular Cyclization of Ynamides and Propargylic Carboxylates

Platinum(II) Acetylides in the Formal [2+2] Cycloaddition-Retroelectrocyclization Reaction: Organodonor Versus Metal Activation

Gold/Brønsted Acid Relay Catalysis for Enantioselective Construction of Spirocyclic Diketones

General Approach to Benzo[b]thiophenes, Benzo[b]furans, and Dibenzofurans via Gold-Catalyzed Cyclization of 1-Heteroarylalka-2,3-dienyl Acetates

Apr 21st 2013

Synthesis of Fused Bicyclic Aminals through Sequential Gold/Lewis Acid Catalysis

Au(I)/Ag(I)-Catalyzed Cascade Approach for the Synthesis of Benzo[4,5]imidazo[1,2-c]pyrrolo[1,2-a]quinazolinones

Silver-Catalyzed Tandem Synthesis of Naphthyridines and Thienopyridines via Three-Component Reaction

Copper Salts as Additives in Gold(I)-Catalyzed Reactions

Heterogeneously Catalyzed Aerobic Cross-Dehydrogenative Coupling of Terminal Alkynes and Monohydrosilanes by Gold Supported on OMS-2

Molecular Understanding of Reactivity and Selectivity for Methanol Oxidation at the Au/TiO2 Interface

Gold Phenolate Complexes: Synthesis, Structure, and Reactivity

Sulfonated Water-Soluble N-Heterocyclic Carbene Silver(I) Complexes: Behavior in Aqueous Medium and as NHC-Transfer Agents to Platinum(II)

Synthesis and Study of Cationic, Two-Coordinate Triphenylphosphine– Gold–π Complexes

Apr 14th 2013

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

Enhancing Catalytic Performance of Palladium in Gold and Palladium Alloy Nanoparticles for Organic Synthesis Reactions through Visible Light Irradiation at Ambient Temperatures

Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an α-Tetrasubstituted Stereocenter

Gold-Catalyzed Synthesis of Glyoxals by Oxidation of Terminal Alkynes: One-Pot Synthesis of Quinoxalines

Apr 7 2013

Silver Ion Mediated In Situ Synthesis of Mixed Diaryl Sulfides from Diaryl Disulfides

Gold-Mediated Selective Cysteine Modification of Peptides Using Allenes.

A silver(I)-catalyzed tandem reaction of 2-alkynylbenzaldoximes with ketenes

Mar 17th 2013

Alkane C–H Insertion by Aryne Intermediates with a Silver Catalyst

Highly Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Diynes to Sulfonimines

Unsupported Nanoporous Gold Catalyst for Highly Selective Hydrogenation of Quinolines

Ag- and Au-Catalyzed Addition of Alcohols to Ynimides: β-Regioselective Carbonylation and Production of Oxazoles

Gold(I)-Catalyzed Macrocyclization of 1,n-Enynes

Silver-Catalyzed Allenylation and Enantioselective Propargylation Reactions of Ketones

Gold-catalyzed synthesis of tetrahydrocarbazole derivatives through an intermolecular cycloaddition of vinyl indoles and N-allenamides

Core–Shell AgNP@CeO2 Nanocomposite Catalyst for Highly Chemoselective Reductions of Unsaturated Aldehydes

Organogold(I) Phosphanes in Palladium-Catalyzed Cross-Coupling Reactions in Aqueous Media

A new oxa-Michael reaction and a gold-catalysed cyclisation en route to C-glycosides

Mar 10th 2013

Gold Catalysis: Regio- and Stereoselective Total Synthesis of Xyloketals D and G and the Related Natural Product Alboatrin

Gold-Catalyzed Oxidative Cyclization of Chiral Homopropargyl Amides: Synthesis of Enantioenriched Lactams

Gold Catalyzed [3+2] Cycloaddition of N-Allenyl amides with Azomethine Imines

Gold-Catalyzed Rearrangement of Allylic Oxonium Ylides: Efficient Synthesis of Highly Functionalized Dihydrofuran-3-ones

Gold-Catalyzed Oxidative Cyclizations on 1,4-Enynes: Evidence for a ?-Substituent Effect on Wagner–Meerwein Rearrangements

Construction of Eight-Membered Carbocycles through Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers

Gold-Catalyzed Reactions of Enynals/Enynones with Norbornenes: Generation and Trapping of Cyclic o-Quinodimethanes (o-QDMs)

Gold(I)-Catalyzed Post-Ugi Hydroarylation: An Approach to Pyrrolopyridines and Azepinoindoles

Mar 3rd 2013

Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self-Assembled Monolayer as Heterogeneous Catalyst for Asymmetric Reactions

Chiral Gold Complex-Catalyzed Hetero-Diels–Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes

Entry to β-Alkoxyacrylates via Gold-Catalyzed Intermolecular Coupling of Alkynoates and Allylic Ethers

Synthesis of 1-Aminoisoquinolines by Gold(III)-Mediated Domino Reactions from 2-Alkynylbenzamides and Ammonium Acetate

Influence of Electronically and Sterically Tunable Cinnamate Ligands on the Spectroscopic Properties and Reactivity of Bis(triphenylphosphine)platinum(0) Olefin Complexe

Unprecedented Large Temperature Dependence of Silver(I)–Silver(I) Distances in Some N-Heterocyclic Carbene Silver(I) Complex Salts

Gold Phosphole Complexes as Efficient Catalysts for Alkyne Activation

Gold Complexes with Tridentate Cyclometalating and NHC Ligands: A Search for New Photoluminescent Gold(III) Compounds

Platinum-Catalyzed Assembly of Quinaldine from Aniline and EthyleneSynthesis, Structural Characterisation and Stereochemical Investigation of Chiral Sulfur-Functionalised N-Heterocyclic Carbene Complexes of Palladium and Platinum
Feb 4th –
Feb 24th 2013
Synthesis of Pyrrolin-4-ones by Pt-Catalyzed Cycloisomerization in PEG under Microwaves

FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction

Oxygen-Assisted Hydroxymatairesinol Dehydrogenation: A Selective Secondary-Alcohol Oxidation over a Gold Catalyst

Formal Total Synthesis of the Algal Toxin (−)-Polycavernoside A
Feb 3rd 2013

Silver-Catalyzed Incorporation of Carbon Dioxide into o-Alkynylaniline Derivatives

Gold-Catalyzed Intramolecular Hydroamination of o-Alkynylbenzyl Carbamates: A Route to Chiral Fluorinated Isoindoline and Isoquinoline Derivatives

Gold(I)-Catalyzed Rearrangement of N-Aryl 2-Alkynylazetidines to Pyrrolo[1,2-a] indoles

Gold(III) Complexes Containing N-Heterocyclic Carbene Ligands: Thiol “Switch-on” Fluorescent Probes and Anti-Cancer Agents

Encapsulation Studies of Cationic Gold Complexes within a Self-Assembled Hexameric Resorcin[4]arene Capsule

Coinage Metal Catalysts for the Addition of O–H to C=C Bonds

A dinuclear cyclometalated gold(III)-phosphine complex targeting thioredoxin reductase inhibits hepatocellular carcinoma in vivo

Jan 27th 2013

A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

Gold(I)-Catalyzed Rearrangement of N-Aryl 2-Alkynylazetidines to Pyrrolo[1,2-a]indoles

Activation of Multiple C-H Bonds Promoted by Gold in AuNbO3+ Clusters

Stille Coupling Involving Bulky Groups Feasible with Gold Cocatalyst

Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3

The Regio- and Stereospecific Intermolecular Dehydrative Alkoxylation of Allylic Alcohols Catalyzed by a Gold(I) N-Heterocyclic Carbene Complex

Mercury(II)-Catalyzed Cyclization of 2-Alkynylphenyl Alkyl Sulfoxides Provides 3-Acylbenzo[b]thiophenes

A dinuclear cyclometalated gold(III)-phosphine complex targeting thioredoxin reductase inhibits hepatocellular carcinoma in vivo

Jan 20th 2013

Platinum-Catalyzed Hydroamination of Ethylene: Study of the Catalyst Decomposition Mechanism

Gold-Catalyzed Formal 1,6-Acyloxy Migration Leading to 3,4-Disubstituted Pyrrolidin-2-ones

Gold(III)-Catalyzed Intramolecular Furanylation and Cyclopropanation of Acyclic Conjugated Enynones

Gold-Allenylidenes – An Experimental and Theoretical Study

Facile transmetalation of a pyridyl-phosphine ligand from ruthenium to gold and silver

Jan 13th 2013

Unraveling the Pathway of Gold(I)-Catalyzed Olefin Hydrogenation: An Ionic Mechanism

Direct Access to Enantioenriched Spiroacetals through Asymmetric Relay Catalytic Three-Component Reaction

Gold-Catalyzed Sequential Activation of Propargylic Carboxylates: A Facile Route to Benzoannulenes

A supramolecular approach to combining enzymatic and transition metal catalysis

Jan 6th 2013

Development of a Gold-Multifaceted Catalysis Approach to the Synthesis of Highly Substituted Pyrroles: Mechanistic Insights via Huisgen Cycloaddition Studies

High Stability, High Activity Pt/ITO Oxygen Reduction Electrocatalysts

Unveiling the Reactivity of Propargylic Hydroperoxides under Gold Catalysis

Gold(I)-Catalysed Alkene Cycloaddition Reactions of Propargyl Acetals

Dec 30th 2012Chemoselective Allene Aziridination via Ag(I) Catalysis
Dec 23rd 2012

Synthesis of Enantioenriched Aza-Proline Derivatives through Gold(I)-Catalyzed Cyclization of Chiral α-Hydrazino Esters

Redox-Controlled Selectivity of C[BOND]H Activation in the Oxidative Cross-Coupling of Arenes

Platinum Complexes of Cationic Ligands for the Aerobic Oxidation of “Inert” Perfluoro-Substituted Alcohols

Gold-catalyzed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

Gold(I)-Catalyzed Aminohalogenation of Fluorinated N′-Aryl-N-Propargyl Amidines for the Synthesis of Imidazole Derivatives under Mild Conditions

Dual Gold Catalysis: σ,π-Propyne Acetylide and Hydroxyl-Bridged Digold Complexes as Easy-to-Prepare and Easy-to-Handle Precatalysts

Reactivity of Stabilized Vinyl Diazo Derivatives toward Unsaturated Hydrocarbons: Regioselective Gold-Catalyzed Carbon–Carbon Bond Formation

Carbophilic 3-Component Cascades: Access to Complex Bioactive Cyclopropyl Diindolylmethanes

Dec 16th 2012

Gold-Catalyzed Sequential Alkyne Activation for the Synthesis of 4,6-Disubstituted Phosphorus 2-Pyrones

Synthesis of Enantioenriched Aza-Proline Derivatives through Gold(I)-Catalyzed Cyclization of Chiral α-Hydrazino Esters

Gold-Catalyzed Domino Cycloisomerization/Pictet–Spengler Reaction of 2-(4-Aminobut-1-yn-1-yl)anilines with Aldehydes: Synthesis of Tetrahydropyrido[4,3-b]indole Scaffolds

A Flexible Metal-Catalyzed Synthesis of Highly Substituted Aryl Phenanthrenyl Selenides

Gold Nanorods Embedded Discotic Nanoribbons

Platinum-Catalyzed Cyclizations via Carbene Intermediates: Syntheses of Complementary Positional Isomers of Isoxazoles

The Redox Chemistry of Gold with High-Valence Doped Calcium Oxide

Gold–Palladium Core–Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance

Dec 09th 2012

Mechanistic Insights into Enantioselective Gold-Catalyzed Allylation of Indoles with Alcohols: The Counterion Effect

Total Structure and Optical Properties of a Phosphine/Thiolate-Protected Au24 Nanocluster

In Situ Reaction Monitoring Reveals a Diastereoselective Ligand Exchange Reaction between the Intrinsically Chiral Au38(SR)24 and Chiral Thiols

Carbazoles via AuCl3-Catalyzed Cyclization of 1-(Indol-2-yl)-3-alkyn-1-ols

Combining Zn ion catalysis with homogeneous gold catalysis: an efficient annulation approach to N-protected indoles

Dec 02nd 2012

Synthesis of the Tetracyclic Core of Berkelic Acid Using Gold(I)-Catalyzed Hydroarylation and Oxidative Radical Cyclizations

Fire and Ice: A Gold(III) Monohydride

Gold(III) Olefin Complexes

Synthesis of Vinyl Sulfides and Vinyl­amines through Catalytic Intramolecular Hydroarylation in the Presence of FeCl3 and AgOTf

Gold-Catalyzed Mannich Addition Reactions of 1,3-Dicarbonyl Compounds with N-Protected Imines

Assembly of Fused Indenes via Au(I)-Catalyzed C1-C5 Cyclization of Enediynes Bearing An Internal Nucleophile
Nov 25th 2012

Gold(III) Olefin Complexes

Straightforward Synthetic Access to gem-Diaurated and Digold σ,π-Acetylide Species

Gold(III)- versus Gold(I)-Induced Cyclization: Synthesis of Six-Membered Mesoionic Carbene and Acyclic (Aryl)(Heteroaryl) Carbene Complexes

Gold for the Generation and Control of Fluxional Barbaralyl Cations

Gold Catalysis: Catalyst Oxidation State Dependent Dichotomy in the Cyclization of Furan–Yne Systems with Aromatic Tethers

Gold-Catalyzed Mannich Addition Reactions of 1,3-Dicarbonyl Compounds with N-Protected Imines

Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems

Silver-Catalyzed Cyclization of N-(Prop-2-yn-1-yl)pyridin-2-amines

Reactivity of Cycloplatinated Amine Complexes: Intramolecular C–C Bond Formation, C–H Activation, and PPh2 Migration in Coordinated Alkynylphosphines

Silver-Catalyzed Direct Addition of Terminal Alkynes to Simple Cyclic Ketones in Water

Nov 18th 2012

Intermolecular [2+2] Reaction of N-Allenylsulfonamides with Vinylarenes: Enantioselective Gold(I)-Catalyzed Synthesis of Cyclobutane Derivatives

Silver catalyzed C–C and C–S coupling of aryl halides and thiols with boronic acids

Assembly of pentacyclic pyrido[4,3,2-mn]acridin-8-ones via a domino reaction initiated by Au(I)-catalyzed 6-endodig cycloisomerization of N-propargylaminoquinones

Oxidative Addition of Phthaloyl Peroxide to Dimethylplatinum(II) Complexes

Reactivity of Cycloplatinated Amine Complexes: Intramolecular C–C Bond Formation, C–H Activation, and PPh2 Migration in Coordinated Alkynylphosphines

Nov 11th 2012Chiral N-Heterocyclic Carbene Gold Complexes: Synthesis, Properties, and Application in Asymmetric Catalysis
Nov 4th 2012Synthesis and Structure of Cationic Phosphine Gold(I) Enol Ether Complexes
Oct 28th 2012Synthesis of Naphthalenes via Platinum-Catalyzed Hydroarylation of Aryl Enynes

Platinum-Catalyzed Oxoarylations of Ynamides with Nitrones

Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines

Oct 21st 2012DNA Self-Assembly of Targeted Near-Infrared-Responsive Gold Nanoparticles for Cancer Thermo-Chemotherapy
Oct 14th 2012Nanoporous Gold Catalyst for Highly Selective Semihydrogenation of Alkynes: Remarkable Effect of Amine Additives

Tempering the Reactivities of Postulated α-Oxo Gold Carbenes Using Bidentate Ligands: Implication of Tricoordinated Gold Intermediates and the Development of an Expedient Bimolecular Assembly of 2,4-Disubstituted Oxazoles

Intermolecular [2+2] Reaction of N-Allenylsulfonamides with Vinylarenes: Enantioselective Gold(I)-Catalyzed Synthesis of Cyclobutane DerivativesThe Fluoride-Free Transmetalation of Organosilanes to Gold

Catalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes

Oct 7th 2012

One-Pot Catalytic Enantioselective Synthesis of Tetrahydropyridines via a Nitro-Mannich/Hydroamination Cascade

Gold(I)-Catalyzed Regiodivergent Rearrangements: 1,2- and 1,2′-Alkyl Migration in Skipped Alkynyl Ketones

Gold catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds

Gold(I) and platinum(II) switch: a post-Ugi intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones

Sept 30th 2012

π−π Interaction Assisted Hydrodefluorination of Perfluoroarenes by Gold Hydride: A Case of Synergistic Effect on C−F Bond Activation

Exploiting the π‑Acceptor Properties of Carbene-Stabilized Phosphorus Centered Trications [L3P] 3+: Applications in Pt(II)Catalysis

Anion-Induced Enantioselective Cyclization of Diynamides to Pyrrolidines Catalyzed by Cationic Gold Complexes

Coordination Chemistry of Gold Catalysts in Solution: A Detailed NMR Study

Intermolecular Mono- and Dihydroamination of Activated Alkenes Using a Recoverable Gold Catalyst

An Alternative Reaction Outcome in the Gold-Catalyzed Rearrangement of 1-Alkynyloxiranes

Synthesis of AzocinoACHTUNGTRENUNG[5,4-b]indoles via Gold-Catalyzed Intramolecular Alkyne Hydroarylation

Sept 9th&23th 2012

Platinum(II) and gold(I) complexes based on 1,1’-bis(diphenylphosphino)metallocene derivatives: Synthesis, characterization and biological activity of the gold complexes

Silver(I)-Catalyzed Tandem Reactions of N-Activated Aziridine-propargylic Esters to Pyrrolidin-3-one Derivatives

Gold-catalyzed direct cycloketalization of acetonide-tethered alkynes in the presence of water

A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes

Gold Vinylidene Complexes: Intermolecular C(sp3)[BOND]H Insertions and Cyclopropanations Pathways

Highly Enantioselective Transfer Hydrogenation of Quinolines Catalyzed by Gold Phosphates: Achiral Ligand Tuning and Chiral-Anion Control of Stereoselectivity

Gold-Catalyzed Functionalization of Unactivated C(sp3)[BOND]H Bonds by Hydride Transfer Facilitated by Alkynylspirocyclopropanes

Gold-Catalyzed Diastereoselective [2+2+2]-Cycloaddition of 1,7-Enynes with Carbonyl Compounds

Dual Hard/Soft Gold Catalysis: Intermolecular Friedel?CCrafts-Type ??-Amidoalkylation/Alkyne Hydroarylation Sequences by N-Acyliminium Ion Chemistry

Gold-Catalyzed Cyclization?CCycloaddition Cascade Reactions of Allenyl Acetals with Nitrones

Study of substrate dependence on the chemoselectivity of the gold-catalysed cycloisomerisation of aryl substituted 1,7-enynes

The Importance of Hydrogen Bonding to Stereoselectivity and Catalyst Turnover in Gold-Catalyzed Cyclization of Monoallylic Diols

A Reaction-Based Sensing Scheme for Gold Species: Introduction of a (2-Ethynyl)benzoate Reactive Moiety

Sept 9th 2012

Gold-Catalyzed Oxidative Rearrangement of Homopropargylic Ether via Oxonium Ylide

Gold-Catalyzed Cyclizations of (o-Alkynyl)phenoxyacrylates with External Nucleophiles: Regio- and Stereoselective Synthesis of Functionalized Benzo[b]oxepines

Sept 2nd 2012

Straightforward Synthesis of Dihydrobenzo[a]fluorenes through Au(I)-Catalyzed Formal [3 + 3] Cycloadditions

Efficient Synthesis of γ-Lactones via Gold-Catalyzed Tandem Cycloisomerization/Oxidation

One-Pot Gold-Catalyzed Synthesis of Azepino[1,2-a]indoles

Base-Stabilized Diborenes: Selective Generation and η2 Side-on Coordination to Silver(I)

AuCl3/AgSbF6-catalyzed rapid epoxide to carbonyl rearrangement

Synthesis of dinuclear N-heterocyclic dicarbene Au(III)/Au(III) and Au(II)/Au(II) complexes via oxidative addition of chlorine or bromine to Au(I)/Au(I) species

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Aug 26th 2012

Regioselectivity Switch: Gold(I)-Catalyzed Oxidative Rearrangement of Propargyl Alcohols to 1,3-Diketones

Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes

Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution

Synthesis of Bicyclic Imidazoles via [2 + 3] Cycloaddition between Nitriles and Regioselectively Generated α-Imino Gold Carbene Intermediates

A Diversity-Oriented Approach to Spiroindolines: Post-Ugi Gold-Catalyzed Diastereoselective Domino Cyclization

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Gold(I)-Catalyzed Regio- and Stereoselective 1,3-Dipolar Cycloaddition Reactions of 1-(1-Alkynyl)cyclopropyl Oximes with Nitrones: A Modular Entry to Highly Substituted Pyrrolo[3,4-d][1,2]oxazepines

Aug 18th 2012

Gold(I)-Catalyzed Addition of Thiols and Thioacids to 3,3-Disubstituted Cyclopropenes

Regioselective Cyclizations Utilizing a Gold-Catalyzed [3,3] Propargyl Ester Rearrangement

Gold-Mediated Insertion of Oxygen into Silicon–Silicon Bond: An Original Au(I)/Au(III) Redox Sequence

Aug 11th 2012Gold-Catalyzed Synthesis of Furans and Furanones from Sulfur Ylides

N-Heterocyclic Carbenes and Imidazole-2-thiones as Ligands for the Gold(I)-Catalysed Hydroamination of Phenylacetylene

Dinuclear Alkynyl Gold(I) Complexes Containing Bridging N-Heterocyclic Dicarbene Ligands: New Synthetic Routes and Luminescence

Hexaphyrin Fused to Two Anthracenes

Selective Au–C Cleavage in (C^N^C)Au(III) Aryl and Alkyl Pincer Complexes

Gold-catalyzed bis-cyclization of 1,2-diol- or acetonide-tethered alkynes. Synthesis of β-lactam-bridged acetals: a combined experimental and theoretical study

July 27th, 2012

Retention of Stereochemistry in Gold-Catalyzed Formal [4+3] Cycloaddition of Epoxides with Arenynamides

Gold-Catalyzed Hydrosilyloxylation Driving Tandem Aldol and Mannich Reactions

Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate

Facile synthesis of 1-aminoisoquinolines via the tandem reactions of 2-alkynylbenzaldoximes with isothiocyanates

Exclusive 1,2-Aryl Shift in Platinum(II) Chloride-Catalyzed Cyclization of 1-(Indol-2-yl)-2,3-allenols

Oxy Effects on the Platinum-Catalyzed Carbo- and Oxacyclizations of 2-Oxiranyl-1-(1-oxyalk-2-ynyl)benzenes

July 21st, 2012Facile Synthesis of Gold(III) Aryl–Carbene Metallacycles

Dinuclear Gold Catalysis: Are Two Gold Centers Better than One?

An Efficient Method for the Synthesis of Alkylidenecyclobutanones by Gold-Catalyzed Oxidative Ring Enlargement of Vinylidenecyclopropanes

Gold Catalysis: Non-Spirocyclic Intermediates in the Conversion of Furanynes by the Formal Insertion of an Alkyne into an Aryl–Alkyl C-C Single Bond
July 14st, 2012

Gold in Total Synthesis: Alkynes as Carbonyl Surrogates

Gold–Gold Cooperation in the Addition of Methanol to Alkynes

Oxidative access to flexible {Pt2(μ-SAr)2} square motifs from platinum thiolato complexes with chelating diphosphine

Gold(I), Gold(III), and Heterometallic Gold(I)–Silver(I) and Gold(I)–Copper(I) Complexes of a Pyridazine-Bridged NHC/Pyrazole Hybrid Ligand and Their Initial Application in Catalysis

July. 07. 2012

Formal Synthesis of 7-Methoxymitosene and Synthesis of its Analog via a Key PtCl2-Catalyzed Cycloisomerization

Total Synthesis of Neurymenolide A Based on a Gold-Catalyzed Synthesis of 4-Hydroxy-2-pyrones

Platinum-Catalyzed Cyclization/[1,2]-Alkyl Migration/Allyl Shift/Cyclization Cascade of Epoxy Alkynyl Allyl Ethers: A Step-Economical Route to Spirobenzo[h]chromanones

The mechanism of oxidative addition of iodine to a dimethylplatinum(II) complex

A Scalable, Efficient Gold-Catalyzed Oxidative Phosphonation of sp3 C-H Bonds using Air as Sustainable Oxidant

Phosphite-Gold(I)-Catalyzed [2+2] Intermolecular Cycloaddition of Enol Ethers with N-Allenylsulfonamides

Gold(I)-Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes

June. 31. 2012

NHC Gold(III) Triflimidate Complexes

Intermolecular Gold-Catalyzed Diastereo- and Enantioselective [2+2+3] Cycloadditions of 1,6-Enynes with Nitrones

Total Synthesis of (±)-Decinine via an Oxidative Biaryl Coupling with Defined Axial Chirality

June 17th 2012

Gold-Catalyzed Cascade Reaction of Hydroxy Enynes for the Synthesis of Oxanorbornenes and Naphthalene Derivatives

A Silver(I)-Catalyzed Tandem Reaction of 2-Alkynylbenzaldoxime with Alkylidenecyclopropane

Probing the Group Tolerance of a Li/Cl Phosphinidenoid Complex Using Alkenyl-Substituted Aldehydes

Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

Merging Organocatalysis and Gold Catalysis—A Critical Evaluation of the Underlying Concepts

Synthesis of 2-Indol-3-ylbenzofulvenes through a Tandem Reaction Catalyzed by Cationic Gold(I) Complexes

Jun 10th 2012

Cyclization of 1,6-Enynes Catalyzed by Gold Nanoparticles Supported on TiO2: Significant Changes in Selectivity and Mechanism, as Compared to Homogeneous Au-Catalysis

Gold-Catalyzed Simultaneous Formation of C–C, C═O, and C–F bonds in the Presence of Selectfluor: A Synthesis of Fluoroindenes from Allene Esters

C-C Bond Formation with Carbon Dioxide Promoted by a Silver Catalyst

Total Synthesis of Neurymenolide A Based on a Gold-Catalyzed Synthesis of 4-Hydroxy-2-pyrones

Platinum-Catalyzed Cyclization/[1,2]-Alkyl Migration/Allyl Shift/Cyclization Cascade of Epoxy Alkynyl Allyl Ethers: A Step-Economical Route to Spirobenzo[h]chromanones

A Silver-Catalyzed Spirocyclization of Alkynyl Silyl Enol Ethers

Phosphite-Gold(I)-Catalyzed [2+2] Intermolecular Cycloaddition of Enol Ethers with N-Allenylsulfonamides

Gold(I)-Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes

Catalytic oxidation/C–H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles

Jun 3rd 2012

Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C–O Bond Formation

Cationic Gold Catalysis with Pyridine-Tethered Au(III) NHC-Carbenes: An Experimental and DFT Computational Study

May 27th 2012

Combining Gold and Palladium Catalysis: One-Pot Access to Pentasubstituted Arenes from Furan–Yne and En–Diyne Substrates

Transition-Metal-Catalyzed Hydroamination and Carboamination Reactions of Anthranilic Allenamides as a Route to 2-Vinyl- and 2-(α-Styryl)quinazolin-4-one Derivatives

Platinum(II) complexes with amide-functionalized NHC-ligands

May 20th 2012

Total synthesis of dendrobate alkaloid (+)-241D, isosolenopsin and isosolenopsin A: application of a gold-catalyzed cyclization

Catalytic C-F Bond Activation of Perfluoroarenes by Tricoordinated Gold(I) Complexes

Microwave-Assisted Synthesis of Pyrazino[2,1-b]quinazolines and 3-Indolyl-2(1H)-pyrazinones Employing a Chemoselective Silver(I)- and Gold(I)-Catalyzed Reaction

Gold-Catalyzed Synthesis of Substituted 2-Aminofurans via Formal [4+1]-Cycloadditions on 3-En-1-ynamides

Gold-catalyzed isomerization of unactivated allenes into 1,3-dienes under ambient conditions

Catalytic Oxidation/C–H Functionalization of N-Arylpropiolamides by Means of Gold Carbenoid: Concise Route to 3-Acyloxindoles

DFT Studies on Gold-Catalyzed Cycloisomerization of 1,5-Enynes

May 13th 2012

Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-Tributylstannylfuran Through Au/Sn Transmetalation

Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes

Dearomatization of Fused Arenes Using Platinum-Catalyzed Intramolecular Formation of Two C-C Bonds

May 6th 2012

Geminally Diaurated Gold(I) Aryls from Boronic Acids

Concise route to indoloazocines via a sequential Ugi / gold-catalyzed intramolecular hydroarylation

Apr 29th, 2012

Double Cyclization/Aryl Migration Across an Alkyne Bond Enabled by Organoboryl and Diarylplatinum Groups

Gold-Catalyzed Carbene Transfer to Alkynes: Access to 2,4-Disubstituted Furans

Structures and Dynamic Solution Behavior of Cationic, Two-Coordinate Gold(I)–π-Allene Complexes

Gold-Catalysis: Highly Efficient and Regio-Selective Carbonyl Migration in Alkynyl-Substituted Indole-3-Carboxamides Leading to Azepino[3,4-b]indol-1-ones

Apr 22nd, 2012

Gold(I)-Catalyzed Synthesis of 1,5-Benzodiazepines Directly from o-Phenylenediamines and Alkynes

Gold(I)-Catalyzed Rearrangement of 3-Silyloxy-1,5-enynes: An Efficient Synthesis of Benzo[b]thiophenes, Dibenzothiophenes, Dibenzofurans, and Indole Derivatives

Mechanism of the N-protecting Group Dependent Annulations of 3-Aryloxy Alkynyl Indoles under Gold Catalysis: A Computational Study

Apr 15th, 2012

Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay toward Highly Functionalized 1,3-Dienes

Coinage Metals-Catalyzed Cascade Reactions of Aryl Alkynylaziridines: Silver(I)-Single vs Gold(I)-Double Cyclizations

Gold(I)-Catalyzed Stereoconvergent, Intermolecular Enantioselective Hydroamination of Allenes

Apr 8th, 2012

Strong Metallophilic Interactions in the Palladium Arylation by Gold Aryls

Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand

Coinage Metals-Catalyzed Cascade Reactions of Aryl Alkynylaziridines: Silver(I)-Single vs Gold(I)-Double Cyclizations

Gold-Catalyzed 1,2-/1,2-Bis-Acetoxy Migration of 1,4-Bis-Propargyl Acetates: A Mechanistic Study

Gold(I)-catalyzed intramolecular hydroamination and ring-opening of sulfonamide-substituted 2-(arylmethylene)cyclopropylcarbinols

Mechanism of the Gold(I)-Catalyzed Rearrangement of Alkynyl Sulfoxides: A DFT Study

Cationic Gold-Catalyzed Regioselective Hydration of 1-Arylalkynes through Carbonyl Group Participation

Transition-Metal-Catalyzed Functionalization of Propargylic Alcohols and Their Derivatives

The Combination of Relay and Cooperative Catalysis with a Gold/Palladium/Brønsted Acid Ternary System for the Cascade Hydroamination/Allylic Alkylation Reaction
Apr 1st, 2012Monomeric Linear Diaminocarbene Complexes of Gold(I) Show Merit in Enantioselective Catalysis

σ-Accepting Properties of a Chlorobismuthine Ligand

Silver and Gold Complexes with a New 1,10-Phenanthroline Analogue N-Heterocyclic Carbene: A Combined Structural, Theoretical, and Photophysical Study

Water-Soluble N-Heterocyclic Carbene Platinum(0) Complexes: Recyclable Catalysts for the Hydrosilylation of Alkynes in Water at Room Temperature

Triazinone-Bridged Neutral Dinuclear Gold(I)-NHC Complex

Steric tuning of C2-symmetric chiral N-heterocyclic carbene in gold-catalyzed asymmetric cyclization of 1,6-enynes

An Alternative Approach to Direct Aldol Reaction Based on Gold-Catalyzed Methoxyl Transfer

March 25th, 2012

Simple Gold-Catalyzed Synthesis of Benzofulvenes—gem-Diaurated Species as “Instant Dual-Activation” Precatalysts

Gold(I)-Catalyzed Unprecedented Rearrangement Reaction Between 2-Aminobenzaldehydes with Propargyl Amines: An Expedient Route to 3-Aminoquinolines

Gold-catalyzed Ring Expansions of 1-Alkynylcyclobutanol Derivatives via Tandem Hydration and α-Ketol Rearrangement

March 18th, 2012

Regiodivergent Synthesis of Functionalized Indene Derivatives via Pt-Catalyzed Rautenstrauch Reaction of Propargyl Carbonates

Efficient and High Yield One-Pot Synthesis of Cyclometalated Platinum(II) β-Diketonates at Ambient Temperature

Platinum-Catalysed Bisindolylation of Allenes: A Complementary Alternative to Gold Catalysis

Factors Controlling the Equilibrium of Pt-Catalyzed [1,2]- versus [1,3]-Acyloxy Migration

March 10th, 2012

Isolable Tris(alkyne) and Bis(alkyne) Complexes of Gold(I)

Kinetic Resolution of 1-(1-Alkynyl)-cyclopropyl Ketones by Gold(I)-Catalyzed Asymmetric [4+3]Cycloaddition with Nitrones: Scope, Mechanism and Applications

Gold-catalyzed amide synthesis from aldehydes and amines in aqueous medium

Cationic Gold-Catalyzed Regioselective Hydration of 1-Arylalkynes through Carbonyl Group Participation

Mar 5th, 2012

Chiral Silver Phosphate-Catalyzed Cycloisomeric Kinetic Resolution of α-Allenic Alcohols

Synthesis of Allenes via Gold-Catalyzed Intermolecular Reaction of Propargylic Alcohols and Aromatic Compounds

Asymmetric Synthesis of Dihydropyranones from Ynones by Sequential Copper(I)-Catalyzed Direct Aldol and Silver(I)-Catalyzed Oxy-Michael Reactions

Isolable Tris(alkyne) and Bis(alkyne) Complexes of Gold(I)

Regioselective Formation of Saturated Abnormal NHC–Gold(I) Complexes by [3+2] Cycloaddition of Azomethine Ylides and Isonitrile Gold(I) Complexes

Pd-Catalyzed Asymmetric Synthesis of N-Allenyl Amides and Their Au-Catalyzed Cycloisomerizative Hydroalkylation: A New Route Toward Enantioenriched Pyrrolidones

Gold- and Silver-Catalyzed Reactions of Propargylic Alcohols in the Presence of Protic Additives

Gold-catalyzed amide synthesis from aldehydes and amines in aqueous medium

Feb 26th, 2012

Ambient Schmittel Cyclization Promoted by Chemoselective Triazole-Gold Catalyst

Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines

Gold-Catalysed Oxyarylation of Styrenes and Mono- and gem-Disubstituted Olefins Facilitated by an Iodine(III) Oxidant

Gold-Catalyzed Synthesis of Dibenzopentalenes – Evidence for Gold Vinylidenes

The More Gold—The More Enantioselective: Cyclohydroaminations of γ-Allenyl Sulfonamides with Mono-, Bis-, and Trisphospholane Gold(I) Catalysts

Feb 19th, 2012

Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines

Structure Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange

Feb 12th, 2012

Platinum-Catalyzed Hydrosilylations of Internal Alkynes: Harnessing Substituent Effects to Achieve High Regioselectivity

Intramolecular gold(III) catalysed Diels–Alder reaction of 1-(2-furyl)-hex-1-en-5-yn-3-ol derivatives: a short and generalised route for the synthesis of hydroxyphenanthrene derivatives

Gold-Catalyzed Furan/Yne Cyclizations for the Regiodefined Assembly of Multisubstituted Protected 1-Naphthols

Feb 5th, 2012

Enantioselective Cyclizations of Silyloxyenynes Catalyzed by Cationic Metal Phosphine Complexes

Gold-Catalyzed Oxidative Cyclizations of cis-3-En-1-ynes to Form Cyclopentenone Derivatives

Au(I)-Catalyzed Intramolecular Hydroamination of the Fluorinated N′-Aryl-N-Propargyl Amidines: Mild Conditions for the Synthesis of 2-Fluoroalkyl Imidazole Derivatives

Gold-Catalysed Oxyarylation of Styrenes and Mono- and gem-Disubstituted Olefins Facilitated by an Iodine(III) Oxidant

Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C-C Coupling and Other Reactions (pages 1864–1884)

Bulk Gold-Catalyzed Reactions of Isocyanides, Amines, and Amine N-Oxides

Efficient One-Pot Synthesis of Unsymmetrical Gold(I) N-Heterocyclic Carbene Complexes and Their Use as C


Jan 25 th, 2012

Para-Selective Gold Catalyzed Direct Alkynylation of Anilines

Gold-Catalyzed Furan-Yne Cyclizations for the Regiodefined Assembly of Multi-substiuted protected 1-naphthol

Recent Advances in the isolation and Reactivity of organogold complexes



Constrained Digold(I) Diaryls: Syntheses, Crystal Structures, and Photophysics

On Homogeneous Gold/Palladium Catalytic Systems

Rapid Access to Chroman-3-ones through Gold-Catalyzed Oxidation of Propargyl Aryl Ethers

Tandem Platinum Dichloride Catalysis and Thermal Reaction of Enynes: Versatile Synthetic Platform Based on Bicyclo[4.1.0]hept-2-enes



Enantioselective Alkynylbenzaldehyde Cyclizations Catalyzed By Chiral Gold(I) Acyclic Diaminocarbene Complexes Containing Weak Au–Arene Interactions

Gold(I)-Catalyzed Enantioselective Intramolecular Dehydrative Amination of Allylic Alcohols with Carbamates

Dimeric Gold Bis(carbene) Complexes by Transmetalation in Water

Synthesis and Structure of Dicationic, Bis(gold) π-Alkene Complexes Containing a 2,2′-Bis(phosphino)biphenyl Ligand



Experimental and Computational Evidence for Gold Vinylidenes: Generation from Terminal Alkynes via a Bifurcation Pathway and Facile C–H Insertions

Formal Intermolecular [2 + 2] Cycloaddition Reaction of Alleneamides with Alkenes via Gold Catalysis

Platinum Complexes with Pyrimidine-Functionalized N-Heterocyclic Carbene Ligands – Synthesis and SolidState Structures

Facile and Reversible 1,3-Dipolar Cycloaddition of Aryl Ketonitrones to Platinum(II)-Bound Nitriles: Synthetic, Structural, and Theoretical Studies



Gold-Catalyzed Formation of Oxonium Ions from Enynes and Their Intra- and Intermolecular Trapping with Allylsilanes

Gold-Catalyzed Three-Component Annulation: Efficient Synthesis of Highly Functionalized Dihydropyrazoles from Alkynes, Hydrazines, and Aldehydes or Ketones

N-Heterocyclic Carbene Gold(I) and Copper(I) Complexes in C–H Bond Activation

Cu(I)-Catalyzed Oxidative Cyclization of Alkynyl Oxiranes and Oxetanes

Mechanism of Gold(I)-Catalyzed Rearrangements of Acetylenic Amine-N-Oxides: Computational Investigations Lead to a New Mechanism Confirmed by Experiment

Cluster Preface: Gold Catalysis for Organic Synthesis: Opportunities Abound

Gold-Catalyzed Cyclization of Oxo-1,5-enynes

Gold-Catalyzed Regioselective Dimerization of Aliphatic Terminal Alkynes

Enantioselective Intramolecular Hydroamination of N-Alkenyl Ureas Catalyzed by tropos BIPHEP-Gold(I) Complexes with Au-Au Interaction

Nanoporous Gold-Catalyzed [4+2] Benzannulation between ortho-Alkynylbenzaldehydes and Alkynes

A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates

Gold-Catalyzed Cycloisomerization of Functionalized 1,5-Enynes – An Entry to Polycyclic Framework

Gold(I)-Catalyzed Stereoselective Synthesis of Alkenyl Phosphates by Hydrophosphoryloxylation

Strained small rings in gold-catalyzed rapid chemical transformations

Gold catalysis in total synthesis—an update



Formation of Five- and Seven-Membered Rings Enabled by the Triisopropylsilyl Auxiliary GroupA Highly Efficient Gold-Catalyzed Oxidative C-C Coupling from C-H Bonds Using Air as Oxidant

Cyclometalated gold(III) iminophosphoranes which incorporate carbohydrate groups

Gold versus Silver-Catalyzed Intermolecular Hydroaminations of Alkenes and Dienes

C(sp3)–F reductive elimination from alkylgold(III) fluoride complexes

Oxidative addition of MeI to some cyclometalated organoplatinum(II) complexes: Kinetics and mechanism

“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects



Design, Synthesis, Evaluation, and Structure of Vitamin D Analogues with Furan Side Chains

A direct and practical approach for the synthesis of Au(I)-NHC complexes from commercially available imidazololium salts and Au(III) salts



Gold-Catalyzed Intermolecular Reactions of Propiolic Acids with Alkenes: [4+2] Annulation and Enyne Cross Metathesis

Gold-Catalyzed Formal [3+3] and [4+2]-Cycloaddition Reactions of Nitrosobenzenes with Alkenylgold Carbenoids



Gold Chemistry Guided by the Isolobality Concept



Au-Catalyzed Piperidine Synthesis via Tandem Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters

Platinum-Catalyzed Direct Amination of Allylic Alcohols with Aqueous Ammonia: Selective Synthesis of Primary Allylamines

Mild chemo-selective hydration of terminal alkynes catalysed by AgSbF6

Electrophilic fluorination of cationic Pt-aryl complexes

Enantioselective Intermolecular Carbon–Carbon Bond Formation of Glyoxylate Imines with Allylstannanes Catalyzed by tropos BIPHEP–Gold(I) Complexes with Au–Au Interactions




Binap–Gold(I) versus Binap–Silver Trifluoroacetate Complexes as Catalysts in 1,3-Dipolar Cycloadditions of Azomethine Ylides

Gold-Catalyzed Intermolecular [4+2] and [2+2+2] Cycloadditions of Ynamides with Alkenes

Phosphate ligands in the gold(I)-catalysed activation of enynes

Gold-mediated bifunctional modification of oligosaccharides via a three-component coupling reaction

Gold(I)-1,3-Diene Complexes: Connecting Structure,Bonding, and Reactivity



Assembly of Digitoxin by Gold(I)-Catalyzed Glycosidation of Glycosyl o-Alkynylbenzoates




Gold-Catalyzed Oxidative Acyloxylation of Arenes

“Synthesis of Arylnaphthalene Lignan Scaffold by Gold-Catalyzed Intramolecular Sequential Electrophilic Addition and Benzannulation”

Selectivity Switch in the Synthesis of Vinylgold(I) Intermediates

Gold-Mediated Bifunctional Modification of Oligosaccharides via a
Three-Component Coupling Reaction




Does Gold as a Substituent Accelerate [3,3] Sigmatropic Shifts?

On the Equilibrium between Alkyne and Olefin Platinum(II) Complexes of Zeise’s Salt Type: Syntheses and Characterization of [K(18C6)][PtCl3(RC≡CR′)]

Yb(OTf)3- or AuI-Catalyzed Domino Intramolecular Hydroamination and Ring-Opening of Sulfonamide-Sustituted 1,1-Vinylidenecyclopropanediesters

Highly Efficient and Diastereoselective Gold(I)-Catalyzed Synthesis of Tertiary Amines from Secondary Amines and Alkynes: Substrate Scope and Mechanistic Insights



Gold(I)-Catalyzed Formation of 3-Pyrazolines through Cycloaddition of Diaziridine to Alkynes

Generation of α,β-Unsaturated Platinum Carbenes from Homopropargylic Alcohols: Rearrangements to Polysubstituted Furans

Enantioselective Gold(I)-Catalyzed Intramolecular (4+3) Cycloadditions of Allenedienes

Gold catalyzed reduction of a hexavalent aromatic sulfonyl phthalimide to sulfur

Pt–Sn/γ-Al2O3-Catalyzed Highly Efficient Direct Synthesis of Secondary and Tertiary Amines and Imines

General Au-Catalyzed Benzannulation Towards Naturally Occurring Carbazole Alkaloids from Methoxypropadiene



Characterization of Vinylgold Intermediates: Gold-Mediated Cyclization of Acetylenic Amides

Unusual Ester-Directed Regiochemical Control in endo-Selective Asymmetric 1,3-Dipolar Cycloadditions of Azomethine Ylides with β-Sulfonyl Acrylates

Gold-Catalyzed Oxidative Cyclizations of 2-Oxiranyl-1-alkynylbenzenes for Diastereoselective Synthesis of Highly Substituted 2-Hydroxyindanones (pages 2589–2592)



Copper(II) Catalyzed Asymmetric Henry Reaction of o-Alkynylbenzaldehydes and Following Gold(I) Mediated Cycloisomerization: An Enantioselective Route to Chiral 1-H-isochromenes and 1,3-Dihydroisobenzofuran

Gold(III)-Catalyzed Tandem Conjugate Addition/Annulation of 4-Hydroxycoumarins with alpha,beta-Unsaturated Ketone

Gold(I)-Catalyzed Polycyclizations of Polyenyne-Type Anilines Based on Hydroamination and Consecutive Hydroarylation Cascade

Gold-Catalyzed [3+2] Cycloaddition/Hydrolytic Michael Addition/Retro-Aldol Reactions of Propargylic Esters Tethered to Cyclohexadienones

Hydroamination of Alkynes with Ammonia: Unforeseen Role of the Gold(I) Catalyst



One-Pot Synthesis of Indole-Fused Scaffolds via Gold-Catalyzed Tandem Annulation Reactions of 1,2-Bis(alkynyl)-2-en-1-ones with Indoles

Photoreactive gold(I) macrocycles with diphosphine and trans,trans-muconate ligands

Gold-Catalyzed Dehydrative Transformations of Unsaturated Alcohol

Novel Mixed Coordination of N and C Donors to Gold–Gold Center



Efficient Synthesis of Lupane-Type Saponins via Gold(I)-Catalyzed Glycosylation with Glycosyl ortho-Alkynylbenzoates as Donors

Synthesis of Fused Carbocycles via a Selective 6-Endo Dig Gold(I)-Catalyzed Carbocyclization




Gold-Catalyzed 1,2-Difunctionalizations of Aminoalkynes Using Only N- and O-Containing Oxidants

PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

Gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers; synthesis of substituted 1,3-dienes

Platinum(II) complexes incorporating racemic and optically active 1-alkyl-3-phospholenes and 1-propyl-phospholane P-ligands: Synthesis, stereostructure, NMR properties and catalytic activity



Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate

Total synthesis of (-)-funebrine via Au-catalyzed regio- and stereoselective γ-butyrolactonization of allenylsilane



Gold(I)-Catalyzed Synthesis of Benzoxocines by an 8-endo-dig Cyclization

Nature of the Intermediates in Gold(I)-Catalyzed Cyclizations of 1,5-Enynes

Total Syntheses of Drimane-Type Sesquiterpenoids Enabled by a Gold-Catalyzed Tandem Reaction

Gold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenes

A gold(I)-catalyzed intramolecular oxidation–cyclopropanation sequence of 1,6-enynes: a convenient access to [n.1.0]bicycloalkanes

Gold/copper-catalyzed activation of the aci-form of nitromethane in the synthesis of methylene-bridged bis-1,3-dicarbonyl compounds




Gold-Catalyzed, Intramolecular, Oxygen-Transfer Reactions of 2-Alkynyl-1,5-diketones or 2-Alkynyl-5-ketoesters: Scope, Expansion, and Mechanistic Investigations on a New [4+2] Cycloaddition

On Gold-Mediated C-H Activation Processes

Gold- or Palladium-Catalyzed Allene Carbocyclization/Functionalization: Simple and Efficient Synthesis of Carbazoles

Gold (I)-Catalyzed Claisen Rearrangement of Allenyl Vinyl Ethers; Synthesis of Substituted 1,3-Dienes




Chiral Brønsted Acid from a Cationic Gold(I) Complex: Catalytic Enantioselective Protonation of Silyl Enol Ethers of Ketones

Gold for C-C Coupling Reactions: A Swiss-Army-Knife Catalyst?

Sequential Alkylation/Gold-Catalyzed Annulation Reactions of Anilines with Propargylic Bromide Derivatives

Synthesis of flinderoles B and C by a gold-catalyzed allene hydroarylation On Gold-Mediated C-H Activation Processes

A Recyclable Polystyrene-Supported Gold(I) Catalyst

Diphosphines and pyrazole/pyrazolate-type ligands as building blocks in luminescent Au(I) complexes




Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Ester

Intermolecular and Selective Synthesis of 2,4,5-Trisubstituted Oxazoles by a Gold-Catalyzed Formal [3+2] Cycloaddition

Diphosphines and pyrazole/pyrazolate-type ligands as building blocks in luminescent Au(I) complexes




Gold-Catalyzed Cyclization of Nonterminal Propargylic Amides to Substituted Alkylideneoxazolines and -oxazines

Cyclopropyl Carbinol Rearrangement for Benzo-Fused Nitrogen Ring Synthesis

Homocoupling of arylboronic acids catalyzed by simple gold salts

Gold(I)-catalysed intramolecular hydroamination of α-quaternary alkynes: synthetic studies towards spiroimine marine toxins



Cyclopropyl Carbinol Rearrangement for Benzo-Fused Nitrogen Ring Synthesis

Potential Energy Surface for (Retro-)Cyclopropanation: Metathesis with a Cationic Gold Complex

Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes

Evaluation of the Electronic Properties of a Carbodiphosphorane through Gold Catalysis

Umpolung Reactivity of Indole through Gold Catalysis

Gold Catalyzed Cyclization of Alkyne-Tethered Dihydropyrimidones

Synthesis of 2,5-Dihydropyridine Derivatives by Gold-Catalyzed Reactions of β-Ketoesters and Propargylamines

Platinum-Catalyzed Diastereoselective Intramolecular Coupling of Allyl Halides and Hydrazones

Gold-Catalyzed Deacylative Cycloisomerization Reactions of 3-Acylindole/ynes: A New Approach for Carbazole Synthesis

Allyl Radical Nature of a Phenylcyclopentadienyl Radical Annelated with Two Homoadamantene Frameworks

Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes



Gold Catalysis in Micellar Systems

Gold α-Oxo Carbenoids in Catalysis: Catalytic Oxygen-Atom Transfer to Alkynes

[Au(CF3)(CO)]: A Gold Carbonyl Compound Stabilized by a Trifluoromethyl Group



Axially Chiral N-Heterocyclic Carbene Gold(I) Complex Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes

Gold-Catalyzed Transformation of 2-Alkynyl Arylazides: Efficient Access to the Valuable Pseudoindoxyl and Indolyl Framework

Gold-Catalyzed Cyclization of Nonterminal Propargylic Amides to Substituted Alkylideneoxazolines and -oxazines

Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

Synthesis of Substituted 1,4,5,6-Tetrahydrocyclopenta[b]pyrroles by Platinum-Catalyzed Cascade Cyclization/Ring Expansion of 2-Alkynyl-1-azaspiro[2.3]hexanes



Oxidative Cycloaddition of 1,1,3,3-Tetramethyldisiloxane to Alkynes Catalyzed by Supported Gold Nanoparticles

Neutral and Cationic Gold(I) Complexes with π-Conjugated Phosphasilene Ligands

Axially Chiral N-Heterocyclic Carbene Gold(I) Complex Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes

AuI/AuIII Catalysis: An Alternative Approach for C – C Oxidative Coupling

Synthesis of 4-Aryl-2(5H)-furanones by Gold(I)-Catalyzed Intramolecular Annulation

Unexpected Bonding Mode of the Diboran(4)yl Ligand: Combining the Boryl Motif with a Dative Pt[BOND]B Interaction

Gold-Catalyzed 1,3-Acyloxy Migration/5-exo-dig Cyclization/1,5-Acyl Migration of Diynyl Esters

Gold-Catalyzed Oxidative Cyclization of 1,5-Enynes Using External Oxidants

Exploration of the Scope of Pt-Catalyzed C–F Activation

Gold(I)-Catalyzed Tandem Alkoxylation/Lactonization of γ-Hydroxy-α,β-Acetylenic Esters



A regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes

Stereoselective synthesis of tetracyclic indolines via gold-catalyzed cascade cyclization reactions

Gold Catalysis: Domino Reaction of En-Diynes to Highly Substituted Phenols

Concise Synthesis of the Antidepressive Drug Candidate GSK1360707 by a Highly Enantioselective Gold-Catalyzed Enyne Cycloisomerization Reaction



A Highly Efficient Access to Spiroketals, Mono-unsaturated Spiroketals, and Furans: Hg(II)-Catalyzed Cyclization of Alkyne Diols and Triols

Concise Synthesis of the Antidepressive Drug Candidate GSK1360707 by a Highly Enantioselective Gold-Catalyzed Enyne Cycloisomerization Reaction

Asymmetric Formal [3+2] Cycloaddition Reaction of Isocyanoesters to 2-Oxobutenoate Esters by a Multifunctional Chiral Silver Catalyst

May.22, 2011

Sequential Combination of Ruthenium-, Base-, and Gold-Catalysis – A New Approach to the Synthesis of Medicinally Important Heterocycles

Gold Catalysis: Products and Intermediates Obtained from N-Propargylcarboxamides Bearing Additional Substituents on Nitrogen

Synthesis of 2-Phenylnaphthalenes through Gold-Catalyzed Dimerization via a Highly Selective Carbon Nucleophile Pathway

May.15, 2011

An Efficient [2 + 2 + 1] Synthesis of 2,5-Disubstituted Oxazoles via Gold-Catalyzed Intermolecular Alkyne Oxidation

Gold-Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine

Gold(I)-Catalyzed Formation of Benzo[b]furans from 3-Silyloxy-1,5-enynes

Gold(III) chloride catalysed synthesis of 5-alkylidene-dihydrothiazoles

May.08, 2011

Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity

Hydroalkoxylation Catalyzed by a Gold(I) Complex Encapsulated in a Supramolecular Host

Syntheses of α-Pyrones Using Gold-Catalyzed Coupling Reactions

Synthesis of the Phenanthrene and Cyclohepta[a]naphthalene Skeletons via Gold(I)-Catalyzed Intramolecular Cyclization of Unactivated Cyclic 5-(2-Arylethyl)-1,3-dienes

On the Memory of Chirality in Gold(I)-Catalyzed Intramolecular Carboalkoxylation of Alkynes

Taking Advantage of the Ambivalent Reactivity of Ynamides in Gold Catalysis: A Rare Case of Alkyne Dimerization

Cytotoxicity of Gold(I) N-Heterocyclic Carbene Complexes Assessed by Using Human Tumor Cell Lines

Gold- and Copper-Catalyzed Cycloisomerizations towards the Synthesis of Thujopsanone-like Compounds

Extended Lifetimes of Gold (III) Chloride Catalysts using Copper(II) Chloride and 2,2,6,6-Tetramethylpiperidine 1-Oxyl(TEMPO)

Gold(I)-Catalyzed Reactions of Propargyl Esters with Vinyl Derivatives

AuI-Catalyzed Intramolecular Cyclization of 2-Alkenylphenyl CarbonylCompounds: Exploring the Oxophilic Lewis Acidity of AuI Species

Gold(I)-catalyzed rearrangement of aryl alkynylaziridines to spiro[isochroman-4,2′-pyrrolines]

Direct reductive amination of aromatic aldehydes catalyzed by gold(I) complex under transfer hydrogenation conditions

Gold-catalyzed Intramolecular Hydroarylation of Olefins. Scope Evaluation and    Preliminary Mechanistic Studies

Recent Developments in Asymmetric Catalysis in the Presence of Chiral Gold Complexes

A gold-catalyzed alkyne-diol cycloisomerization for the synthesis of oxygenated 5,5-spiroketals

One-pot gold-catalyzed synthesis of 3-silylethynyl indoles from unprotected o-alkynylanilines

Apr.10, 2011

Combining Gold(I)/Gold(III) Catalysis and C-H Functionalization: A Formal Intramolecular [3+2] Annulation towards Tricyclic Indolines and Mechanistic Studies

Synthesis of Ginsenoside Rh2 and Chikusetsusaponin-LT8 via Gold(I)-catalyzed Glycosylation with a Glycosyl ortho-Alkynylbenzoate as Donor

Gold Catalyzed Carbocyclization of Phenyl Substituted Allylic Acetates to Synthesize Benzocycle Derivatives

Apr.3, 2011

Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

Heterocycles from gold catalysis

Straightforward Synthesis of Bridged Azaoxa Skeletons: Gold-Catalyzed Aminoketalization of Garner’s Aldehyde-Derived Alkynes

Regio- and Stereoselective Construction of Highly Functionalized 3-Benzazepine Skeletons through Ring-Opening Cycloamination Reactions Catalyzed by Gold

Mar. 27, 2011

Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines

Synthesis and Structure of Gold and Platinum Menthyl Complexes

Selective Gold(I)-Catalyzed Formation of Tetracyclic Indolines: A Single Transition State and Bifurcations Lead to Multiple Products

Cyclopropenylyliden-stabilisierte Di(aryl/alkyl)phospheniumkationen: Anwendungen in der homogenen Gold-Katalyse

March.20, 2011

Cyclopropenylylidene-Stabilized Diaryl and Dialkyl Phosphenium Cations: Applications in Homogeneous Gold Catalysis

Gold(III) Complexes Catalyze Deoximations/Transoximations at Neutral pH

Gold Catalysis: Products and Intermediates Obtained from N-Propargylcarboxamides Bearing Additional Substituents on Nitrogen

Gold-Catalyzed Reactions of 2-C-Branched Carbohydrates: Mild Glycosidations and Selective Anomerizations

Ph3PAuNTf2 as a Superior Catalyst for the Selective Synthesis of 2H-Chromenes: Application to the Concise Synthesis of Benzopyran Natural Product

Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

Gold-Catalyzed Direct Amination of Arenes with Azodicarboxylates

Gold-catalyzed decorations of arenes and heteroarenes with C–C multiple bonds

One-pot nitro-Mannich/hydroamination cascades for the direct synthesis of 2,5-disubstituted pyrroles using base and gold catalysis

Dissymmetric gold(I) N-heterocyclic carbene complexes: a key unexpected structural parameter for highly efficient catalysts in the addition of alcohols to internal alkynes

Gold(I)-catalyzed intermolecular (4 + 2) cycloaddition of allenamides and acyclic dienes

Gold Catalyzed Oxycyclizations of Alkynols and Alkyndiols

Feb. 27, 2011

Gold(I)-Catalyzed Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition and Mannich Reactions of Azlactones

A Fischer Carbene within an Arduengo Carbene

Gold-Catalyzed Nitrene Transfer to Activated Alkynes: Formation of α,β-Unsaturated Amidines

An Approach to Highly Functionalized Quinolines and Isoquinolines via a Gold-Catalyzed Benzannulation

Synthesis of Carbazoles by Gold(I)-Catalyzed Carbocyclization of 2-(Enynyl)indolesGold-Catalyzed Cascade Friedel–Crafts/Furan-Yne Cyclization/Heteroenyne Metathesis for the Highly Efficient Construction of Phenanthrene Derivatives

Feb. 20, 2011

Gold(I)-Catalyzed Cycloisomerization of 1,6-Diynes: Synthesis of 2,3-Disubstituted 3-Pyrroline Derivatives

Gold-Catalyzed Synthesis of Benzil Derivatives and α-Keto Imides via Oxidation of AlkynesEnantioselective

Gold-Catalyzed Functionalization of Unreactive sp3 C-H Bonds through a Redox–Neutral Domino Reaction

Reusable and Durable Immobilized-Cationic Gold(I) Catalysts for Environmentally Benign Bond-Forming Reactions

Feb. 13, 2011

Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles

Polymer-Incarcerated Gold-Palladium Nanoclusters with Boron on Carbon: A Mild and Efficient Catalyst for the Sequential Aerobic Oxidation-Michael Addition of 1,3-Dicarbonyl Compounds to Allylic Alcohols

Gold(I)-Catalyzed Intramolecular Amination of Allylic Alcohols With Alkylamines

Gold(I)-Catalyzed, Highly Diastereoselective, Tandem Heterocyclizations/[3+2] Cycloadditions: Synthesis of Highly Substituted Cyclopenta[c]furans

Feb. 06, 2011

Gold(III) N-Heterocyclic Carbene Complexes Mediated Synthesis of β-Enaminones From 1,3-Dicarbonyl Compounds and Aliphatic Amines

Platinum-catalyzed cyclization reaction of alkynes: synthesis of azepino[3,4-b]indol-1-ones

Allylic alcohols: Valuable synthetic equivalents of non-activated alkenes in gold-catalyzed enantioselective alkylation of indoles

Jan. 30, 2011

A General Procedure for the Synthesis of Enones via Gold-Catalyzed Meyer-Schuster Rearrangement of Propargylic Alcohols at Room Temperature

Mechanism of the Dehydrogenative Silylation of Alcohols Catalyzed by Cationic Gold Complexes: An Experimental and Theoretical Study

Gold-Catalysed Activation of Epoxides: Application in the Synthesis of Bicyclic Ketals

Jan. 23, 2011

Direct Synthesis of Fused Indoles by Gold-Catalyzed Cascade Cyclization of Diynes

Gold-Catalyzed Stereoselective Synthesis of Azacyclic Compounds through a Redox/[2 + 2 + 1] Cycloaddition Cascade of Nitroalkyne Substrates

Gold-Catalyzed Regioselective Hydration of Propargyl Acetates Assisted by a Neighboring Carbonyl Group: Access to α-Acyloxy Methyl Ketones and Synthesis of (±)-Actinopolymorphol B

Gold-Catalyzed Rearrangements: Reaction Pathways Using 1-Alkenyl-2-alkynylcyclopropane Substrates

Flexible Gold-Catalyzed Regioselective Oxidative Difunctionalization of Unactivated Alkenes



Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions

Efficient Cycloisomerization of Propargyl Amides by Electrophilic Gold(I) Complexes of KITPHOS Monophosphines: A Comparative Study

Close Menu