Dec. 22 – Dec. 31 2017 | Medicinal Applications of Gold(I/III)-Based Complexes Bearing N-Heterocyclic Carbene and Phosphine Ligands Di(N-heterocyclic carbene) gold(III) imidate complexes obtained by oxidative addition of N-halosuccinimides Gold(II) Trihalide Complexes from Organogold(III) Precursors Synthesis of benzannulated spiroketals with gold-catalyzed cycloisomerization/spiroketalization cascade |
Dec. 15 – Dec. 21 2017 | Diastereoselective Synthesis of C-Vinyl Glycosides via Gold(I)-Catalyzed Tandem 1,3-Acyloxy Migration/Ferrier Rearrangement Hydrogen-Bonding-Assisted Bronsted Acid and Gold Catalysis: Access to Both (E)- and (Z)-1,2-Haloalkenes via Hydrochlorination of Haloalkynes Gold-Catalyzed Controllable C2-Functionalization of Benzofurans with Aryl Diazoesters Dissecting the Gold(I)-Catalyzed Carboaminations of N-Allyl Tetrahydro-β-carbolines to Allenes Gold(I)-Catalyzed 1,3-O-Transposition of Ynones: Mechanism and Catalytic Acceleration with Electron-Rich Aldehydes Gold promoted arylative cyclization of alkynoic acids with arenediazonium salts |
Dec. 08 – Dec. 14 2017 | Gold catalyzed Heck-coupling of arenediazonium o-benzenedisulfonimides Gold-Catalyzed Divergent Ring-Closing Modes of Indole-Tethered Amino Allenynes Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex Merging Gold Catalysis and Bronsted Acid Catalysis for the Synthesis of Tetrahydrobenzo[b][1,8]naphthyridines |
Dec. 01 – Dec. 07 2017 | Spectroscopic Evidence for Ligand Substitution Reactions at the Solid-Liquid Interface of a Sub-micrometer Gold(I) Carbene Complex Well-Defined Chiral Gold(III) Complexes: New Opportunities in Asymmetric Catalysis |
Nov. 18 – Nov. 30 2017 | Gold-catalyzed preparation of annelated 2-azetidinones via divergent heterocyclization of enyne-tethered oxazolidines |
Nov. 11 – Nov. 17 2017 | Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition Cyclopropanation of Benzene Rings by Oxidatively Generated α-Oxo Gold Carbene: One-Pot Access to Tetrahydropyranone-Fused Cycloheptatrienes from Propargyl Benzyl Ethers Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry A Gold-Catalyzed Domino Cyclization Enabling Rapid Construction of Diverse Polyheterocyclic Frameworks |
Nov. 04 – Nov. 10 2017 | Rapid Iododeboronation with and without Gold Catalysis: Application to Radiolabelling of Arenes |
Oct 28- Nov 03 2017 Congrong Liu | Ru/Cu Photoredox or Cu/Ag Catalyzed C4–H Sulfonylation of 1-Naphthylamides at Room Temperature Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O2CCF2SO2F) and N-fluorobenzenesulfonimide |
Oct 21- Oct 27 2017 Shengrong | Fluorescence resonance energy transfer (FRET) for the verification of dual gold catalysis Radical Enamination of Vinyl Azides: Direct Synthesis of N‑Unprotected Enamines |
Oct 14- Oct 20 2017 Hongyi | C(sp3)−H Bond Activation by Vinylidene Gold(I) Complexes: A Concerted Asynchronous or Stepwise Process?
Gold-Catalyzed Synthesis of 1-(Furan-3-yl)-1,2-diones
The Use of Resorcinarene Cavitands in Metal-Based Catalysis On-Water Silver(I)-Catalyzed Cycloisomerization of Acetylenic Free Amines/Amides towards 7-Azaindole/Indole/Isoquinolone Derivatives Synthesis of Cyclic and Heterocyclic Compounds via Gold-Catalyzed Reactions |
Oct 07- Oct 13 2017 Xinpeng | Tetrazol-5-ylidene Gold(III) Complexes from Sequential [2 + 3] Cycloaddition of Azide to Metal-Bound Isocyanides and N4 Alkylation Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products Gold(I)-Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)-Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols Lactols in Asymmetric Sequential Organo- and Gold-Catalysis: Synthesis of Densely Functionalized Epimeric Bicyclic O,O-Acetals Where does Au coordinate to N-(2-pyridiyl)benzotriazole: gold-catalyzed chemoselective dehydrogenation and borrowing hydrogen reactions The Coordination and Supramolecular Chemistry of Gold Metalloligands |
Oct 02- Oct 06 2017 Xu | Stepwise Reversible Oxidation of N-Peralkyl-Substituted NHC–CAAC Derived Triazaalkenes: Isolation of Radical Cations and Dications Silver Makes Better Electrical Contacts to Thiol-Terminated Silanes than Gold Highly Luminescent Pincer Gold(III) Aryl Emitters: Thermally Activated Delayed Fluorescence and Solution-Processed OLEDs Gold-catalyzed Fluorination of Alkynyl Esters and Ketones: Efficient Access to Fluorinated 1,3-Dicarbonyl Compounds Silver-mediated oxidative C–H difluoromethylation of phenanthridines and 1,10-phenanthrolines Highly Strained Organogold Complexes and Their Gold- or Rhodium-Catalyzed Isomerizations |
Sep 25- Oct 01 2017 Shengrong | Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals Silver-mediated oxidative C–H difluoromethylation of phenanthridines and 1,10-phenanthrolines (CF3)3Au as a Highly Acidic Organogold(III) Fragment Exploration of a Au(I)-mediated three-component reaction for the synthesis of DNA-tagged highly substituted spiroheterocycles Synthesis of Spiroindolenines via Regioselective Gold(I)-Catalyzed Cyclizations of N-Propargyl Tryptamines Gold(I) catalyzed cascade cyclization: intramolecular two-fold nucleophilic addition to vinylidenecyclopropanes (VDCPs) Gold-catalyzed synthesis of β-trifluoromethylated α,β-unsaturated ketones from CF3-substituted propargylic carboxylates and their reactivity in Diels-Alder reactions A Structure-Based Activity Study of Highly Active Unsymmetrically Substituted NHC Gold(I) Catalysts |
Sep 18- Sep 24 2017 Hongyi Chen | Alkynyl Thioethers in Gold-Catalyzed Annulations to form Oxazoles Photosensitizer-free visible light-mediated gold-catalysed cis-difunctionalization of silyl-substituted alkynes Exploring hydroamination-cycloaddition-fragmentation sequences to access polycyclicguanidines and vinyl-2-aminoimidazoles Silver-catalyzed chemoselective annulation of propargyl amines with alkynes for access to pyridines and pyrroles |
Sep 11- Sep 17 2017 Xinpeng | Tandem [3 + 2] Cycloaddition/1,4-Addition Reaction of Azomethine Ylides and Aza-o-quinone Methides for Asymmetric Synthesis of Imidazolidines Chemoselective Double Annulation of Two Different Isocyanides: Rapid Access to Trifluoromethylated Indole-Fused Heterocycles Gold-Catalyzed Synthesis of 1-(Indol-3-yl)carbazoles: Selective 1,2-Alkyl vs 1,2-Vinyl Migration Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes The First Gold(III) Formate: Evidence for β-Hydride Elimination Silver-Catalyzed Double Hydrocarbonation of 2-Trifluoromethyl-1,3-Conjugated Enynes with 1,3-Dicarbonyl Compounds: Synthesis of Ring-Trifluoromethylated Cyclopentene Gold(I)-catalyzed synthesis of 2-substituted indoles from 2-alkynylnitroarenes with diboron as reductant AgOTf-catalyzed sequential synthesis of 4-isoquinolones via oxidative ring opening of aziridines and aza-Michael addition |
Sep 04- Sep 10 2017 Zaigang Luo | Short Enantioselective Total Synthesis of (−)-Rhazinilam Using a Gold(I)-Catalyzed Cyclization Divergent Regio- and Stereoselective Gold-catalyzedSynthesis ofa-Fluorosulfones and b-Fluorovinylsulfones from Alkynylsulfones Ag(I)-Catalyzed cycloisomerization reactions: synthesis of substituted phenanthrenes and naphthothiophenes |
Aug 28- Sep 03 2017 Yubin Bai | Gold(I)/Gold(III)-Catalyzed Selective Synthesis of N Sulfonyl Enaminone Isomers from Sulfonamides and Ynones via Two Distinct Reaction Pathways Asymmetric Synthesis of Glutamic Acid Derivatives by SilverCatalyzed Conjugate Addition−Elimination Reactions Nucleophile dependent formation of 6- and 7-membered N-heterocycles by platinumcatalysed cyclisation of 1,5-bisallenes Ag(I)-Catalyzed one-pot synthesis of 4-fluorobenzo[b][1,6] naphthyridines and 4-fluoroisoquinolines via iminofluorination of alkynes with Selectfluor Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products |
Aug 14- Aug 20 2017 Xingguang Li | A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis Gold-catalyzed para-selective C–H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds |
Aug 01- Aug 06 2017 Shengrong | Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex Asymmetric syntheses of 8-oxabicyclo[3,2,1]octane and 11-oxatricyclo[5.3.1.0]undecane from glycals |
Jul 24-Jul 30 2017 Hongyi | Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture Silver-Catalyzed Cascade 1,6-Addition/Cyclization of para-Quinone Methides with Propargyl Malonates: An Approach to Spiro[4.5]deca-6,9-dien-8-ones Complex Annulations through Silver Carbenoid Intermediate: An Alternative Entry to Transformations of 1,2,3-Triazoles Silver-Catalyzed Tandem C≡C Bond Hydroazidation/Radical Addition/Cyclization of Biphenyl Acetylene: One-Pot Synthesis of 6-Methyl Sulfonylated Phenanthridines |
Jul 17-Jul 23 2017 Xinpeng | Chemoselective Asymmetric Intramolecular Dearomatization of Phenols with α-Diazoacetamides Catalyzed by Silver Phosphate Inner-Sphere versus Outer-Sphere Coordination of BF4 in a NHC-Gold(I) Complex Silver-Catalyzed Oxidative C(sp3)−P Bond Formation through C−C and P−H Bond Cleavage Investigations on Gold-Catalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals Photopromoted Entry to Benzothiophenes, Benzoselenophenes, 3H-Indoles, Isocoumarins, Benzosultams, and (Thio)flavones by Gold-Catalyzed Arylative Heterocyclization of Alkynes |
Jul 03-Jul 09 2017 Zaigang | Silver-Catalyzed Intramolecular C(5)–H Acyloxylation of 1,4-Di-substituted 1,2,3-Triazoles Regioselective Domino Synthesis of 2-Alkylflavans via Hidden Brønsted Acid Catalysis |
Jun 26 -Jul 02 2017 Yubin | Dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts: rapid access to enantioenriched 2,3-dihydropyrroles Silver-mediated radical 5-exo-dig cyclization of 2-alkynylbenzonitriles: synthesis of phosphinylated 1-indenones |
Jun 19 -Jun 25 2017 Xu Ma | Platinum(II) Dihalide Complexes with 9-Arsafluorenes: Effects of Ligand Modification on the Phosphorescent Properties Synthesis and cytotoxicity studies of novel NHC–Gold(I) pseudohalides and thiolates Synthesis, characterization and anti-proliferative activity of propylene linked bis-benzimidazolium salts and their respective dinuclear Silver(I)-N-heterocyclic carbene complexes Access to silver-NHC complexes from soluble silver species in aqueous or ethanolic ammonia |
Jun 12 -Jun 18 2017 Xingguang | Stereoselective Synthesis of Tetrasubstituted Furylalkenes via Gold-Catalyzed Cross-Coupling of Enynones with Diazo Compounds Gold-Catalyzed Oxidation Terminal Alkyne: An Approach to Synthesize Substituted Dihydronaphthalen-2(1H)-ones and Phenanthrenols Gold(I)-catalyzed access to neomerane skeletons Acenaphthoimidazolylidene Gold Complex-Catalyzed Alkylsulfonylation of Boronic Acids by Potassium Metabisulfite and Alkyl Halides: A Direct and Robust Protocol To Access Sulfones |
Jun 05 -Jun 11 2017 Zhitong | Access to Benzo[a]carbazoles and Indeno[1,2-c]quinolines by a Gold(I)-Catalyzed Tunable Domino Cyclization of Difunctional 1,2-Diphenylethynes Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis Unraveling the Anion/Ligand Interplay in the Reaction Mechanism of Gold(I)-Catalyzed Alkoxylation of Alkynes |
May 29 -Jun 04 2017 Hongyi | Total Synthesis of Dictyodendrins by the Gold-Catalyzed Cascade Cyclization of Conjugated Diynes with Pyrroles Silver-Catalyzed Three-Component 1,1-Aminoacylation of Homopropargylamines: α-Additions for Both Terminal Alkynes and Isocyanides Access to Tetronic Acids via Silver-Catalyzed CO2 Incorporation into Conjugated Ynones Dual Gold Catalysis: Bidirectional Processes and Tandem sp3-C−H Insertion Reactions |
May 22-May 28 2017 Xinpeng | Gold-Catalyzed Formal [3 + 2] Cycloaddition of Ynamides with 4,5-Dihydro-1,2,4-oxadiazoles: Synthesis of Functionalized 4-Aminoimidazoles The Catalytically Lignan-Activation-Based Approach for the Synthesis of (epi)-Podophyllotoxin Derivatives Synthesis of Polysubstituted Polycyclic Aromatic Hydrocarbons by Gold-Catalyzed Cyclization–Oxidation of Alkylidenecyclopropane-Containing 1,5-Enynes Gold-Catalyzed Cadiot–Chodkiewicz-Type Cross-Coupling of Terminal Alkynes with Alkynyl Hypervalent Iodine Reagents: Highly Selective Synthesis of Unsymmetrical 1,3-Diynes Gold(I)-Catalyzed Enantioselective Synthesis of Tetrahydrocarbazoles through Dearomative [4+2] Cycloadditions of 3/2-Substituted 2/3-Vinylindoles Silver-mediated radical 5-exo-digcyclization of 2-alkynylbenzonitriles: synthesis of phosphinylated 1-indenones |
May 15-May 21 2017 Zhixun | Au-Catalyzed [2 + 3] Annulation of Enamides with Propargyl Esters: Total Synthesis of Cephalotaxine and Cephalezomine H Metal Confinement through N-(9-Alkyl)fluorenyl-Substituted N-Heterocyclic Carbenes and Its Consequences in Gold-Catalysed Reactions Involving Enynes General Entry into o-,o′-Heteroatom-Linked N-(Hetero)aryl-Imidazole Motifs by Gold-Catalysed Formal [3+2]-Dipolar Cycloaddition Gold-catalyzed oxidative hydroacylation reactions of α-iminoalkynes with aldehydes and O2 α-Diazo oxime ethers for N-heterocycle synthesis |
May 08-May 14 2017 Xu | Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis Phosphine-Scavenging Role of Gold(I) Complexes from Pd(PBu3)2in the Bimetallic Catalysis of Carbostannylation of Alkynes The Power of Ferrocene, Mesoionic Carbenes, and Gold: Redox-Switchable Catalysis |
May 01-May 07 2017 Xingguang | Synthesis of Spiroketals by Synergistic Gold and Scandium Catalysis A Heterogeneous Gold(I)-Catalyzed [2 + 2 + 1] Annulation of Terminal Alkynes, Nitriles, and Oxygen Atoms Leading to 2,5-Disubstituted Oxazoles Alkynyl sulfoxides as α-sulfinyl carbene equivalents: gold-catalysed oxidative cyclopropanation Formal Synthesis of (+)-Laurencin by Gold(I)-Catalyzed Intramolecular Dehydrative Alkoxylation Silver(I) Catalyzed Intramolecular Cyclization of N-(2-(alk-1-yn-1-yl))-1H-Tetrazoles leading to the formation of N-cyano-2-substituted Indoles under ambient conditions |
Apr 24-Apr 30 2017 Zhitong | Enantioselective Silver and Amine Co-catalyzed Desymmetrizing Cycloisomerization of Alkyne-Linked Cyclohexanones Gold(I)-Catalyzed Cycloisomerization of ortho-(Propargyloxy)arenemethylenecyclopropanes Controlled by Adjacent Substituents at Aromatic Rings Silver-Catalyzed Direct C6–H Arylation of Purines and Purine Nucleosides with Arylboronic Acids |
Apr 17-Apr 23 2017 Li | Aldehydes as Carbon Radical Acceptors: Silver Nitrate-Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives General Entry into o-,o’-Heteroatom-Linked N-(Hetero)aryl Imidazole Motifs by Gold-Catalysed Formal [3+2]-Dipolar Cycloaddition Gold(III)-arene complexes by insertion of olefins into gold-aryl bonds |
Apr 10-Apr 16 2017 Shengrong | Gold(I)-Catalyzed [2 + 2 + 2] Cyclotrimerization of 1,3-Diarylpropargyl Acetals Silver(I)-Catalyzed Regioselective Synthesis of Triazole Fused-1,5-Benzoxazocinones |
Apr 03-Apr 09 2017 Yubin | Au-Catalyzed Synthesis of Thiopyrano[2,3-indoles Featuring Tandem Rearrangement and Hydroarylation Gold(I)-Catalyzed Cyclization for the Synthesis of 8-Hydroxy-3- substituted Isocoumarins: Total Synthesis of Exserolide F Rapid access to cyclopentadiene derivatives through gold-catalyzed cycloisomerization of ynamides with cyclopropenes by preferential activation of alkenes over alkynes Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU> Silver-Catalyzed [2+1] Cyclopropenation of Alkynes with Unstable Diazoalkanes:N-Nosylhydrazones as Room-Temperature Decomposable Diazo Surrogates Direct Reductive Amination of Aldehydes via Environmentally Benign Bentonite-Gold Nanohybrid Catalysis Silver-Catalyzed Regio- and Stereoselective Thiocyanation of Haloalkynes: Access to (Z)-Vinyl Thiocyanates |
Mar 27-Apr 03 2017 Hongyi | Gold-Catalyzed Oxidative [2+2+1] Annulations of Aryldiazo Nitriles with Imines To Yield Polyarylated Imidazolium Salts Synthetic Access Toward Cycloastragenol Glycosides Synthesis of Propargyl-Functionalized NHC Gold Complexes Formation of Gold(III) Alkyls from Gold Alkoxide Complexes |
Mar 20-Mar 26 2017 Xinpeng | Platinum-Catalyzed Double Acylation of 2-(Aryloxy)pyridines via Direct C–H Activation Asymmetric Total Synthesis of (−)-Aspidophylline A Synthesis of Pentafluoroethyl Ethers by Silver-Mediated Oxidative Pentafluoroethylation of Alcohols and Phenols Use of a Traceless Activating and Directing Group for the Construction of Trifluoromethylpyrazoles: One-Pot Transformation of Nitroolefins and Trifluorodiazoethane Gold-Catalyzed Formal Cyclisation/Dimerization of Thiophene-Tethered Diynes Photosensitizer-Free, Gold-Catalyzed C–C Cross-Coupling of Boronic Acids and Diazonium Salts Enabled by Visible Light |
Mar 13-Mar 19 2017 Yuk Fai | Silver-catalyzed decarboxylative bromination of aliphatic carboxylic acids Silver-catalyzed regioselective fluorination of carbonyl directed alkynes: synthesis of α-fluoroketones Silver-catalyzed cyclization of ortho-carbonylarylacetylenols for the synthesis of dihydronaphthofurans On the gold-catalyzed generation of phenyl cations from 1,5-diynes Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes: en route to tetrahydropyrimidines Gold catalysis: synthesis of spiro, bridged, and fused ketal natural products TEMPO-catalyzed oxidative dimerization and cyanation of indoles for the synthesis of 2-(1H-indol-3-yl)-3-oxoindoline-2-carbonitriles Mechanistic study on silver-catalyzed direct amination of unactivated C-H bond |
Mar 06-Mar 12 2017 Zhixun | Electrostatic Control of Regioselectivity in Au(I)-Catalyzed Hydroarylation Gold(I)-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Alkenes with 2-Pyridones Silver-Catalyzed 1,3-Acyloxy Migration/Diels–Alder Reaction of 1,9-Dien-4-yne Esters to Partially Hydrogenated Isoquinolines N1-Selective alkenylation of 1-sulfonyl-1,2,3-triazoles with alkynes via gold catalysis |
Feb 27-Mar 05 2017 Xu Ma | Silver-Catalyzed C(sp3)–H Chlorination Synthesis of β-(1→2)-Linked 6-Deoxy-L-altropyranose Oligosaccharides via Gold(I)-Catalyzed Glycosylation of an ortho-Hexynylbenzoate Donor Gold(I)-Catalyzed Enantioselective [2+2+2] Cycloadditions: An Expedient Entry to Enantioenriched Tetrahydropyran Scaffolds Direct and Autocatalytic Reductive Elimination from Gold Complexes ([(Ph3P)Au(Ar)(CF3)(X)], X=F, Cl, Br, I): The Key Role of Halide Ligands Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O–H bonds of 2-pyridones A new approach for the synthesis of tetrabenzimidazolium salt as a precursor for the tetra-N-heterocyclic carbene dinuclear silver(I) complex |
Feb 13-Feb 19 2017 Zhitong Zheng | Silver-Catalyzed Radical-Involved Cascade Cyclization of Diphenylphosphine with Cinnamamides: Access to 2-Phosphinoyl-3H-pyrrolo[1,2-a]indoles In Vivo Gold Complex Catalysis within Live Mice On the Gold-Catalyzed Generation of Vinyl Cations from 1,5-Diynes Enantioselective Aza-Ene-type Reactions of Enamides with Gold Carbenes Generated from α-Diazoesters Rationally Designed Blue Triplet Emitting Gold(III) Complexes Based on a Phenylpyridine-Derived Framework Stereoselective Synthesis of a Ceramide Transporter Protein (CERT)-Dependent Ceramide-Trafficking Inhibitor, (1R,3S)-HPA-12, via Gold(I)-Catalyzed Cyclization of a Propargylic N-Hydroxylamine |
Feb 06-Feb 12 2017 Li Chen | Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization Gold-Catalyzed [2,3]-Sigmatropic Rearrangement: Reaction of Aryl Allyl Alcohols with Diazo Compounds One Lump or Two? A Plurality of Pathways in Gold(III)-Catalyzed Cyclization Transforming Propargyl Acetates to a Carene-like Bicyclo[4.1.0]heptane Gold-Catalyzed Hydroarylation of N-Aryl Alkynamides for the Synthesis of 2-Quinolinones Silver(I)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones Gold-Catalysed Formal Cyclisation/Dimerization of Thiophene-Tethered Diynes Aryne formation via the hexadehydro Diels-Alder reaction and their Ritter-type transformations catalyzed by a cationic silver complex Gold-Oxazoline Complex-Catalyzed Cross-Dehydrogenative Coupling of Glycine Derivatives and Alkenes Regioselective Direct C3-Phosphorylation of N-Sulfonylindoles under Mild Oxidative Conditions |
Jan 30-Feb 05 2017 Yuguang Wang | Photoinduced gold-catalyzed domino C(sp) arylation/oxyarylation of TMS-terminated alkynols with arenediazonium salts Unexpected skeletal rearrangement in the gold(I)/silver(I)-catalyzed conversion of 7-aryl-1,6-enynes to bicyclo[3.2.0]hept-6-enes via hidden brønsted acid catalysis Desulfinylation of Ag(I) sulfinyl mesoionic carbenes: preparation of C-unsubstituted Au(I)–1,2,3-triazole carbene complexes Gold-catalyzed direct alkynylation of azulenes Silver(I)-promoted cascade reaction of propargylic alcohols, carbon dioxide, and vicinal diols: thermodynamically favorable route to cyclic carbonates Gold-catalyzed ring-expansion through acyl migration to afford furan-fused polycyclic compounds A cationic unsaturated platinum(II) complex that promotes the tautomerization of acetylene to vinylidene Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds |
Jan 23-Jan 29 2017 Shengrong | Silver-catalyzed [2+1] cyclopropenation of alkynes with unstable diazoalkanes: N-nosylhydrazones as room-temperature decomposable diazo surrogates Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)–1,2,3-Triazole Carbene Complexes Gold-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Iodoalkynes: Access to (Z)-β-Iodoenol Esters and 1,4-Disubstituted (Z)-Enynyl Esters Silver-Catalyzed Anti-Markovnikov Hydroxyfluorination of Styrenes A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene Highly para-Selective C−H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters Gold-Catalyzed [3+2]/Retro-[3+2]/[3+2] Cycloaddition Cascade Reaction of N-Alkoxyazomethine Ylides Gold(I) Fluorohalides: Theory and Experiment Silver-Catalyzed Regio- and Stereoselective Thiocyanation of Haloalkynes: Access to (Z)-Vinyl Thiocyanates The Gold-Catalyzed Hydroarylation of Alkynes with Electron-Rich Heteroarenes – A Kinetic Investigation and New Synthetic Possibilities Late-Stage Diversification of Non-Steroidal Anti-Inflammatory Drugs by Transition Metal-Catalyzed C–H Alkenylations, Thiolations and Selenylations Silver-Catalyzed Carbon-Phosphorus Functionalization for Polyheterocycle Formation Gold-Catalyzed 1,4-Carbooxygenation of 3-En-1-ynamides with Allylic and Propargylic Alcohols via Non-Claisen Pathways Sulfide and Sulfonyl Chloride as Sulfonylating Precursors for the Synthesis of Sulfone-Containing Isoquinolinonediones Dual gold and photoredox catalysis: visible light-mediated intermolecular atom transfer thiosulfonylation of alkenes Silver-catalyzed formal [3+2]-cycloaddition of α-trifluoromethylated methyl isocyanides: a facile stereoselective synthesis of CF3-substituted heterocycles Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution Mechanistic study on silver-catalyzed direct amination of unactivated C-H bond |
Jan 16-Jan 22 2017 Yubing Bai | Silver-mediated radical coupling reaction of isocyanides and alcohols/phenols in the presence of water: unprecedented hydration and radical coupling reaction sequence Silver-catalyzed germinal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide AgNO3-catalyzed direct C–H arylation of quinolones by oxidative decarboxylation of aromatic carboxylic acids |
Jan 9-Jan 15 2017 Hongyi | A 11-Steps Total Synthesis of Magellanine through a Gold(I)-Catalyzed Dehydro Diels–Alder Reaction Oxidative Aza-Annulation of Enynyl Azides to 2-Keto/Formyl-1H-pyrroles Diverse Pathways in Catalytic Reactions of Propargyl Aryldiazoacetates: Selectivity between Three Reaction Sites Accessing alternative reaction pathways of the intermolecular condensation between homo-propargyl alcohols and terminal alkynes through divergent gold catalysis Convenient synthesis of 6-alkyl phenanthridines and 1-alkyl isoquinolines via silver-catalyzed oxidative radical decarboxylation Gold-Catalyzed Regiodivergent [2 + 2 + 2]-Cycloadditions of Allenes with Triazines Gold-Catalyzed Unexpected Ring Transformation of Pyrimidodiazepine Derivatives |
Jan 2-Jan 8 2017 Xinpeng | Understanding the Effect of α-Cationic Phosphines and Group 15 Analogues on π-Acid Catalysis Anchoring Triazole-Gold(I) Complex into Porous Organic Polymer To Boost the Stability and Reactivity of Gold(I) Catalyst Gold-catalyzed sequential annulations towards 3,4-fused bi/tri-cyclic furans involving a [3+2+2]-cycloaddition An efficient approach to generate aryl carbenes: gold-catalyzed sequential activation of 1,6-diynes Convenient synthesis of 6-alkyl phenanthridines and 1-alkyl isoquinolines via silver-catalyzed oxidative radical decarboxylation Oxidative Divergent Bicyclizations of 1,n-Enynes through α-C(sp3)–H Functionalization of Alkyl Nitriles Ag-Assisted Fluorination of Unprotected 4,6-Disubstituted 2-Aminopyrimidines with Selectfluor Carbon(0)-Bridged Pt/Ag Dinuclear and Tetranuclear Complexes Based on a Cyclometalated Pincer Carbodiphosphorane Platform Silver-catalysed tandem hydroamination and cyclization of 2-trifluoromethyl-1,3-enynes with primary amines: modular entry to 4-trifluoromethyl-3-pyrrolines Silver-catalyzed one-pot synthesis of benzyl 2-alkynoates under ambient pressure of CO2 and ligand-free conditions |
