This Page keeps a track of the latest advances in Au/Ag/Pt catalysis and is supported by the National Science Foundation (NSF) under grant # 0969157. Thank you for visiting!!!

Dec 26,


[{Au(IPr)}2(μ-OH)]X Complexes: Synthetic, Structural and Catalytic Studies

An Alternative Synthesis of 2-Alkylidene-3,4-dihydro-2H-1,4-benzoxazines by Intramolecular Gold-Catalyzed Hydroalkoxylation of 2-(Prop-2-yn-1-ylamino)phenols

Dec 19,


Lewis Acid Catalyzed Intramolecular Direct Ene Reaction of Indoles

Reversal of Selectivity in Gold-Catalyzed Cyclizations of 3,3-Disubstituted 1,4-Diynes

Gold-complexes catalyzed oxidative α-cyanation of tertiary amines

Gold-catalysed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles

Dec. 12,


Stereo- and Regioselective Gold-Catalyzed Hydroamination of Internal Alkynes with Dialkylamines

Gold-Catalyzed Cyclopenta- and Cycloheptannulation Cascades: A Stereocontrolled Approach to the Scaffold of Frondosins A and B

Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions

Dec 05,


Effects of haloniums on gold-catalyzed ring expansion of 1-oxiranyl-1-alkynylcyclopropanes

Gold-mediated C–H bond functionalisation

Gold-Catalyzed Direct Activation of Allylic Alcohols in the Stereoselective Synthesis of Functionalized 2-Vinyl-Morpholines

Unexpected Regioselectivity in Cycloisomerization of 2-Alkynyl-3-nitro­thiophenes

Nov 28,


Mechanistic Study on the Gold-Catalyzed C−S Bond Formation of α-Thioallenes To Form 2,5-Dihydrothiophenes

Olefination of α,α′-Divinyl Ketones through Catalytic Meyer−Schuster Rearrangement

Cyclization Accompanied with 1,2-Phenyl Migration in the Protonation of Ruthenium Acetylide Complex Containing an Allenyl Group

Gold(I)-catalysed synthesis of conjugated trienes

Nov 21,


Gold(I)-Catalyzed Intramolecular Tandem Addition/Friedel−Crafts Reactions between Acyclic Enamides and 1-Arylalkynes

Gold-Catalyzed Oxidative Ring-Expansions and Ring-Cleavages of Alkynylcyclopropanes by Intermolecular Reactions Oxidized by Diphenylsulfoxide†

Efficient and Clean Gold-Catalyzed One-Pot Selective N-Alkylation of Amines with Alcohols

Gold-Catalyzed Direct Activation of Allylic Alcohols in the Stereoselective Synthesis of Functionalized 2-Vinyl-Morpholines

Nov 14,


Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides

Gold(I)-Catalyzed Cycloisomerization of β-Alkynylpropiolactones to Substituted α-Pyrones

On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped PropargylpyridinesGold-catalyzed rearrangement of substituted allyl aryl ethers

Nov 07,


Gold-Catalyzed Synthesis of α-Fluoro Acetals and α-Fluoro Ketones from Alkynes

Ligand influence in the selective gold-mediated synthesis of allenes

Mechanistic Dichotomy with Alkynes in the Formal Hydrohydrazination/Fischer Indolization Tandem Reaction Catalyzed by a Ph3PAuNTf2/pTSA Binary System

Gold-Catalyzed Diastereoselective Synthesis of α-Fluoroenones from Propargyl Acetates

Oct 31,


Highly Selective Ratiometric Fluorescent Sensing for Hg2+ and Au3+, Respectively, in Aqueous Media

The [4+2], not [2+2], Mechanism Occurs in the Gold-Catalyzed Intramolecular Oxygen Transfer Reaction of 2-Alkynyl-1,5-Diketones

Gold(I)-Catalyzed Cycloisomerization of 2-Fluoroalk-3-yn-1-ones: Synthesis of 2,5-Substituted 3-Fluorofurans

Gold-Catalyzed Synthesis of a-Fluoro Acetals and a-Fluoro Ketones from Alkynes

Oct. 24,


Synthesis and Catalytic Activity of Gold Chiral Nitrogen Acyclic Carbenes and Gold Hydrogen Bonded Heterocyclic Carbenes in Cyclopropanation of Vinyl Arenes and in Intramolecular Hydroalkoxylation of Allenes

An Efficient Synthesis of Polysubstituted Naphthalene Derivatives by Gold-Catalyzed Cyclization of 1-Arylalka-2,3-dienyl Acetates

Exo/endo selectivity-control in Lewis-acid catalyzed tandem heterocyclization/formal [4+3] cycloaddition: synthesis of polyheterocycles from 2-(1-alkynyl)-2-alken-1-ones and 1,3-diphenylisobenzofuran

Oct 17,


A Modular, Efficient, and Stereoselective Synthesis of Substituted Piperidin-4-ols

Gold(I)-Catalyzed Asymmetric Synthesis of Planar Chiral Arene Chromium Complexes

Gold-Catalyzed Cascade Cyclization-Oxidative Alkynylation of Allenoates

Synthesis of 2-Alkyl- and Aryl-3-ethoxycarbonyl-2,5-dihydrofurans through Gold-Catalyzed Intramolecular Hydroalkoxylation

Development of Versatile and Silver-Free Protocols for Gold(I) Catalysis

Oct. 10,


3,3¢-Bis(arylbenzofurans) via a Gold-Catalyzed Domino Process

Novel Acyclic Diaminocarbene Ligands with Increased Steric Demand and Their Application in Gold Catalysis

Carbocations or Cyclopropyl Gold Carbenes in Cyclizations of Enynes



Experimental and Theoretical Investigation into the Gold-Catalyzed Reactivity of Cyclopropenylmethyl Acetates

Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes

In situ coupled oxidation cycle catalyzed by highly active and reusable Pt-catalysts: dehydrogenative oxidation reactions in the presence of a catalytic amount of o-chloranil using molecular oxygen as the terminal oxidant

Unprecedented Water Addition to the α,β-Unsaturated Enone Bond, Mediated by the Combination of Carbonate and Platinum(II)

Mechanism of the gold-catalyzed cyclopropanation of alkenes with 1,6-enynes

Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes

Arylsilanes: Application to Gold-Catalyzed Oxyarylation of Alkenes

An Ir–Pt Catalyst for the Multistep Preparation of Functionalized Indoles from the Reaction of Amino Alcohols and Alkynyl Alcohols



Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis

A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology

One-Pot Synthesis of Menthol Catalyzed by a Highly Diastereoselective Au/MgF2 Catalyst

Gold(I)/Zn(II) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles

Sep. 19,


Formal Total Synthesis of Okadaic Acid via Regiocontrolled Gold(I)-Catalyzed Spiroketalizations

Gold-Catalyzed Cascade Annulations of 2-(Ynol)aryl Aldehydes: Facile Synthesis of Benzochromanes and Benzobicyclo[n.3.1]acetals

Synthesis, Photophysical Properties, and Molecular Aggregation of Gold(I) Complexes Containing Carbon-Donor Ligands

Redox-Active Catalyst Based on Poly(Anilinesulfonic Acid)- Supported Gold Nanoparticles for Aerobic Alcohol Oxidation in Water

Gold-Catalyzed Annulations of 1-(2,3-Butadienyl)-1H-Indole Derivatives

Gold-catalyzed glycosidations: unusual cleavage of the interglycosidic bond while studying the armed/disarmed effect of propargyl glycosides

Gold catalysed cyclisation reactions of 1,6-diynes triggered by the addition of methanol

Sept. 12,


Gold(I)-Catalyzed Cyclization of β-Allenylhydrazones: An Efficient Synthesis of Multisubstituted N-Aminopyrroles

Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

Gold (I) catalysis of X–H bond insertions

Sept. 5,


Gold(I) and Bronsted Acid Catalyzed Intramolecular Rearrangements of Vinylidenecyclopropanes

Gold(III)-Catalyzed Tandem Reaction of O-Arylhydroxylamines with 1,3-Dicarbonyl
Compounds: Highly Selective Synthesis of 3-Carbonylated Benzofuran Derivatives

Gold-catalyzed regiospecific intermolecular hydrothiolation of allenes

August 29,


Mechanistic Study of Gold(I)-Catalyzed IntermolecularHydroamination of Allenes

Gold-Catalyzed Stereoselective Synthesis of 9-Oxabicyclo[3.3.1]nona-4,7-dienes from Diverse 1-Oxo-4-oxy-5-ynes: A Viable Formal [4 + 2] Cycloaddition on an strans-Heterodiene Framework

Fluorine-Enabled Cationic Gold Catalysis: Functionalized Hydration of Alkynes

August 21,


C−C Coupling Reactivity of an Alkylgold(III) Fluoride Complex with Arylboronic Acids

Synthesis of 3-Oxa- and 3-Azabicyclo[4.1.0]heptanes by Gold-Catalyzed Cycloisomerization of Cyclopropenes

Direct Alkynylation of Thiophenes: Cooperative Activation of TIPS–EBX with Gold and Brønsted Acids

Elementary Steps in Gold Catalysis: The Significance of gem-Diauration

August 15,


Gold-Catalyzed Annulation/Fragmentation: Formation of Free Gold Carbenes
by Retro-Cyclopropanation

Silver- and Gold-Mediated Intramolecular Cyclization to Substituted Tetracyclic Isoquinolizinium Hexafluorostilbates

Synthesis of cis-3-Acyl-4-alkenylpyrrolidines via Gold(I)-Catalyzed Cycloisomerization Reaction of

Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction

August 08,


Stereoselective Syntheses of Trisubstituted Olefins via Platinum Catalysis:
r-Silylenones with Geometrical Complementarity

Gold(I)-Catalyzed Addition of Diphenyl Phosphate to Alkynes: Isomerization of Kinetic Enol Phosphates to the Thermodynamically Favored Isomers

AuI-Catalyzed Direct Hydroamination/Hydroarylation and Double Hydroamination of Terminal Alkynes

Metal-Catalyzed Cycloisomerization and Tandem Oxycyclization/ Hydroxylation of Alkynols: Synthesis of Nonfused, Spiranic and Fused Oxabicyclic β-Lactams

Aug. 1,


Diastereo- and Enantioselective Gold(I)-Catalyzed Intermolecular
Tandem Cyclization/[3+3]Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones

Gold(I)-Catalyzed Cycloisomerization of Enynes Containing Cyclopropenes

Glycosylation initiated cationic ring-opening polymerization of tetrahydrofuran to prepare neo-glycopolymers

July. 25,


Synthesis and characterization of organogold complexes containing an acid stable Au–C bond through triazole-yne 5-endo-dig cyclization

Synthesis of Diverse Indole-Containing Scaffolds by Gold(I)-Catalyzed Tandem Reactions of 3-Propargylindoles Initiated by 1,2-Indole Migrations: Scope and Computational Studies (p NA)

Gold(I)-catalysed alcohol additions to cyclopropenes

July. 18,


Reagent-Dependent Formation of C-C and C-F Bonds in Pt Complexes: An
Unexpected Twist in the Electrophilic Fluorination Chemistry

Biphasic Pd-Au Alloy Catalyst for Low-Temperature CO Oxidation

Gold Catalysis: Tandem Reactions of Diyne–Diols and External Nucleophiles as an Easy Access to Tricyclic Cage-Like Structures

In Situ Formation of Au–Pd Bimetallic Active Sites Promoting the Physically Mixed Monometallic Catalysts in the Liquid-Phase Oxidation of Alcohols

July. 11,


Gold Catalyzed Diastereoselective Cascade Allylation/Enyne Cycloisomerization to Construct Densely Functionalized Oxygen Hetereocycles

Gold Catalysis: In Situ EXAFS Study of Homogeneous Oxidative Esterification

Gold(I)-Catalyzed Cascade for Synthesis of Pyrrolo[1,2-a:2‘,1’-c]-/Pyrido[2,1-c]pyrrolo[1,2-a]quinoxalinones

July. 04,


Gold-Catalyzed Synthesis of Bicyclo[3.2.0]heptenes via a Formal [3+2]/[2+2]-Annulation of Allylsilane with 4-Methoxybut-2-yn-1-ols

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

Asymmetric One-Pot Sequential Organo- and Gold Catalysis for the Enantioselective Synthesis of Dihydropyrrole Derivatives )

Regio- and Stereoselective Intermolecular Hydroalkoxylation of Alkynes Catalysed by Cationic Gold(I) Complexes

June. 27,


Gold-Catalyzed Stereocontrolled Oxacyclization/[4+2]-Cycloaddition Cascade
of Ketone-Allene Substrates 

Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes

Homogeneous Gold Catalysis Beyond Assumptions and Proposals—Characterized Intermediates

June. 20,


Gold-Catalyzed Three-Component Coupling: Oxidative Oxyarylation of Alkenes

Unlikeliness of Pd-Free Gold(I)-Catalyzed Sonogashira Coupling Reactions

June. 13,


Carboxylation of C−H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes

Gold(I)-Catalyzed Domino Reaction of Aziridinyl Alkynes

June. 06,


Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

Gold-Catalyzed One-Step Practical Synthesis of Oxetan-3-ones from Readily
Available Propargylic Alcohols

Efficient Synthesis of Lactic Acid by Aerobic Oxidation of Glycerol on Au–Pt/TiO2 Catalysts

May. 30,


Gold-Catalyzed Tandem Cyclizations of 1,6-Diynes Triggered by Internal
N- and O-Nucleophiles

Novel Sulfonated N-Heterocyclic Carbene Gold(I) Complexes: Homogeneous Gold Catalysis for the Hydration of Terminal Alkynes in Aqueous Media

Gold-Catalyzed Domino Reactions Consisting of Regio- and Stereoselective1,2-Alkyl Migration

May. 23,


Gold(I)-Catalyzed Enantioselective Synthesis of Functionalized Indenes 

Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans

Gold-Catalyzed Cycloisomerization Reactions of 2-Tosylaminophenylprop-1-yn-3-ols as a Versatile Approach for Indole Synthesis

May. 16,


Gold-Catalyzed Three-Component Tandem Process: An Efficient and Facile Assembly of Complex Butenolides from Alkynes, Amines, and Glyoxylic Acid

Atomically Precise Au25(SR)18 Nanoparticles as Catalysts for the Selective Hydrogenation of α,β-Unsaturated Ketones and Aldehyde

Platinum-Catalyzed Intramolecular Hydroarylation of Allenyl Arenes: Efficient Synthesis of 1,4-Dihydronaphthalenes

Access to 2,5-Diamidopyrroles and 2,5-Diamidofurans by Au(I)-Catalyzed Double Hydroamination or Hydration of 1,3-Diynes

Synthesis of Polycyclic Compounds by a Cascade Cycloisomerisation/Diels-Alder Reaction

Gold/Acid-Cocatalyzed Regiodivergent Preparation of Bridged Ketals via Direct Bis-Oxycyclization of Alkynic Acetonides

New and Easily Accessible Nitrogen Acyclic Gold(I) Carbenes: Structure and Application in the Gold-Catalyzed Phenol Synthesis as well as the Hydration of Alkynes

May 09,


Regioselective Synthesis of 3-Benzazepinones and Unexpected 5-Bromo-3-benzazepinones

Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes

Direct Synthesis of Trisubstituted Isoxazoles through Gold-Catalyzed Domino Reaction of Alkynyl Oxime

Gold-Catalyzed Tandem Cyclization of Dienol Silyl Ethers for the Preparation of Bicyclo[4.3.0]nonane Derivatives

Gold(I)-Catalyzed Tandem Transformation: A Simple Approach for the Synthesis of Pyrrolo/Pyrido[2,1-a][1,3]benzoxazinones and Pyrrolo/Pyrido[2,1-a]quinazolinones

May 02,


Gold-Catalyzed Cyclization and Subsequent Arylidene Group Transfer of O-Propioloyl Oximes

Gold-Catalyzed Domino Reactions Consisting of Regio- and Stereoselective 1,2-Alkyl Migration

Platinum-catalyzed cycloisomerization of 1,4-enynes via activation of a sp3-hybridized C–H bond

Au-Catalyzed Tandem Cyclization/[1,2]-Alkyl Migration Reaction of Epoxy Alkynes: Synthesis of Spiropyranones

Gold and palladium combined for the Sonogashira-type cross-coupling of arenediazonium salts

Apr. 25,


Highly Enantioselective Relay Catalysis in the Three-Component Reaction for Direct Construction of Structurally Complex Heterocycles

Gold-Catalyzed Intramolecular Indole/Alkyne Cyclization Cascades through a Heterolytic Fragmentation: 1,5-Indole Migration and Allenylation

Gold(I)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

Apr. 18,


Efficient Synthesis of E-r-Haloenones Through Chemoselective Alkyne Activation Over Allene with Triazole-Au Catalysts

NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-exo-dig Heterocyclization of 1-(o-Ethynylaryl)ureas

Metal–Arene Interactions in Dialkylbiarylphosphane Complexes of Copper,
Silver, and Gold

Construction of 2,3-Dihydrofuran Cores through the [3+2] Cycloaddition
of Gold a-Carbonylcarbenoids with Alkenes

Apr. 11,


An Alternative Approach to Aldol Reactions: Gold-Catalyzed Formation of Boron Enolates from Alkynes

Gold-Catalyzed Cross-Couplings: New Opportunities for C您的浏览器可能不支持显示此图像。 C Bond Formation 

Gold(I)-Catalyzed Tandem Rearrangement-Nucleophilic Substitution of 您的浏览器可能不支持显示此图像。 -Acetoxy Alkynyl Oxiranes or Aziridines: Efficient Approach to Furans and Pyrroles

Apr. 04,


Gold-Catalyzed Intramolecular Oxidative Cross-Coupling of Nonactivated Arenes

Gold-Catalyzed Dealkoxylative Carbocyclization/[3+3]-Annulation Cascade of Acetal-Allene or Ketal-Allene Substrates

Platinum-Catalyzed Intramolecular Hydrohydrazination: Evidence for Alkene Insertion into a Pt−N Bond

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

Mar. 14,


Mechanistic Insights in Gold-Stabilized Nonclassical Carbocations: Gold-Catalyzed Rearrangement of 3-Cyclopropyl Propargylic Acetates

Remarkable anion effects uncovered in the development of a Au(III)-catalyzed tandem nucleophilic substitution–1,5-enyne cycloisomerization process



Silver-Catalyzed Enantioselective Carbon Dioxide Incorporation into Bispropargylic Alcohols

Gold(I)-Catalyzed Tandem Cyclization Approach to Tetracyclic Indolines

Gold-Catalyzed Intermolecular Hydrophenoxylation of Unactivated Internal Alkynes

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

Feb. 28,


Stereoselective One-Pot Synthesis of 1-Aminoindanes and 5,6-Fused Azacycles Using a Gold-Catalyzed Redox-Pinacol-Mannich-Michael Cascade

Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides

Cationic Gold(I)-Catalyzed Intramolecular Cyclization of γ-Hydroxyalkynones into 3(2H)-Furanones

Pt-Catalyzed Hydrative Cyclization of 2-Enynylbenzaldehydes and Its Application to Faveline Synthesis

Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles

Gold(I)-Catalyzed Tandem Rearrangement–Nucleophilic Substitution ofα-Acetoxy Alkynyl Oxiranes or Aziridines: Efficient Approach to Furans and Pyrroles

Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations

Feb. 21,


Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence

Enantioselective Gold Catalysis: Opportunities Provided by Monodentate Phosphoramidite Ligands with an Acyclic TADDOL Backbone

A Facile and Mild Synthesis of Enamides using a Gold-Catalyzed Nucleophilic Addition to Allenamides

Gold(I)- and Yb (OTf)3-Cocatalyzed Rearrangements of Epoxy Alkynes: Transfer of a Carbonyl Group in a Five-Membered Carbocycle

Feb. 14,


Gold(I)-Catalyzed One-Pot Tandem Coupling/Cyclization: An Efficient Synthesis of Pyrrolo/PyridoACHTUNGTRENUNG[2,1-b]benzo[d]ACHTUNGTRENUNG[1,3]oxazin-1-ones

Feb. 08,


Comparative Theoretical Study of 1,3-Dipolar Cycloadditions of Allyl-Anion Type Dipoles to Free and Pt-Bound Nitriles

Gold- and Platinum-Catalyzed Formal Markownikoff’s Double Hydroamination of Alkynes: A Rapid Access to Tetrahydroquinazolinones and Angularly-Fused Analogues Thereof

Au/Ag-Catalyzed Intramolecular Ring-Opening of Vinylidene-cyclopropanes (VDCPs): An Easy Access to Functional Tetrahydropyrans

Feb. 01,


Domino Process in Silver-Catalyzed Reactions of N-Arylformimidates and Active Methylene Compounds Involving Cycloisomerization and 1,3-Alkenyl Shift

Pt-Catalyzed Tandem 1,2-Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters

Stereoselective One-Pot Synthesis of 1-Aminoindanes and 5,6-Fused Azacycles Using a Gold-Catalyzed Redox-Pinacol-Mannich-Michael Cascade

Aqueous Room Temperature Gold-Catalyzed Chemoselective Transfer Hydrogenation of Aldehydes

Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations

Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Jan. 24,


Gold- and Platinum-Catalyzed Formal Markownikoff’s Double Hydroamination of Alkynes: A Rapid Access to Tetrahydroquinazolinones and Angularly-Fused Analogues Thereof

Gold-Catalyzed Ethynylation of Arenes

Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines

Gold(I)-catalyzed one-pot reaction between 2-alkynylanilines and alkynols leading to the formation of C-3 substituted indoles: a case of formal carboamination of alkynes


Jan. 17,


Gold(I)-Catalyzed Ring Expansions of Unactivated Alkynylcyclopropanes to

(E)-2-Alkylidenecyclobutanamines in the Presence of Sulfonamides

Unusual Approach to Branched 3-Alkynylamides and to 1,5-Dihydropyrrol-2-ones

Gold(III)-Catalyzed Tandem Reaction of Ketones with Phenols: Efficient and Highly Selective Synthesis
of Functionalized 4H-Chromenes

Cyclization of Propargylic Amides: Mild Access to Oxazole Derivatives

Gold(I)- and YbACHTUNGTRENUNG(OTf)3-Cocatalyzed Rearrangements of Epoxy Alkynes:
Transfer of a Carbonyl Group in a Five-Membered Carbocycle

Synthesis of Bicyclic Ethers by a Gold/Palladium/Gold-Catalyzed Cyclization/Cross Coupling Sequence

Jan. 10,


Diastereoselective c-vinyl butyrolactone synthesis via gold catalyzed cyclization of allylic acetate

Gold(I)-Catalyzed Enantioselective Synthesis of Pyrazolidines, Isoxazolidines, and Tetrahydrooxazines

Serendipitous Discovery of the Catalytic Hydroammoniumation and Methylamination of Alkynes

Gold-Catalyzed Transannular [4+3] Cycloaddition Reactions

Jan. 05,


Gold and Organocatalysis Combined

Regioselective Synthesis of tert-Allylic Ethers via Gold(I)-Catalyzed Intermolecular Hydroalkoxylation of Allenes

Dec. 29,


Synthesis of Pyrroles by Gold(I)-Catalyzed Amino−Claisen Rearrangement of N-Propargyl Enaminone Derivatives

Gold(I)-Catalyzed Glycosylation with Glycosyl ortho-Alkynylbenzoates as Donors: General Scope and Application in the Synthesis of a Cyclic Triterpene Saponin

Regiocontrolled Synthesis of Ethene-Bridged para-Phenylene Oligomers Based on PtII- and RuII-Catalyzed Aromatization

Dec 20,


Catalyzed Catalysis Using Carbophilic Lewis Acidic Gold and Lewis Basic Palladium: Synthesis of Substituted Butenolides and Isocoumarins

PtCl2-Catalyzed Cycloisomerization of 1,6-Enynes for the Synthesis of Substituted Bicyclo[3.1.0]hexanes

Gold-Catalyzed Cyclization of Alkynylaziridines as an Efficient Approach toward Functionalized
N-Phth Pyrroles

1,2,3-Triazole as a Special “X-Factor” in Promoting Hashmi Phenol Synthesis

Gold Catalysis: Enantiotopos SelectionGold-Catalyzed endo-Cyclizations of 1,4-Diynes to Seven-Membered Ring Heterocycles

Dec 13,


Reusable Gold(I) Catalysts with Unique Regioselectivity for Intermolecular Hydroamination of Alkynes

Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length

Zwitterionic Relatives of Cationic Platinum Group Metal Complexes: Applications in Stoichiometric and
Catalytic s-Bond Activation

Tandem Enzyme/Gold-Catalysis: From Racemic a-Allenic Acetates to Enantiomerically Enriched 2,5-Dihydrofurans in One Pot

Dec 06,


Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

Gold(I)-Catalyzed Tandem C−H and C−C Activation (Cleavage)

Sequential Platinum-Catalyzed Cycloisomerization and Cope Rearrangement of Dienynes 

Propargyl Amine Synthesis Catalysed by Gold and Copper Thin Films by Using Microwave-Assisted Continuous-Flow Organic Synthesis

Nov. 29,


Catalyzed Catalysis Using Carbophilic Lewis Acidic Gold and Lewis Basic Palladium: Synthesis of Substituted Butenolides and Isocoumarins

Gold-Silane and Gold-Stannane Complexes: Saturated Molecules as σ-Acceptor Ligands

Highly Substituted Furo[3,4-c]azepines by Gold(I)-Catalyzed Diastereoselective Tandem Double Heterocyclizations and 1,2-Alkyl Migration

Cyclization of Propargylic Amides: Mild Access to Oxazole Derivatives

A Formal Synthesis of Porantheridine and an Epimer

Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

Nov. 22,


Silver- and Gold-Catalyzed Intramolecular Rearrangement of Propargylic Alcohols Tethered with Methylenecyclopropanes: Stereoselective Synthesis of Allenylcyclobutanols and
1-Vinyl-3-oxabicyclo[3.2.1]octan-8-one Derivatives

Platinum-Catalyzed Hydrogenative Cyclization of Yne-Enones, Yne-Aldehydes,
and Yne-Dienes

Platinum-Catalyzed Multisubstituted Benzo[b]selenophene Synthesis

Nov. 15,


Enantioselective Gold-Catalyzed Allylic Alkylation of Indoles with
Alcohols: An Efficient Route to Functionalized Tetrahydrocarbazoles

Direct Alkynylation of Indole and Pyrrole Heterocycles

Concise One-Pot Tandem Synthesis of Indoles and Isoquinolines from Amides

Nov. 8,


Enhancement of Reaction Efficiency by Functionalized Alcohols on Gold(I)-Catalyzed Intermolecular Hydroalkoxylation of Unactivated Olefins

Efficient, Regioselective Access to Bicyclic Imidazo[1,2-x]- Heterocycles via Gold- and Base-Promoted Cyclization of 1-Alkynylimidazoles

Gold-Catalyzed endo-Cyclizations of 1,4-Diynes to Seven-membered Ring Heterocycles

Gold Catalysis: Enantiotopos Selection

Nov. 1,


Platinum(II)-Catalyzed Intermolecular [3 + 2] Cycloaddition of Propadienyl Silyl Ethers and Alkenyl Ethers

C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3 C−H Bonds Catalyzed by Platinum Tetraiodide

Enantioselective One-Pot Organocatalytic Michael Addition/Gold-Catalyzed Tandem Acetalyzation/Cyclization

Oct. 25,


The Au(I)-Catalyzed Intramolecular Hydroarylation of Terminal Alkynes Under Mild Conditions:
Application to the Synthesis of 2H-Chromenes, Coumarins, Benzofurans, and Dihydroquinolines

Highly Diastereoselective Gold- or Copper-Catalyzed Formal [4+3] Cycloaddition of 1-(1-Alkynyl) Cyclopropyl Ketones and Nitrones

Oct. 18,


Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave Effects, Substrate Scope, and Mechanistic Study

Gold Catalysis: Isolation of Vinylgold Complexes Derived from Alkynes

Glycosylation Using Unprotected Alkynyl Donors

A Direct Approach to 5-Hydroxybenzofurans via a Platinum-Catalyzed Domino Rearrangement/5-endodig Cyclization Reaction of Quinols

Oct. 11,


Highly Efficient and Tunable Synthesis of Dioxabicyclo[4.2.1] Ketals and Tetrahydropyrans via Gold-Catalyzed Cycloisomerization of 2-Alkynyl-1,5-diols

Dinuclear Gold−Silver Resting States May Explain Silver Effects in Gold(I)-Catalysis

Gold(III) Chloride Catalyzed Synthesis of 1-Cyanoisoindoles

Gold(I)-Catalyzed Synthesis of Highly Substituted 2-Cyclopentenones from 5-Siloxypent-3-en-1-ynes

Oct. 04,


Highly Regioselective Gold-Catalyzed Ring-Opening Allylation and Azidation of Dihydrofurans

Gold Catalysis: Efficient 1,3-Induction with Diastereotopic Homopropargyl Alcohols in the Phenol Synthesis

Gold and Palladium Combined for Cross-Coupling

Aqueous Room Temperature Gold-Catalyzed Chemoselective Transfer Hydrogenation of Aldehydes

PdCl2-Promoted Electrophilic Annulation of 2-Alkynylphenol Derivatives with Disulfides or Diselenides in the Presence of Iodine

Tandem Enzyme/Gold-Catalysis: From Racemic α-Allenic Acetates to Enantiomerically Enriched 2,5-Dihydrofurans in One Pot

Sept. 28,


Gold- or Platinum-Catalyzed Synthesis of Sulfur Heterocycles: Access to Sulfur Ylides without Using Sacrificial Functionality

Formal Alkyne Aza-Prins Cyclization: Gold(I)-Catalyzed Cycloisomerization of Mixed N,O-Acetals Generated from Homopropargylic Amines to Highly Substituted Piperidines

Total Synthesis and Stereochemical Assignment of (−)-Ushikulide A

Gold- or Platinum-Catalyzed Synthesis of Sulfur Heterocycles: Access to Sulfur Ylides without Using Sacrificial Functionality

Platinum-Catalyzed Intramolecular Cyclizations of Alkynes: Efficient Synthesis of Pyrroloazepinone Derivatives

Gold(I)-Catalyzed Intermolecular Oxyarylation of Alkynes: Unexpected Regiochemistry in the Alkylation of Arenes

Sept. 21,


Gold- or Platinum-Catalyzed Cascade Processes of Alkynol Derivatives Involving Hydroalkoxylation Reactions Followed by Prins-Type Cyclizations

Gold-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Aryl-1-allene-6-enes

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of theDivergence between [4C+3C] and [4C+2C] Pathways

An Unusual Access to Medium Sized Cycloalkynes by a New Gold(I)-Catalysed Cycloisomerisation of Diynes

An efficient synthesis of carbazoles from PtCl2-catalyzed cyclization of 1-(indol-2-yl)-2,3-allenols

Highly Regioselective Au(I)-Catalyzed Hydroamination of Ynamides and Propiolic Acid Derivatives with Anilines

Dec. 23, 2007

Synthesis of Multisubstituted 2-(Dihydrofuran-2(3H)-ylidene)acetates via Intramolecular Carboalkoxylation by Platinum-Olefin Catalyst System

Gold- vs. Platinum-Catalyzed Polycyclizations by O-Acyl Migration. Solvent-Free Reactions

Dec. 16, 2007

Gold(I)-Catalyzed Intramolecular [4+2] Cycloadditions of Arylalkynes or 1,3-Enynes with Alkenes: Scope and Mechanism

Synthesis of Functionalized Furans via Gold(I)-Catalyzed Claisen-Type Rearrangement

Platinum-Catalyzed Intramolecular [4C+3C] Cycloaddition between Dienes and Allenes

Dec. 9, 2007

Platinum-Catalyzed Regio- and Stereoselective Arylthiolation of Internal Alkynes

PtCl4-Catalyzed Domino Synthesis of Fused Bicyclic Acetals

Au(I)-catalyzed efficient synthesis of α-acyloxy-α′-silyl ketones from α-acyloxy-α-alkynylsilanes

Gold-promoted styrene polymerization

Water Compatible Gold(III)-Catalysed Synthesis of Unsymmetrical Ethers from Alcohols

Dec. 2, 2007

Platinum(II)-Catalyzed Cross-Coupling of Polyfluoroaryl Imines

Alkyne versus Allene Activation in Platinum- and Gold-Catalyzed Cycloisomerization of Hydroxylated 1,5-Allenynes

New Pyridine ONN-Pincer Gold and Palladium Complexes: Synthesis, Characterization and Catalysis in Hydrogenation, Hydrosilylation and C-C Cross-Coupling Reactions

Gold-Catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans

Nov. 25, 2007

DFT Study of the Mechanisms of In Water Au(I)-Catalyzed Tandem [3,3]-Rearrangement/Nazarov Reaction/[1,2]-Hydrogen Shift of Enynyl Acetates: A Proton-Transport Catalysis Strategy in the Water-Catalyzed [1,2]-Hydrogen Shift

The Skeletal Rearrangement of Gold- and Platinum-Catalyzed Cycloisomerization of cis-4,6-Dien-1-yn-3-ols: Pinacol Rearrangement and Formation of Bicyclo[4.1.0]heptenone and Reorganized Styrene Derivatives

Synthesis of C-2 methylene glycosides from C-2 propargyloxymethyl glycals exploiting the alkynophilicity of AuCl3

Nov. 18, 2007Platinum-Catalyzed Formation of Cyclic-Ketone-Fused Indoles from N-(2-Alkynylphenyl)lactams
Nov. 11, 2007

Gold-Catalyzed Intramolecular Carbocyclization of Alkynyl Ketones Leading to Highly Substituted Cyclic Enones

Platinum-Catalyzed Chemoselectively Hydrative Dimerization of 2-Alkynyl-1-acetylbenzenes for One-Pot Facile Synthesis of Chrysene Derivatives

Gold-Catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans (p NA)

Highly selective hydroarylation of propiolic acid derivatives using a PtCl2/AgOTf catalytic system

Nov. 04, 2007

Gold(I)-Catalyzed Dynamic Kinetic Enantioselective Intramolecular Hydroamination of Allenes

Platinum-Catalyzed Addition of Dimethylsilylene to beta-Methyl alpha, beta-Unsaturated Ketones: gamma-Silylation Forming 1-Oxa-2-silacyclohex-5-enes

Transition-Metal Complexes Featuring Z-Type Ligands: Agreement or Discrepancy between Geometry and dn Configuration?

Gold(III) catalyzed oxidation of sulfides to sulfoxides with hydrogen peroxide

A general gold-catalyzed direct oxidative coupling of non-activated arenes

Close Menu